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Graphene-Based Materials as Efficient Photocatalysts for Water Splitting

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Graphene-Based Materials as Efficient Photocatalysts for Water Splitting

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dc.contributor.author Albero-Sancho, Josep es_ES
dc.contributor.author Mateo-Mateo, Diego es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2021-01-20T04:31:35Z
dc.date.available 2021-01-20T04:31:35Z
dc.date.issued 2019-03-01 es_ES
dc.identifier.issn 1420-3049 es_ES
dc.identifier.uri http://hdl.handle.net/10251/159515
dc.description.abstract [EN] Photocatalysis has been proposed as one of the most promising approaches for solar fuel production. Among the photocatalysts studied for water splitting, graphene and related materials have recently emerged as attractive candidates due to their striking properties and sustainable production when obtained from biomass wastes. In most of the cases reported so far, graphene has been typically used as additive to enhance its photocatalytic activity of semiconductor materials as consequence of the improved charge separation and visible light harvesting. However, graphene-based materials have demonstrated also intrinsic photocatalytic activity towards solar fuels production, and more specifically for water splitting. The photocatalytic activity of graphene derives from defects generated during synthesis or their introduction through post-synthetic treatments. In this short review, we aim to summarize the most representative examples of graphene based photocatalysts and the different approaches carried out in order to improve the photocatalytic activity towards water splitting. It will be presented that the introduction of defects in the graphenic lattice as well as the incorporation of small amounts of metal or metal oxide nanoparticles on the graphene surface improve the photocatalytic activity of graphene. What is more, a simple one-step preparation method has demonstrated to provide crystal orientation to the nanoparticles strongly grafted on graphene resulting in remarkable photocatalytic properties. These two features, crystal orientation and strong grafting, have been identified as a general methodology to further enhance the photocatalytic activity in graphenebased materials for water splitting. Finally, future prospects in this filed will be also commented. es_ES
dc.description.sponsorship This research was funded by the Spanish Ministry of Economy and Competitiveness, grant numbers SEV2016-0683 and CTQ2015-69563-CO2-1, and by Generalitat Valenciana, grant number Prometeo 2017-083. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation MINECO/CTQ2015-69563-CO2-1 es_ES
dc.relation.ispartof Molecules es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Defective graphene es_ES
dc.subject Photocatalysis es_ES
dc.subject Solar fuels es_ES
dc.subject Hydrogen generation es_ES
dc.subject Facet-oriented nanoparticles es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Graphene-Based Materials as Efficient Photocatalysts for Water Splitting es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/molecules24050906 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2017%2F083/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Albero-Sancho, J.; Mateo-Mateo, D.; García Gómez, H. (2019). Graphene-Based Materials as Efficient Photocatalysts for Water Splitting. Molecules. 24(5):1-21. https://doi.org/10.3390/molecules24050906 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/molecules24050906 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 21 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 24 es_ES
dc.description.issue 5 es_ES
dc.identifier.pmid 30841539 es_ES
dc.identifier.pmcid PMC6429481 es_ES
dc.relation.pasarela S\407304 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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