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dc.contributor.author | Carsí Rosique, Marta | es_ES |
dc.contributor.author | Sanchis Sánchez, María Jesús | es_ES |
dc.contributor.author | Gómez, Clara M. | es_ES |
dc.contributor.author | Rodriguez, Sol | es_ES |
dc.contributor.author | García-Torres, Fernando | es_ES |
dc.date.accessioned | 2021-01-30T04:31:32Z | |
dc.date.available | 2021-01-30T04:31:32Z | |
dc.date.issued | 2019-06 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/160299 | |
dc.description.abstract | [EN] Films of carrageenan (KC) and glycerol (g) with different contents of chitin nanowhiskers (CHW) were prepared by a solution casting process. The molecular dynamics of pure carrageenan (KC), carrageenan/glycerol (KCg) and KCg with different quantities of CHWs as a filler was studied using dielectric relaxation spectroscopy. The analysis of the CHW effect on the molecular mobility at the glass transition, T-g, indicates that non-attractive intermolecular interactions between KCg and CHW occur. The fragility index increased upon CHW incorporation, due to a reduction in the polymer chains mobility produced by the CHW confinement of the KCg network. The apparent activation energy associated with the relaxation dynamics of the chains at T-g slightly increased with the CHW content. The filler nature effect, CHW or montmorillonite (MMT), on the dynamic mobility of the composites was analyzed by comparing the dynamic behavior of both carrageenan-based composites (KCg/xCHW, KCg/xMMT). | es_ES |
dc.description.sponsorship | This research was funded by the DGCYT grant number [MAT2015-63955-R] and the Vice-Rectorate for Research of the Pontificia Universidad Catolica del Peru and the the Peruvian Science and Technology Program (INNOVATE-PERU) And The APC was funded by MDPI. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | MDPI AG | es_ES |
dc.relation.ispartof | Polymers | es_ES |
dc.rights | Reconocimiento (by) | es_ES |
dc.subject | Carrageenan | es_ES |
dc.subject | Chitin | es_ES |
dc.subject | Dielectric relaxation spectroscopy | es_ES |
dc.subject | Electric modulus | es_ES |
dc.subject | Fragility | es_ES |
dc.subject.classification | MAQUINAS Y MOTORES TERMICOS | es_ES |
dc.title | Effect of Chitin Whiskers on the Molecular Dynamics of Carrageenan-Based Nanocomposites | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.3390/polym11061083 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//MAT2015-63955-R/ES/NANOESTRUCTURAS SEMICONDUCTORAS Y NANOCOMPOSITES PARA LA RECUPERACION ENERGETICA/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada | es_ES |
dc.description.bibliographicCitation | Carsí Rosique, M.; Sanchis Sánchez, MJ.; Gómez, CM.; Rodriguez, S.; García-Torres, F. (2019). Effect of Chitin Whiskers on the Molecular Dynamics of Carrageenan-Based Nanocomposites. Polymers. 11(6):1-16. https://doi.org/10.3390/polym11061083 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.3390/polym11061083 | es_ES |
dc.description.upvformatpinicio | 1 | es_ES |
dc.description.upvformatpfin | 16 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 11 | es_ES |
dc.description.issue | 6 | es_ES |
dc.identifier.eissn | 2073-4360 | es_ES |
dc.identifier.pmid | 31242647 | es_ES |
dc.identifier.pmcid | PMC6630605 | es_ES |
dc.relation.pasarela | S\389972 | es_ES |
dc.contributor.funder | Ministerio de la producción, Perú | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
dc.contributor.funder | Pontificia Universidad Católica del Perú | es_ES |
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dc.subject.ods | 12.- Garantizar las pautas de consumo y de producción sostenibles | es_ES |
dc.subject.ods | 15.- Proteger, restaurar y promover la utilización sostenible de los ecosistemas terrestres, gestionar de manera sostenible los bosques, combatir la desertificación y detener y revertir la degradación de la tierra, y frenar la pérdida de diversidad biológica | es_ES |
dc.subject.ods | 06.- Garantizar la disponibilidad y la gestión sostenible del agua y el saneamiento para todos | es_ES |
dc.subject.ods | 09.- Desarrollar infraestructuras resilientes, promover la industrialización inclusiva y sostenible, y fomentar la innovación | es_ES |
dc.subject.ods | 14.- Conservar y utilizar de forma sostenible los océanos, mares y recursos marinos para lograr el desarrollo sostenible | es_ES |