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Influence of Carbon Supports on Palladium Nanoparticle Activity toward Hydrodeoxygenation and Aerobic Oxidation in Biomass Transformations

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Influence of Carbon Supports on Palladium Nanoparticle Activity toward Hydrodeoxygenation and Aerobic Oxidation in Biomass Transformations

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dc.contributor.author Espinosa-López, Juan Carlos es_ES
dc.contributor.author Castro Contreras, Rubén es_ES
dc.contributor.author Navalón Oltra, Sergio es_ES
dc.contributor.author Rivera-Cárcamo, Camila es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author Machado, Bruno F. es_ES
dc.contributor.author Serp, Philippe es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2020-12-04T04:31:29Z
dc.date.available 2020-12-04T04:31:29Z
dc.date.issued 2019-04-16 es_ES
dc.identifier.issn 1434-1948 es_ES
dc.identifier.uri http://hdl.handle.net/10251/156414
dc.description.abstract [EN] Three palladium catalysts at similar loadings supported on few-layers graphene (FLG), carbon nanotubes (CNT) and carbon nanofibers (CNF) have been prepared by wet impregnation of palladium nitrate with the purpose of determine the influence of the support on Pd catalytic activity. The supports and catalysts have been characterized by chemical analysis, Raman spectroscopy, XRD, electron microscopy and XPS. The average Pd particle size depends on the carbon support, ranging from 1.6 nm for CNF to 2.6 nm for FLG. The catalytic activity of these catalysts was evaluated for two different reactions of interest for biomass transformations, namely hydrodeoxygenation of vanillin to 2-methoxy-4-methyl-phenol (creosol) that requires a bifunctional catalyst with hydrogenating and Lewis acid sites, and aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid. Both compounds have application either as food flavouring additive and polyester co-monomer. For the two reactions the activity order of the fresh catalyst was Pd/FLG > Pd/CNF > Pd/CNT, indicating that FLG contributes favorably to the activity in spite of the larger Pd size of the nanoparticles on this support, a fact that has been attributed to the interaction with the prismatic planes on where Pd nanoparticles are located. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa GTQ2015-65163-C02-R1 and CTQ2014-53292-R) is gratefully acknowledged. Generalidad Valenciana is also thanked for funding (Prometeo 2017/063). S. N. thanks financial support by the Fundacion Ramon Areces (XVIII Concurso Nacional para la Adjudicacion de Ayudas a la Investigacion en Ciencias de la Vida y de la Materia, 2016). C. R. C. thanks CONICYT for the financial support (Becas de doctorado en el extranjero "Becas Chile" - no 72170200). The authors thank Dr. Tobias Placke (Universitat Munster, Germany) for nitrogen adsorption measurements and adsorptive potential distributions calculations. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof European Journal of Inorganic Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Palladium nanoparticles es_ES
dc.subject Carbon support es_ES
dc.subject Biomass transformation es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Influence of Carbon Supports on Palladium Nanoparticle Activity toward Hydrodeoxygenation and Aerobic Oxidation in Biomass Transformations es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/ejic.201900190 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2017%2F063/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CONICYT//72170200/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2014-53292-R/ES/MATERIALES GRAFENICOS COMO CATALIZADORES PARA REACCIONES ORGANICAS./ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-69153-C2-1-R/ES/EXPLOTANDO EL USO DEL GRAFENO EN CATALISIS. USO DEL GRAFENO COMO CARBOCATALIZADOR O COMO SOPORTE/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología Eléctrica - Institut de Tecnologia Elèctrica es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Espinosa-López, JC.; Castro Contreras, R.; Navalón Oltra, S.; Rivera-Cárcamo, C.; Alvaro Rodríguez, MM.; Machado, BF.; Serp, P.... (2019). Influence of Carbon Supports on Palladium Nanoparticle Activity toward Hydrodeoxygenation and Aerobic Oxidation in Biomass Transformations. European Journal of Inorganic Chemistry. (14):1979-1987. https://doi.org/10.1002/ejic.201900190 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/ejic.201900190 es_ES
dc.description.upvformatpinicio 1979 es_ES
dc.description.upvformatpfin 1987 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.issue 14 es_ES
dc.relation.pasarela S\405136 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Fundación Ramón Areces es_ES
dc.contributor.funder Comisión Nacional de Investigación Científica y Tecnológica, Chile es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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