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Expandable Layered Hybrid Materials Based on Individual 1D Metalorganic Nanoribbons

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Expandable Layered Hybrid Materials Based on Individual 1D Metalorganic Nanoribbons

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dc.contributor.author Moreno-Rodríguez, José María es_ES
dc.contributor.author Velty, Alexandra es_ES
dc.contributor.author DÍAZ MORALES, URBANO MANUEL es_ES
dc.date.accessioned 2021-01-16T04:31:41Z
dc.date.available 2021-01-16T04:31:41Z
dc.date.issued 2019-06-02 es_ES
dc.identifier.uri http://hdl.handle.net/10251/159196
dc.description.abstract [EN] Different metalorganic lamellar hybrid materials based on associated nanoribbons were synthesized by the use of alkyl-benzyl monocarboxylate spacers, containing alkyl tails with variable lengths, which acted like structural growing inhibitors. These molecular agents were perpendicularly located and coordinated to aluminium nodes in the interlayer space, controlling the separation between individual structure sub-units. The hybrid materials were studied by X-ray diffraction (XRD), chemical and thermogravimetrical analysis (TGA), nuclear magnetic resonance (NMR) and infrared spectroscopy (IR), and field emission scanning electron microscopy (FESEM)/transmission electron microscopy (TEM), showing their physicochemical properties. The specific capacity of the metalorganic materials to be exfoliated through post-synthesis treatments, using several solvents due to the presence of 1D structure sub-units and a marked hydrophobic nature, was also evidenced. es_ES
dc.description.sponsorship The authors are grateful for financial support from the Spanish Government by MAT2017-82288-C2-1-P and Severo Ochoa Excellence Program SEV-2016-0683. J. M. M. acknowledges Predoctoral Fellowships from MINECO for economical support. The authors thank the MULTY2HYCAT EU-Horizon 2020 funded project under grant agreement no.720783. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Materials es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject MOFs es_ES
dc.subject Layered materials es_ES
dc.subject Hybrids es_ES
dc.subject Monocarboxylate spacers es_ES
dc.subject Growing inhibitors es_ES
dc.subject Exfoliation es_ES
dc.title Expandable Layered Hybrid Materials Based on Individual 1D Metalorganic Nanoribbons es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/ma12121953 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/720783/EU/MULTI-site organic-inorganic HYbrid CATalysts for MULTI-step chemical processes/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-82288-C2-1-P/ES/MATERIALES HIBRIDOS MULTIFUNCIONALES BASADOS EN NANO-UNIDADES ESTRUCTURALES ACTIVAS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Moreno-Rodríguez, JM.; Velty, A.; Díaz Morales, UM. (2019). Expandable Layered Hybrid Materials Based on Individual 1D Metalorganic Nanoribbons. Materials. 12(12):1-13. https://doi.org/10.3390/ma12121953 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/ma12121953 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 13 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 12 es_ES
dc.description.issue 12 es_ES
dc.identifier.eissn 1996-1944 es_ES
dc.identifier.pmid 31213003 es_ES
dc.identifier.pmcid PMC6631333 es_ES
dc.relation.pasarela S\407673 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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