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Exploring the catalytic performance of a series of bimetallic MIL-100(Fe, Ni) MOFs

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Exploring the catalytic performance of a series of bimetallic MIL-100(Fe, Ni) MOFs

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dc.contributor.author Giménez-Marqués, Mónica es_ES
dc.contributor.author Santiago-Portillo, Andrea es_ES
dc.contributor.author Navalón Oltra, Sergio es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author Briois, Valérie es_ES
dc.contributor.author Nouar, Farid es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.contributor.author Serre, Christian es_ES
dc.date.accessioned 2021-01-12T21:03:22Z
dc.date.available 2021-01-12T21:03:22Z
dc.date.issued 2019-09-21 es_ES
dc.identifier.issn 2050-7488 es_ES
dc.identifier.uri http://hdl.handle.net/10251/158854
dc.description.abstract [EN] A series of mixed-metal Fe-III/Ni-II metal-organic frameworks (MOFs) of the MIL-100 type containing different metal ratios have been synthesized de novo, following an approach that requires tuning of the Fe-III/Ni-II reactivity. The resulting heterometallic MIL-100(Fe, Ni) materials maintain thermal, chemical and structural stability with respect to the parent MIL-100(Fe) MOF as can be deduced from various techniques. The nature and the oxidation state of the accessible metal cations have been evaluated by in situ infrared spectroscopy and extended X-ray absorption fine structure measurements. The obtained mixed-metal MOFs and the parent material have been evaluated as heterogeneous catalysts in a model acid-catalyzed reaction, i.e., the Prins reaction. It is found that the catalytic activity improves by more than one order of magnitude upon incorporation of Ni-II, with a complete selectivity for the formation of nopol. This increase in the catalytic activity upon incorporation of Ni-II correlates with the enhancement in the Lewis acidity of the material as determined by CO adsorption. The heterometallic MOF can be recycled without observation of metal leaching, while maintaining the crystal structure under the reaction conditions. es_ES
dc.description.sponsorship This work was supported by the European Commission under the Marie Sklodowska-Curie agreement H2020-MSCA-IF-658224. Measurements at the ROCK synchrotron beamline of SOLEIL were supported by a public grant overseen by the French National Research Agency (ANR) as part of the "Investissements d'Avenir" program (reference: ANR10-EQPX45). H. G. thanks financial support by the Spanish Ministry of Science and Innovation (Severo Ochoa and RTI2018-098237-CO21) and Generalitat Valenciana (Prometeo 2017/083). S. N. thanks financial support by the Fundacion Ramon Areces (XVIII Concurso Nacional para la Adjudicacion de Ayudas a la Investigacion en Ciencias de la Vida y de la Materia, 2016) and Ministerio de Ciencia, Innovacion y Universidades CTQ-2018 RTI2018-099482-A-I00 project. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Journal of Materials Chemistry A es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Metalorganic frameworks (MOFs) es_ES
dc.subject Heterogeneous catalyst es_ES
dc.subject Acid-catalyzed reactions es_ES
dc.subject Catalyst activity es_ES
dc.subject Extended X ray absorption fine structure spectroscopy es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Exploring the catalytic performance of a series of bimetallic MIL-100(Fe, Ni) MOFs es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c9ta01948k es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/658224/EU/Rational design of novel heterometallic MOFs for their use in heterogeneous catalysis for cascade reactions/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-098237-B-C21/ES/HETEROUNIONES DE GRAFENO CON CONFIGURACION CONTROLADA. SINTESIS Y APLICACIONES COMO SOPORTE EN CATALISIS Y EN ELECTRODOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/ANR//ANR-10-EQPX-0045/FR/Spectromètre EXAFS Rapide pour Cinétiques Chimiques/ROCK/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Giménez-Marqués, M.; Santiago-Portillo, A.; Navalón Oltra, S.; Alvaro Rodríguez, MM.; Briois, V.; Nouar, F.; García Gómez, H.... (2019). Exploring the catalytic performance of a series of bimetallic MIL-100(Fe, Ni) MOFs. Journal of Materials Chemistry A. 7(35):20285-20292. https://doi.org/10.1039/c9ta01948k es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c9ta01948k es_ES
dc.description.upvformatpinicio 20285 es_ES
dc.description.upvformatpfin 20292 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 7 es_ES
dc.description.issue 35 es_ES
dc.relation.pasarela S\404895 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Fundación Ramón Areces es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Agence Nationale de la Recherche, Francia es_ES
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