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Metal organic frameworks as solid catalysts for liquid-phase continuous flow reactions

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Metal organic frameworks as solid catalysts for liquid-phase continuous flow reactions

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dc.contributor.author Dhakshinamoorthy, Amarajothi es_ES
dc.contributor.author Navalón Oltra, Sergio es_ES
dc.contributor.author Asiri, Abdullah M. es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2021-01-14T04:33:01Z
dc.date.available 2021-01-14T04:33:01Z
dc.date.issued 2020-01-04 es_ES
dc.identifier.issn 1359-7345 es_ES
dc.identifier.uri http://hdl.handle.net/10251/158949
dc.description.abstract [EN] Metal organic frameworks (MOFs) are widely used as solid catalysts in the liquid phase under batch mode conditions. Moving towards the development of industrial processes, data of the performance of MOFs under continuous flow operation would be desirable. This feature article describes the state of the art regarding the use of MOFs as catalysts of continuous flow processes, paying special attention to the issue of catalyst stability. The review is organized according to the type of bond that is formed in the reaction from C-C, to C-O to C-N bonds. Examples are presented of MOF catalysts that are stable under continuous flow operation, even for those structures that are not very stable such as Cu-3(BTC)(2). It can be anticipated that there will be a growth in the percentage of studies carried out under continuous flow with the final goal of implementing a commercial chemical process using MOFs as a catalyst. es_ES
dc.description.sponsorship A. D. thanks the University Grants Commission, New Delhi, for the award of an Assistant Professorship under its Faculty Recharge Programme. A. D. also thanks the Department of Science and Technology, India, for the financial support through Extramural Research Funding (EMR/2016/006500). Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and RTI2018-890237-CO2-R1) and Generalitat Valenciana (Prometeo 2017-083) is gratefully acknowledged. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation MINECO/RTI2018-890237-CO2-R1 es_ES
dc.relation.ispartof Chemical Communications es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Metal organic frameworks as solid catalysts for liquid-phase continuous flow reactions es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c9cc07953j es_ES
dc.relation.projectID info:eu-repo/grantAgreement/DST//EMR%2F2016%2F006500/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2017%2F083/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Dhakshinamoorthy, A.; Navalón Oltra, S.; Asiri, AM.; García Gómez, H. (2020). Metal organic frameworks as solid catalysts for liquid-phase continuous flow reactions. Chemical Communications. 56(1):26-45. https://doi.org/10.1039/c9cc07953j es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c9cc07953j es_ES
dc.description.upvformatpinicio 26 es_ES
dc.description.upvformatpfin 45 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 56 es_ES
dc.description.issue 1 es_ES
dc.identifier.pmid 31782441 es_ES
dc.relation.pasarela S\407315 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder University Grants Commission, India es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Department of Science and Technology, Ministry of Science and Technology, India es_ES
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