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Tuning zirconia-supported metal catalysts for selective one-step hydrogenation of levoglucosenone

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Tuning zirconia-supported metal catalysts for selective one-step hydrogenation of levoglucosenone

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dc.contributor.author Mazarío-Santa-Pau, Jaime es_ES
dc.contributor.author Parreño-Romero, Miriam es_ES
dc.contributor.author Concepción Heydorn, Patricia es_ES
dc.contributor.author Chávez-Sifontes, Marvin es_ES
dc.contributor.author Spanevello, Rolando A. es_ES
dc.contributor.author Comba, María B. es_ES
dc.contributor.author Suárez, Alejandra G. es_ES
dc.contributor.author Domine, Marcelo Eduardo es_ES
dc.date.accessioned 2020-12-10T04:31:52Z
dc.date.available 2020-12-10T04:31:52Z
dc.date.issued 2019-09-07 es_ES
dc.identifier.issn 1463-9262 es_ES
dc.identifier.uri http://hdl.handle.net/10251/156660
dc.description.abstract [EN] Levoglucosenone, directly produced from cellulose-containing residual biomass via pyrolysis treatments, is believed to be a promising bio-renewable platform for both fine and commodity chemicals. In this work, the possibilities given by tuneable catalysts based on Pd and Pt supported on metallic oxides to produce the desired product in the one-pot hydrogenation of levoglucosenone are evaluated. Particularly, the excellent catalytic performance of Pd/ZrO2 and Pt/ZrO2 type materials for the synthesis of dihydrolevoglucosenone (or Cyrene) and levoglucosanol, respectively, during the mild hydrogenation of levoglucosenone is demonstrated. In the Cyrene synthesis, the Pd/t-ZrO2 material showed the best catalytic activity compared to other Pd-supported on metallic oxides. This catalyst achieved nearly 95% yields of Cyrene by working under mild reaction conditions, with very low catalyst loadings (¿3 wt%) and using water as the solvent. On the other hand, the one-pot hydrogenation of levoglucosenone to levoglucosanol is reported for the first time with a Pt-based heterogeneous catalyst (Pt/ZrO2-mix, yield ¿90%), by working at low temperatures and mild H2 pressures with water as the solvent. Comparison of the results attained with other Pt-supported metallic oxides let us to conclude that the metal crystal facets (specifically the 100 facet) play an important role in the hydrogenation process to give levoglucosanol selectively. In addition, the stability and re-usability of both catalysts under operational conditions are also evaluated. Finally, catalytic tests including the use of crude bio-liquids obtained from cellulose-rich biomass pyrolysis and containing ¿66 wt% of levoglucosenone are also assayed, thus demonstrating the possibility of scaling-up the process over these metals supported on zirconia catalysts. es_ES
dc.description.sponsorship Financial support by the Spanish Government (CTQ-201567592, SEV-2016-0683 and PGC2018-097277-B-100) is gratefully acknowledged. R.S. thanks the CONICET financial support (CONICET-CSIC, PVCE Program, RD 4183/15). J.M. thanks MICINN (CTQ2015-67592) for the PhD fellowship. Authors also thank the Electron Microscopy Service of Universitat Politecnica de Valencia for their support. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Green Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.title Tuning zirconia-supported metal catalysts for selective one-step hydrogenation of levoglucosenone es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c9gc01857c es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CONICET//RD 4183%2F15/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-67592-P/ES/VALORIZACION DE COMPUESTO OXIGENADOS PRESENTES EN FRACCIONES ACUOSAS DERIVADAS DE BIOMASA EN COMBUSTIBLES Y PRODUCTOS QUIMICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-097277-B-I00/ES/MEJORA DEL CONCEPTO DE BIORREFINERIA MEDIANTE IMPLEMENTACION DE NUEVOS PROCESOS CATALITICOS CON CATALIZADORES SOLIDOS DE METALES NO NOBLES PARA LA PRODUCCION DE BIOCOMPUESTOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Mazarío-Santa-Pau, J.; Parreño-Romero, M.; Concepción Heydorn, P.; Chávez-Sifontes, M.; Spanevello, RA.; Comba, MB.; Suárez, AG.... (2019). Tuning zirconia-supported metal catalysts for selective one-step hydrogenation of levoglucosenone. Green Chemistry. 21(17):4769-4785. https://doi.org/10.1039/c9gc01857c es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c9gc01857c es_ES
dc.description.upvformatpinicio 4769 es_ES
dc.description.upvformatpfin 4785 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 21 es_ES
dc.description.issue 17 es_ES
dc.relation.pasarela S\409696 es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Consejo Nacional de Investigaciones Científicas y Técnicas, Argentina es_ES
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dc.subject.ods 13.- Tomar medidas urgentes para combatir el cambio climático y sus efectos es_ES
dc.subject.ods 12.- Garantizar las pautas de consumo y de producción sostenibles es_ES


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