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Reinventing the De Mayo reaction: synthesis of 1,5-diketones or 1,5-ketoesters via visible light [2+2] cycloaddition of beta-diketones or beta-ketoesters with styrenes

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Reinventing the De Mayo reaction: synthesis of 1,5-diketones or 1,5-ketoesters via visible light [2+2] cycloaddition of beta-diketones or beta-ketoesters with styrenes

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Martínez-Haya, R.; Marzo, L.; König, B. (2018). Reinventing the De Mayo reaction: synthesis of 1,5-diketones or 1,5-ketoesters via visible light [2+2] cycloaddition of beta-diketones or beta-ketoesters with styrenes. Chemical Communications. 54(82):11602-11605. https://doi.org/10.1039/c8cc07044j

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Título: Reinventing the De Mayo reaction: synthesis of 1,5-diketones or 1,5-ketoesters via visible light [2+2] cycloaddition of beta-diketones or beta-ketoesters with styrenes
Autor: Martínez-Haya, Rebeca Marzo, L. König, B.
Fecha difusión:
Resumen:
[EN] A visible light mediated De Mayo reaction between 1,3-diketones and styrenes following a [2+2] cycloaddition pathway via a photosensitization mechanism gives access to 1,5-diketones. The reaction has been applied to ...[+]
Palabras clave: Photoredox catalysis , Organic-Synthesis , Energy-Transfer , Photochemistry , Photocycloaddition , Photophysics , Photocatalysis , Enlargement , Complexes , Chemistry
Derechos de uso: Reserva de todos los derechos
Fuente:
Chemical Communications. (issn: 1359-7345 )
DOI: 10.1039/c8cc07044j
Editorial:
The Royal Society of Chemistry
Versión del editor: https://doi.org/10.1039/c8cc07044j
Código del Proyecto:
info:eu-repo/grantAgreement/DFG//GRK 1626/
Agradecimientos:
This work was supported by the Deutsche Forschungsgemein-schaft DFG (GRK 1626, Chemical Photocatalysis). L. M. thanks the Alexander von Humboldt foundation for a postdoctoral fellowship. R. M.-H. thanks the DAAD for a ...[+]
Tipo: Artículo

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