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De novo synthesis of mesoporous photoactive titanium(iv)-organic frameworks with MIL-100 topology

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De novo synthesis of mesoporous photoactive titanium(iv)-organic frameworks with MIL-100 topology

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dc.contributor.author Castells-Gil, Javier es_ES
dc.contributor.author Padial, Natalia M. es_ES
dc.contributor.author Almora-Barrios, Neyvis es_ES
dc.contributor.author da Silva, Ivan es_ES
dc.contributor.author Mateo-Mateo, Diego es_ES
dc.contributor.author Albero-Sancho, Josep es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.contributor.author Martí-Gastaldo, Carlos es_ES
dc.date.accessioned 2020-11-13T04:32:09Z
dc.date.available 2020-11-13T04:32:09Z
dc.date.issued 2019-04-21 es_ES
dc.identifier.issn 2041-6520 es_ES
dc.identifier.uri http://hdl.handle.net/10251/154996
dc.description.abstract [EN] Most developments in the chemistry and applications of metal-organic frameworks (MOFs) have been made possible thanks to the value of reticular chemistry in guiding the unlimited combination of organic connectors and secondary building units (SBUs) into targeted architectures. However, the development of new titanium-frameworks still remains limited by the difficulties in controlling the formation of persistent Ti-SBUs with predetermined directionality amenable to the isoreticular approach. Here we report the synthesis of a mesoporous Ti-MOF displaying a MIL-100 topology. MIL-100(Ti) combines excellent chemical stability and mesoporosity, intrinsic to this archetypical family of porous materials, with photoactive Ti-3((3)-O) metal-oxo clusters. By using high-throughput synthetic methodologies, we have confirmed that the formation of this SBU is thermodynamically favored as it is not strictly dependent on the metal precursor of choice and can be regarded as an adequate building block to control the design of new Ti-MOF architectures. We are confident that the addition of a mesoporous solid to the small number of crystalline, porous titanium-frameworks available will be a valuable asset to accelerate the development of new porous photocatalysts without the pore size limitations currently imposed by the microporous materials available. es_ES
dc.description.sponsorship This work was supported by the EU (ERC Stg Chem-fs-MOF 714122) and Spanish MINECO (MDM-2015-0538 & CTQ2017-83486-P). C. M.-G. and J. C.-G. thank the Spanish MINECO for a Ramon y Cajal Fellowship (RYC-2012-10894) and FPI Scholarship (CTQ2014-59209-P). N. M. P. thanks the European Union for a Marie Skodowska-Curie Global Fellowship (H2020-MSCA-IF-2016-GF-749359-EnanSET). We thank the ISIS Facility for the access to synchrotron radiation, BSC-RES and Prof. Enrique Orti for computational resources and Belen Lerma-Berlanga for technical help. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation ERC/ERC Stg Chem-fs-MOF 714122 es_ES
dc.relation.ispartof Chemical Science es_ES
dc.rights Reconocimiento - No comercial (by-nc) es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title De novo synthesis of mesoporous photoactive titanium(iv)-organic frameworks with MIL-100 topology es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c8sc05218b es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/749359/EU/Homogeneous and heterogeneous enantioselective Single Electron Transfer (SET) catalysis in cross-coupling reactions/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-83486-P/ES/REDES METAL-ORGANICAS DE INSPIRACION BIOLOGICA: COMPLEJIDAD QUIMICA EN ENTORNOS DE PORO VERSATILES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2014-59209-P/ES/OLIMEROS DE COORDINACION MAGNETICOS SENSIBLES A ESTIMULOS QUIMICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/714122/Chemical Engineering of Functional Stable Metal-Organic Frameworks: Porous Crystals and Thin Film Devices/chem-fs-MOF/
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MDM-2015-0538/ES/INSTITUTO DE CIENCIA MOLECULAR/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//RYC-2012-10894/ES/RYC-2012-10894/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Castells-Gil, J.; Padial, NM.; Almora-Barrios, N.; Da Silva, I.; Mateo-Mateo, D.; Albero-Sancho, J.; García Gómez, H.... (2019). De novo synthesis of mesoporous photoactive titanium(iv)-organic frameworks with MIL-100 topology. Chemical Science. 10(15):4313-4321. https://doi.org/10.1039/c8sc05218b es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c8sc05218b es_ES
dc.description.upvformatpinicio 4313 es_ES
dc.description.upvformatpfin 4321 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 10 es_ES
dc.description.issue 15 es_ES
dc.identifier.pmid 31057758 es_ES
dc.identifier.pmcid PMC6472189 es_ES
dc.relation.pasarela S\407058 es_ES
dc.contributor.funder European Research Council es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder European Commission
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