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Perylene-Grafted Silicas: Mechanistic Study and Applications in Heterogeneous Photoredox Catalysis

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Perylene-Grafted Silicas: Mechanistic Study and Applications in Heterogeneous Photoredox Catalysis

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dc.contributor.author Carrillo, Adela I. es_ES
dc.contributor.author Elhage, Ayda es_ES
dc.contributor.author Marín García, Mª Luisa es_ES
dc.contributor.author Lanterna, Anabel E. es_ES
dc.date.accessioned 2020-11-18T04:31:46Z
dc.date.available 2020-11-18T04:31:46Z
dc.date.issued 2019-11-22 es_ES
dc.identifier.issn 0947-6539 es_ES
dc.identifier.uri http://hdl.handle.net/10251/155244
dc.description This is the peer reviewed version of the following article: Chem. Eur. J. 2019, 25, 14928 14934, which has been published in final form at https://doi.org/10.1002/chem.201903539. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving es_ES
dc.description.abstract [EN] A mechanistic study is herein presented for the use of heterogeneous photocatalysts based on perylene moieties. First, the successful immobilization of perylene diimides (PDI) on silica matrices is demonstrated, including their full characterization by means of electronic microscopy, surface area measurements, powder XRD, thermogravimetric analysis, and FTIR, Si-29 and C-13 solid-state NMR, fluorescence, and diffuse reflectance spectroscopies. Then, the photoredox activity of the material was tested by using two model reactions, alkene oxidation and 4-nitrobenzylbromide reduction, and mechanistic studies were performed. The mechanistic insights into their photoredox activity show they have promising dual photocatalytic activity for both organic oxidations and reductions. es_ES
dc.description.sponsorship This work was supported by the Natural Sciences and Engineering Research Council of Canada and the Canada Foundation for Innovation. The authors are grateful to Prof. J.C. Scaiano for his generous support. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Chemistry - A European Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject MCM-41 es_ES
dc.subject Photoredox catalysis es_ES
dc.subject Reaction mechanisms es_ES
dc.subject SBA-15 es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Perylene-Grafted Silicas: Mechanistic Study and Applications in Heterogeneous Photoredox Catalysis es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/chem.201903539 es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Carrillo, AI.; Elhage, A.; Marín García, ML.; Lanterna, AE. (2019). Perylene-Grafted Silicas: Mechanistic Study and Applications in Heterogeneous Photoredox Catalysis. Chemistry - A European Journal. 25(65):14928-14934. https://doi.org/10.1002/chem.201903539 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/chem.201903539 es_ES
dc.description.upvformatpinicio 14928 es_ES
dc.description.upvformatpfin 14934 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 25 es_ES
dc.description.issue 65 es_ES
dc.identifier.pmid 31532564 es_ES
dc.relation.pasarela S\404249 es_ES
dc.contributor.funder Canada Foundation for Innovation es_ES
dc.contributor.funder Natural Sciences and Engineering Research Council of Canada es_ES
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