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A reliable procedure for the preparation of graphene-boron nitride superlattices as large area (cm x cm) films on arbitrary substrates or powders (gram scale) and unexpected electrocatalytic properties

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A reliable procedure for the preparation of graphene-boron nitride superlattices as large area (cm x cm) films on arbitrary substrates or powders (gram scale) and unexpected electrocatalytic properties

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dc.contributor.author Rendon-Patiño, Alejandra es_ES
dc.contributor.author Doménech, Antonio es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.contributor.author Primo Arnau, Ana Maria es_ES
dc.date.accessioned 2021-01-21T04:32:15Z
dc.date.available 2021-01-21T04:32:15Z
dc.date.issued 2019-02-14 es_ES
dc.identifier.issn 2040-3364 es_ES
dc.identifier.uri http://hdl.handle.net/10251/159613
dc.description.abstract [EN] Herein, a reliable procedure for the preparation of graphene-boron nitride superlattices, either as films or powders, consisting of the pyrolysis at 900 degrees C of polystyrene embedded pre-formed boron nitride single sheets is reported. The procedure can serve to prepare large area films (cm x cm) of this superlattice on quartz, copper foil and ceramics. Selected area electron diffraction patterns at every location on the films show the occurrence of the graphene-boron nitride superlattice all over the film. The procedure can also be applied to the preparation of powdered samples on a gram scale. Comparison with other materials indicates that the superlattice appears spontaneously as the growing graphene sheets develop, due to the templating effect of pre-existing boron nitride single sheets. Since the characteristic boron nitride emission in the visible region is completely quenched in the superlattice configuration, it is proposed that fluorescence microscopy can be used as a routine technique to determine the occurrence of superlattice in large area films. Electrodes of this material show an unforeseen catalytic activity for oxygen reduction reaction and exhibit a decrease of the heterojunction-electrolyte interphase electrical resistance. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and CTQ-2015-69653-CO2-R1) is gratefully acknowledged. AR and AP thank the Spanish Ministry of Economy and Competitiveness for a postgraduate scholarship and a Ramon y Cajal research associate contract, respectively. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation MINECO/CTQ2015-69653-CO2-R1 es_ES
dc.relation.ispartof Nanoscale es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title A reliable procedure for the preparation of graphene-boron nitride superlattices as large area (cm x cm) films on arbitrary substrates or powders (gram scale) and unexpected electrocatalytic properties es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c8nr08377k es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Rendon-Patiño, A.; Doménech, A.; García Gómez, H.; Primo Arnau, AM. (2019). A reliable procedure for the preparation of graphene-boron nitride superlattices as large area (cm x cm) films on arbitrary substrates or powders (gram scale) and unexpected electrocatalytic properties. Nanoscale. 11(6):2981-2990. https://doi.org/10.1039/c8nr08377k es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c8nr08377k es_ES
dc.description.upvformatpinicio 2981 es_ES
dc.description.upvformatpfin 2990 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 11 es_ES
dc.description.issue 6 es_ES
dc.identifier.pmid 30698195 es_ES
dc.relation.pasarela S\406918 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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