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Optimization of the Loading of an Environmentally Friendly Compatibilizer Derived from Linseed Oil in Poly(Lactic Acid)/Diatomaceous Earth Composites

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Optimization of the Loading of an Environmentally Friendly Compatibilizer Derived from Linseed Oil in Poly(Lactic Acid)/Diatomaceous Earth Composites

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dc.contributor.author Gonzalez, Lucia es_ES
dc.contributor.author Agüero, Ángel es_ES
dc.contributor.author Quiles-Carrillo, Luis es_ES
dc.contributor.author Lascano-Aimacaña, Diego Sebastián es_ES
dc.contributor.author Montanes, Nestor es_ES
dc.date.accessioned 2021-01-16T04:31:58Z
dc.date.available 2021-01-16T04:31:58Z
dc.date.issued 2019-05-02 es_ES
dc.identifier.uri http://hdl.handle.net/10251/159203
dc.description.abstract [EN] Maleinized linseed oil (MLO) has been successfully used as biobased compatibilizer in polyester blends. Its effciency as compatibilizer in polymer composites with organic and inorganic fillers, compared to other traditional fillers, has also been proved. The goal of this work is to optimize the amount of MLO on poly(lactic acid)/diatomaceous earth (PLA/DE) composites to open new potential to these materials in the active packaging industry without compromising the environmental effciency of these composites. The amount of DE remains constant at 10 wt% and MLO varies from 1 to 15 phr (weight parts of MLO per 100 g of PLA/DE composite). The e ect of MLO on mechanical, thermal, thermomechanical and morphological properties is described in this work. The obtained results show a clear embrittlement of the uncompatibilized PLA/DE composites, which is progressively reduced by the addition of MLO. MLO shows good miscibility at low concentrations (lower than 5 phr) while above 5 phr, a clear phase separation phenomenon can be detected, with the formation of rounded microvoids and shapes which have a positive e ect on impact strength. es_ES
dc.description.sponsorship This research was funded by the Ministry of Science, Innovation, and Universities (MICIU) project number MAT2017-84909-C2-2-R. L. Quiles-Carrillo is recipient of a FPU grant (FPU15/03812) from the Spanish Ministry of Education, Culture, and Sports (MECD). D. Lascano acknowledges UPV for the grant received though the PAID-01-18 program. N. Montanes acknowledges the project "Development and production of new material from revalued industrial wastes for technological sector applications" for partially funding this research. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Materials es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Maleinized linseed oil MLO es_ES
dc.subject Poly(lactic acid) es_ES
dc.subject Diatomaceous earth es_ES
dc.subject Biocomposites es_ES
dc.subject Active containers es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Optimization of the Loading of an Environmentally Friendly Compatibilizer Derived from Linseed Oil in Poly(Lactic Acid)/Diatomaceous Earth Composites es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/ma12101627 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UPV//PAID-01-18/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84909-C2-2-R/ES/PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MECD//FPU15%2F03812/ES/FPU15%2F03812/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.description.bibliographicCitation Gonzalez, L.; Agüero, Á.; Quiles-Carrillo, L.; Lascano-Aimacaña, DS.; Montanes, N. (2019). Optimization of the Loading of an Environmentally Friendly Compatibilizer Derived from Linseed Oil in Poly(Lactic Acid)/Diatomaceous Earth Composites. Materials. 12(10):1-15. https://doi.org/10.3390/ma12101627 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/ma12101627 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 15 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 12 es_ES
dc.description.issue 10 es_ES
dc.identifier.eissn 1996-1944 es_ES
dc.identifier.pmid 31108954 es_ES
dc.identifier.pmcid PMC6566712 es_ES
dc.relation.pasarela S\388021 es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
dc.contributor.funder Ministerio de Educación, Cultura y Deporte es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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