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Nanolayered cobalt-molybdenum sulphides (Co-Mo-S) catalyse borrowing hydrogen C-S bond formation reactions of thiols or H2S with alcohols

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Nanolayered cobalt-molybdenum sulphides (Co-Mo-S) catalyse borrowing hydrogen C-S bond formation reactions of thiols or H2S with alcohols

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dc.contributor.author Sorribes-Terrés, Iván es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2020-11-13T04:33:03Z
dc.date.available 2020-11-13T04:33:03Z
dc.date.issued 2019-03-14 es_ES
dc.identifier.issn 2041-6520 es_ES
dc.identifier.uri http://hdl.handle.net/10251/155013
dc.description.abstract [EN] Nanolayered cobalt-molybdenum sulphide (Co-Mo-S) materials have been established as excellent catalysts for C-S bond construction. These catalysts allow for the preparation of a broad range of thioethers in good to excellent yields from structurally diverse thiols and readily available primary as well as secondary alcohols. Chemoselectivity in the presence of sensitive groups such as double bonds, nitriles, carboxylic esters and halogens has been demonstrated. It is also shown that the reaction takes place through a hydrogen-autotransfer (borrowing hydrogen) mechanism that involves Co-Mo-Smediated dehydrogenation and hydrogenation reactions. A novel catalytic protocol based on the thioetherification of alcohols with hydrogen sulphide (H2S) to furnish symmetrical thioethers has also been developed using these earth-abundant metal-based sulphide catalysts. es_ES
dc.description.sponsorship Financial support by the Spanish Government-MINECO through the program "Severo Ochoa" (SEV-2016-0683) is gratefully acknowledged. I. S. also acknowledges the Vice-Rectorate for Research, Innovation and Transfer of the Universitat Politecnica de Valencia (UPV) for a postdoctoral fellowship and the Spanish Government-MINECO for a "Juan de la Cierva-Incorporacion" fellowship. The authors also acknowledge the Microscopy Service of the UPV and Dr Jose Maria Moreno for kind help with TEM and STEM measurements. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Chemical Science es_ES
dc.rights Reconocimiento - No comercial (by-nc) es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.title Nanolayered cobalt-molybdenum sulphides (Co-Mo-S) catalyse borrowing hydrogen C-S bond formation reactions of thiols or H2S with alcohols es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c8sc05782f es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Sorribes-Terrés, I.; Corma Canós, A. (2019). Nanolayered cobalt-molybdenum sulphides (Co-Mo-S) catalyse borrowing hydrogen C-S bond formation reactions of thiols or H2S with alcohols. Chemical Science. 10(10):3130-3142. https://doi.org/10.1039/c8sc05782f es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c8sc05782f es_ES
dc.description.upvformatpinicio 3130 es_ES
dc.description.upvformatpfin 3142 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 10 es_ES
dc.description.issue 10 es_ES
dc.identifier.pmid 30996896 es_ES
dc.identifier.pmcid PMC6429612 es_ES
dc.relation.pasarela S\409955 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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