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A Time-Resolved Study on the Reactivity of Alcoholic Drinks with the Hydroxyl Radical

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A Time-Resolved Study on the Reactivity of Alcoholic Drinks with the Hydroxyl Radical

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dc.contributor.author Rodriguez-Muniz, Gemma M. es_ES
dc.contributor.author Miranda Alonso, Miguel Ángel es_ES
dc.contributor.author Marín García, Mª Luisa es_ES
dc.date.accessioned 2021-01-21T04:31:46Z
dc.date.available 2021-01-21T04:31:46Z
dc.date.issued 2019-01-02 es_ES
dc.identifier.issn 1420-3049 es_ES
dc.identifier.uri http://hdl.handle.net/10251/159600
dc.description.abstract [EN] Reactive oxygen species (ROS) can provoke damage to cells, where their concentrations are regulated by antioxidants. As the hydroxyl radical (center dot OH) is the most oxidizing ROS, we have focused our attention on the use of a mechanistically based time-resolved methodology, such as laser flash photolysis, to determine the relative reactivity of alcoholic beverages towards center dot OH as an indicator of their antioxidant potential. The selected drinks were of two different origins: (i) those derived from grapes such as red wine, white wine, white vermouth, marc and brandy and (ii) spirits not derived from grapes: triple sec, gin, whisky, and rum. Initially, we determined the quenching rate constant of ethanol with center dot OH and then we explored the reactivity of the different beverages, which was higher than expected based on their alcoholic content. This can be attributed to the presence of antioxidants and was especially remarkable for the grape-derived drinks. es_ES
dc.description.sponsorship This research was funded by Spanish Government (Grant SEV-2016-0683) and Generalitat Valenciana (Prometeo Program). es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Molecules es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Antioxidants es_ES
dc.subject Laser flash photolysis es_ES
dc.subject Spirits es_ES
dc.subject Transient absorption es_ES
dc.subject Wine es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title A Time-Resolved Study on the Reactivity of Alcoholic Drinks with the Hydroxyl Radical es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/molecules24020234 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEOII%2F2013%2F005/ES/ESPECIES FOTOACTIVAS Y SU INTERACCION CON BIOMOLECULAS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Rodriguez-Muniz, GM.; Miranda Alonso, MÁ.; Marín García, ML. (2019). A Time-Resolved Study on the Reactivity of Alcoholic Drinks with the Hydroxyl Radical. Molecules. 24(2):1-9. https://doi.org/10.3390/molecules24020234 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/molecules24020234 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 9 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 24 es_ES
dc.description.issue 2 es_ES
dc.identifier.pmid 30634584 es_ES
dc.identifier.pmcid PMC6359750 es_ES
dc.relation.pasarela S\404295 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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