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Reinventing the De Mayo reaction: synthesis of 1,5-diketones or 1,5-ketoesters via visible light [2+2] cycloaddition of beta-diketones or beta-ketoesters with styrenes

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Reinventing the De Mayo reaction: synthesis of 1,5-diketones or 1,5-ketoesters via visible light [2+2] cycloaddition of beta-diketones or beta-ketoesters with styrenes

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dc.contributor.author Martínez-Haya, Rebeca es_ES
dc.contributor.author Marzo, L. es_ES
dc.contributor.author König, B. es_ES
dc.date.accessioned 2020-11-14T04:32:00Z
dc.date.available 2020-11-14T04:32:00Z
dc.date.issued 2018-10-21 es_ES
dc.identifier.issn 1359-7345 es_ES
dc.identifier.uri http://hdl.handle.net/10251/155064
dc.description.abstract [EN] A visible light mediated De Mayo reaction between 1,3-diketones and styrenes following a [2+2] cycloaddition pathway via a photosensitization mechanism gives access to 1,5-diketones. The reaction has been applied to substituted styrenes and aryl- and alkyl-substituted ketones. Moreover, the method converts -ketoesters, -amido esters, and -cyano ketones. Seven membered rings, a frequent structural motif of natural products, are also accessible using this methodology. es_ES
dc.description.sponsorship This work was supported by the Deutsche Forschungsgemein-schaft DFG (GRK 1626, Chemical Photocatalysis). L. M. thanks the Alexander von Humboldt foundation for a postdoctoral fellowship. R. M.-H. thanks the DAAD for a short-term research grant. We thank Ms Regina Hoheisel (University of Regensburg) for her assistance in cyclic voltammetry measurements. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Chemical Communications es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Photoredox catalysis es_ES
dc.subject Organic-Synthesis es_ES
dc.subject Energy-Transfer es_ES
dc.subject Photochemistry es_ES
dc.subject Photocycloaddition es_ES
dc.subject Photophysics es_ES
dc.subject Photocatalysis es_ES
dc.subject Enlargement es_ES
dc.subject Complexes es_ES
dc.subject Chemistry es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Reinventing the De Mayo reaction: synthesis of 1,5-diketones or 1,5-ketoesters via visible light [2+2] cycloaddition of beta-diketones or beta-ketoesters with styrenes es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c8cc07044j es_ES
dc.relation.projectID info:eu-repo/grantAgreement/DFG//GRK 1626/ es_ES
dc.rights.accessRights Abierto es_ES
dc.description.bibliographicCitation Martínez-Haya, R.; Marzo, L.; König, B. (2018). Reinventing the De Mayo reaction: synthesis of 1,5-diketones or 1,5-ketoesters via visible light [2+2] cycloaddition of beta-diketones or beta-ketoesters with styrenes. Chemical Communications. 54(82):11602-11605. https://doi.org/10.1039/c8cc07044j es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c8cc07044j es_ES
dc.description.upvformatpinicio 11602 es_ES
dc.description.upvformatpfin 11605 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 54 es_ES
dc.description.issue 82 es_ES
dc.identifier.pmid 30264086 es_ES
dc.relation.pasarela S\388462 es_ES
dc.contributor.funder Deutsche Forschungsgemeinschaft es_ES
dc.contributor.funder Alexander von Humboldt Foundation es_ES
dc.contributor.funder Deutscher Akademischer Austauschdienst es_ES
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