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A highly conductive nanostructured PEDOT polymer confined into the mesoporous MIL-100(Fe)

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A highly conductive nanostructured PEDOT polymer confined into the mesoporous MIL-100(Fe)

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dc.contributor.author Salcedo-Abraira, Pablo es_ES
dc.contributor.author Santiago-Portillo, Andrea es_ES
dc.contributor.author Atienzar Corvillo, Pedro Enrique es_ES
dc.contributor.author Bordet, Pierre es_ES
dc.contributor.author Salles, Fabrice es_ES
dc.contributor.author Guillou, Nathalie es_ES
dc.contributor.author Elkaim, Erik es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.contributor.author Navalón Oltra, Sergio es_ES
dc.contributor.author Horcajada, Patricia es_ES
dc.date.accessioned 2020-11-24T04:32:06Z
dc.date.available 2020-11-24T04:32:06Z
dc.date.issued 2019-07-14 es_ES
dc.identifier.issn 1477-9226 es_ES
dc.identifier.uri http://hdl.handle.net/10251/155507
dc.description.abstract [EN] Despite the higher efficiency, larger color range and faster stimulus response of polymeric electrochromic materials, their poor cyclability strongly hampers their application in optoelectronics. As an original strategy to stabilize and further nanostructure these polymers, herein an efficient encapsulation and in situ polymerization inside highly porous metal-organic frameworks (MOFs) is reported. In particular, the successful accommodation of poly(3,4-ethylendioxythiophene) (PEDOT) and its partially oxidized polarons inside the mesopores of the nontoxic iron trimesate MIL-100(Fe) is convincingly proved by a large panel of experimental techniques. Remarkably, the polymer-MOF interaction occurring for entrapped PEDOT within the pores (deeply assessed by experimental and simulation methods) might be responsible for the enhanced electrical conductivity of the resulting PEDOT@MIL-100(Fe) composite when compared to the insulating MIL-100(Fe) and the conductive free PEDOT. Furthermore, it was possible to observe the electrochromic properties of the PEDOT@MIL-100(Fe) composite, achieving an improved stability and good cyclability as a consequence of the effective protection by the MOF matrix. es_ES
dc.description.sponsorship This work was supported by a 2017 Leonardo Grant for Researchers and Cultural Creators, BBVA Foundation (IN[17]_CBB_QUI_0197). The work was also partially supported by IMDEA Energy and Raphuel project (ENE2016-79608-C2-1-R, MINECOAEI/FEDER, UE). PH acknowledges the Spanish Ramon y Cajal Programme (grant agreement no. 2014-16823). S. N. thanks the Spanish Ministerio de Educacion, Cultura y Deporte for Jose Castillejo mobility programme (CAS14/00067) and financial support by Fundacion Ramon Areces (XVIII Concurso Nacional para la Adjudicacion de Ayudas a la Investigacion en Ciencias de la Vida y de la Materia, 2016). We also thank the synchrotron Soleil for providing access to the Cristal beamline. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Dalton Transactions es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title A highly conductive nanostructured PEDOT polymer confined into the mesoporous MIL-100(Fe) es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c9dt00917e es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MECD//CAS14%2F00067/ES/CAS14%2F00067/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/fBBVA//IN[17]_CBB_QUI_0197/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//ENE2016-79608-C2-1-R/ES/FOTOCONVERSION DE CO2 A COMBUSTIBLES SOLARES UTILIZADO MATERIALES MULTIFUNCIONALES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//RYC-2014-16823/ES/RYC-2014-16823/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Salcedo-Abraira, P.; Santiago-Portillo, A.; Atienzar Corvillo, PE.; Bordet, P.; Salles, F.; Guillou, N.; Elkaim, E.... (2019). A highly conductive nanostructured PEDOT polymer confined into the mesoporous MIL-100(Fe). Dalton Transactions. 48(26):9807-9817. https://doi.org/10.1039/c9dt00917e es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c9dt00917e es_ES
dc.description.upvformatpinicio 9807 es_ES
dc.description.upvformatpfin 9817 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 48 es_ES
dc.description.issue 26 es_ES
dc.identifier.pmid 31089630 es_ES
dc.relation.pasarela S\407138 es_ES
dc.contributor.funder Fundación BBVA es_ES
dc.contributor.funder Fundación Ramón Areces es_ES
dc.contributor.funder Fundación IMDEA Energía es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Ministerio de Educación, Cultura y Deporte es_ES
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