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Regioselective generation and reactivity control of subnanometric platinum clusters in zeolites for high-temperature catalysis

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Regioselective generation and reactivity control of subnanometric platinum clusters in zeolites for high-temperature catalysis

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Liu, L.; Lopez-Haro, M.; Lopes, CW.; Li, C.; Concepción Heydorn, P.; Simonelli, L.; Calvino, JJ.... (2019). Regioselective generation and reactivity control of subnanometric platinum clusters in zeolites for high-temperature catalysis. Nature Materials. 18(8):866-875. https://doi.org/10.1038/s41563-019-0412-6

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/159599

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Title: Regioselective generation and reactivity control of subnanometric platinum clusters in zeolites for high-temperature catalysis
Author: Liu, Lichen Lopez-Haro, Miguel Lopes, Christian W. Li, Chengeng Concepción Heydorn, Patricia Simonelli, Laura Calvino, Jose J. Corma Canós, Avelino
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
[EN] Subnanometric metal species (single atoms and clusters) have been demonstrated to be unique compared with their nanoparticulate counterparts. However, the poor stabilization of subnanometric metal species towards ...[+]
Copyrigths: Reserva de todos los derechos
Source:
Nature Materials. (issn: 1476-1122 )
DOI: 10.1038/s41563-019-0412-6
Publisher:
Nature Publishing Group
Publisher version: https://doi.org/10.1038/s41563-019-0412-6
Project ID:
info:eu-repo/grantAgreement/CAPES//13191%2F13-6/
info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/
info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-87579-R/ES/FASES 2D ULTRAFINAS SOBRE OXIDOS CON MORFOLOGIA CONTROLADA: PLATAFORMA DE NANOCATALIZADORES MULTICOMPONENTE CON APLICACIONES EN PROTECCION DEL MEDIO AMBIENTE/
info:eu-repo/grantAgreement/MINECO//MAT2016-81118-P/ES/DISEÑO Y CARACTERIZACION AVANZADA DE CATALIZADORES CON NANOINTERFASES MODELO AU%2F%2FCEO2/
Thanks:
This work has been supported by the European Union through the European Research Council (grant ERC-AdG-2014-671093, SynCatMatch) and the Spanish government through the Severo Ochoa Programme (SEV-2016-0683). L.L. thanks ...[+]
Type: Artículo

References

Liu, L. & Corma, A. Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles. Chem. Rev. 118, 4981–5079 (2018).

Gallego, E. M. et al. “Ab initio” synthesis of zeolites for preestablished catalytic reactions. Science 355, 1051–1054 (2017).

Kosinov, N., Liu, C., Hensen, E. J. M. & Pidko, E. A. Engineering of transition metal catalysts confined in zeolites. Chem. Mater. 30, 3177–3198 (2018). [+]
Liu, L. & Corma, A. Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles. Chem. Rev. 118, 4981–5079 (2018).

Gallego, E. M. et al. “Ab initio” synthesis of zeolites for preestablished catalytic reactions. Science 355, 1051–1054 (2017).

Kosinov, N., Liu, C., Hensen, E. J. M. & Pidko, E. A. Engineering of transition metal catalysts confined in zeolites. Chem. Mater. 30, 3177–3198 (2018).

Ortalan, V., Uzun, A., Gates, B. C. & Browning, N. D. Direct imaging of single metal atoms and clusters in the pores of dealuminated HY zeolite. Nat. Nanotechnol. 5, 506–510 (2010).

Li, C. et al. Selective introduction of acid sites in different confined positions in ZSM-5 and its catalytic implications. ACS Catal. 8, 7688–7697 (2018).

Knott, B. C. et al. Consideration of the aluminum distribution in zeolites in theoretical and experimental catalysis research. ACS Catal. 8, 770–784 (2017).

Yokoi, T., Mochizuki, H., Namba, S., Kondo, J. N. & Tatsumi, T. Control of the Al distribution in the framework of ZSM-5 zeolite and its evaluation by solid-state NMR technique and catalytic properties. J. Phys. Chem. C 119, 15303–15315 (2015).

Goel, S., Zones, S. I. & Iglesia, E. Encapsulation of metal clusters within MFI via interzeolite transformations and direct hydrothermal syntheses and catalytic consequences of their confinement. J. Am. Chem. Soc. 136, 15280–15290 (2014).

Wang, N. et al. In situ confinement of ultrasmall Pd clusters within nanosized silicalite-1 zeolite for highly efficient catalysis of hydrogen generation. J. Am. Chem. Soc. 138, 7484–7487 (2016).

Iida, T., Zanchet, D., Ohara, K., Wakihara, T. & Roman-Leshkov, Y. Concerted bimetallic nanocluster synthesis and encapsulation via induced zeolite framework demetallation for shape and substrate selective heterogeneous catalysis. Angew. Chem. Int. Ed. 57, 6454–6458 (2018).

Zhang, J. et al. Sinter-resistant metal nanoparticle catalysts achieved by immobilization within zeolite crystals via seed-directed growth. Nat. Catal. 1, 540–546 (2018).

Campbell, C. T., Parker, S. C. & Starr, D. E. The effect of size-dependent nanoparticle energetics on catalyst sintering. Science 298, 811–814 (2002).

Flytzani-Stephanopoulos, M. & Gates, B. C. Atomically dispersed supported metal catalysts. Annu. Rev. Chem. Biomol. Eng. 3, 545–574 (2012).

Liu, L. et al. Generation of subnanometric platinum with high stability during transformation of a 2D zeolite into 3D. Nat. Mater. 16, 132–138 (2017).

Liu, L. et al. Evolution and stabilization of subnanometric metal species in confined space by in situ TEM. Nat. Commun. 9, 574 (2018).

Xiong, H. et al. Thermally stable and regenerable platinum-tin clusters for propane dehydrogenation prepared by atom trapping on ceria. Angew. Chem. Int. Ed. 56, 8986–8991 (2017).

Sattler, J. J., Ruiz-Martinez, J., Santillan-Jimenez, E. & Weckhuysen, B. M. Catalytic dehydrogenation of light alkanes on metals and metal oxides. Chem. Rev. 114, 10613–10653 (2014).

Zhu, J. et al. Size-dependent reaction mechanism and kinetics for propane dehydrogenation over Pt catalysts. ACS Catal. 5, 6310–6319 (2015).

Yang, M. et al. A common single-site Pt(II)–O(OH)x– species stabilized by sodium on “active” and “inert” supports catalyzes the water-gas shift reaction. J. Am. Chem. Soc. 137, 3470–3473 (2015).

Yang, M. et al. Catalytically active Au-O(OH)x- species stabilized by alkali ions on zeolites and mesoporous oxides. Science 346, 1498–1501 (2014).

Zhai, Y. et al. Alkali-stabilized Pt-OHx species catalyze low-temperature water-gas shift reactions. Science 329, 1633–1636 (2010).

Lazic, I., Bosch, E. G. T. & Lazar, S. Phase contrast STEM for thin samples: integrated differential phase contrast. Ultramicroscopy 160, 265–280 (2016).

Yucelen, E., Lazic, I. & Bosch, E. G. T. Phase contrast scanning transmission electron microscopy imaging of light and heavy atoms at the limit of contrast and resolution. Sci. Rep. 8, 2676 (2018).

Van Koningsveld, H. On the location and disorder of the tetrapropylammonium (TPA) ion in zeolite ZSM‐5 with improved framework accuracy. Acta Crystallogr. B 43, 127–132 (1987).

Dib, E., Grand, J., Mintova, S. & Fernandez, C. Structure-directing agent governs the location of silanol defects in zeolites. Chem. Mater. 27, 7577–7579 (2015).

Denayer, J. F., De Meyer, K., Martens, J. A. & Baron, G. V. Molecular competition effects in liquid-phase adsorption of long-chain n-alkane mixtures in ZSM-5 zeolite pores. Angew. Chem. Int. Ed. 42, 2774–2777 (2003).

Grand, J. et al. One-pot synthesis of silanol-free nanosized MFI zeolite. Nat. Mater. 16, 1010–1015 (2017).

de Graaf, J., van Dillen, A. J., de Jong, K. P. & Koningsberger, D. C. Preparation of highly dispersed Pt particles in zeolite Y with a narrow particle size distribution: characterization by hydrogen chemisorption, TEM, EXAFS spectroscopy, and particle modeling. J. Catal. 203, 307–321 (2001).

Bare, S. R. et al. Uniform catalytic site in Sn-beta-zeolite determined using X-ray absorption fine structure. J. Am. Chem. Soc. 127, 12924–12932 (2005).

Hammond, C. et al. Identification of active and spectator Sn sites in Sn-beta following solid-state stannation, and consequences for Lewis acid catalysis. ChemCatChem 7, 3322–3331 (2015).

Stakheev, A. Y., Shpiro, E. S., Jaeger, N. I. & Schulz-Ekloff, G. Electronic state and location of Pt metal clusters in KL zeolite: FTIR study of CO chemisorption. Catal. Lett. 32, 147–158 (1995).

Huang, H. et al. Effects of heat treatment atmosphere on the structure and activity of Pt3Sn nanoparticle electrocatalysts: a characterization case study. Faraday Discuss. 208, 555–573 (2018).

Alexeev, O. S. & Gates, B. C. Supported bimetallic cluster catalysts. Ind. Eng. Chem. Res. 42, 1571–1587 (2003).

Sankar, M. et al. Designing bimetallic catalysts for a green and sustainable future. Chem. Soc. Rev. 41, 8099–8139 (2012).

Ferrando, R., Jellinek, J. & Johnston, R. L. Nanoalloys: from theory to applications of alloy clusters and nanoparticles. Chem. Rev. 108, 845–910 (2008).

Zhu, H. et al. Sn surface-enriched Pt–Sn bimetallic nanoparticles as a selective and stable catalyst for propane dehydrogenation. J. Catal. 320, 52–62 (2014).

Wu, J., Peng, Z. & Bell, A. T. Effects of composition and metal particle size on ethane dehydrogenation over PtxSn100-x/Mg(Al)O (70⩽x⩽100). J. Catal. 311, 161–168 (2014).

López-Haro, M. et al. A macroscopically relevant 3D-metrology approach for nanocatalysis research. Part. Part. Syst. Charact. 35, 1700343 (2018).

Kirkland, E. J. Advanced Computing in Electron Microscopy (Springer, 2010).

Bernal, S. et al. The interpretation of HREM images of supported metal catalysts using image simulation: profile view images. Ultramicroscopy 72, 135–164 (1998).

Simonelli, L. et al. CLÆSS: the hard X-ray absorption beamline of the ALBA CELLS synchrotron. Cogent Phys. 3, 1231987 (2016).

Guilera, G., Rey, F., Hernández-Fenollosa, J. & Cortés-Vergaz, J. J. One body, many heads; the Cerberus of catalysis. A new multipurpose in-situ cell for XAS at ALBA. J. Phys. Conf. Ser. 430, 012057 (2013).

Ravel, B. & Newville, M. ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT. J. Synchrotron Radiat. 12, 537–541 (2005).

Yin, F., Ji, S., Wu, P., Zhao, F. & Li, C. Deactivation behavior of Pd-based SBA-15 mesoporous silica catalysts for the catalytic combustion of methane. J. Catal. 257, 108–116 (2008).

Allian, A. D. et al. Chemisorption of CO and mechanism of CO oxidation on supported platinum nanoclusters. J. Am. Chem. Soc. 133, 4498–4517 (2011).

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