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Ice-Templating for the Elaboration of Oxygen Permeation Asymmetric Tubular Membrane with Radial Oriented Porosity

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Ice-Templating for the Elaboration of Oxygen Permeation Asymmetric Tubular Membrane with Radial Oriented Porosity

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dc.contributor.author Gaudillere, Cyril Christian es_ES
dc.contributor.author García-Fayos, Julio es_ES
dc.contributor.author Plaza-Belda, Jorge es_ES
dc.contributor.author Serra Alfaro, José Manuel es_ES
dc.date.accessioned 2020-11-17T04:32:01Z
dc.date.available 2020-11-17T04:32:01Z
dc.date.issued 2019-04-02 es_ES
dc.identifier.uri http://hdl.handle.net/10251/155116
dc.description.abstract [EN] An original asymmetric tubular membrane for oxygen production applications was manufactured in a two-step process. A 3 mol% Y2O3 stabilized ZrO2 (3YSZ) porous tubular support was manufactured by the freeze-casting technique, offering a hierarchical and radial-oriented porosity of about 15 µm in width, separated by fully densified walls of about 2 µm thick, suggesting low pressure drop and boosted gas transport. The external surface of the support was successively dip-coated to get a Ce0.8Gd0.2O2¿¿ ¿ 5mol%Co (CGO-Co) interlayer of 80 µm in thickness and an outer dense layer of La0.6Sr0.4Co0.2Fe0.8O3¿¿ (LSCF) with a thickness of 30 µm. The whole tubular membrane presents both uniform geometric characteristics and microstructure all along its length. Chemical reactivity between each layer was studied by coupling X-Ray Diffraction (XRD) analysis and Energy Dispersive X-Ray spectroscopy (EDX) mapping at each step of the manufacturing process. Cation interdiffusion between different phases was discarded, confirming the compatibility of this tri-layer asymmetric ceramic membrane for oxygen production purposes. For the first time, a freeze-cast tubular membrane has been evaluated for oxygen permeation, exhibiting a value of 0.31 mL·min¿1·cm¿2 at 1000 °C under air and argon as feed and sweep gases, respectively. Finally, under the same conditions and increasing the oxygen partial pressure to get pure oxygen as feed, the oxygen permeation reached 1.07 mL·min¿1·cm¿2. es_ES
dc.description.sponsorship Funding from the Spanish Government (ENE2014-57651 and SEV-2016-0683 grants) is kindly acknowledged. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Ceramics es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Ice templating es_ES
dc.subject Freeze-casting es_ES
dc.subject Tubular asymmetric membrane es_ES
dc.subject Oxygen permeation es_ES
dc.subject Perovskite material es_ES
dc.title Ice-Templating for the Elaboration of Oxygen Permeation Asymmetric Tubular Membrane with Radial Oriented Porosity es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/ceramics2020020 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//ENE2014-57651-R/ES/ALMACENAMIENTO DE ENERGIA VIA REDUCCION DE CO2 A COMBUSTIBLES Y PRODUCTOS QUIMICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Gaudillere, CC.; García-Fayos, J.; Plaza-Belda, J.; Serra Alfaro, JM. (2019). Ice-Templating for the Elaboration of Oxygen Permeation Asymmetric Tubular Membrane with Radial Oriented Porosity. Ceramics. 2(2):246-259. https://doi.org/10.3390/ceramics2020020 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/ceramics2020020 es_ES
dc.description.upvformatpinicio 246 es_ES
dc.description.upvformatpfin 259 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 2 es_ES
dc.description.issue 2 es_ES
dc.identifier.eissn 2571-6131 es_ES
dc.relation.pasarela S\389205 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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