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Manufacturing and Characterization of Functionalized Aliphatic Polyester from Poly(lactic acid) with Halloysite Nanotubes

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Manufacturing and Characterization of Functionalized Aliphatic Polyester from Poly(lactic acid) with Halloysite Nanotubes

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dc.contributor.author Montava-Jorda, Sergi es_ES
dc.contributor.author Chacon, Victor es_ES
dc.contributor.author Lascano-Aimacaña, Diego Sebastián es_ES
dc.contributor.author Sanchez-Nacher, Lourdes es_ES
dc.contributor.author Montanes, Nestor es_ES
dc.date.accessioned 2021-01-30T04:32:10Z
dc.date.available 2021-01-30T04:32:10Z
dc.date.issued 2019-08 es_ES
dc.identifier.uri http://hdl.handle.net/10251/160321
dc.description.abstract [EN] This work reports the potential of poly(lactic acid)-PLA composites with different halloysite nanotube (HNTs) loading (3, 6 and 9 wt%) for further uses in advanced applications as HNTs could be used as carriers for active compounds for medicine, packaging and other sectors. This work focuses on the effect of HNTs on mechanical, thermal, thermomechanical and degradation of PLA composites with HNTs. These composites can be manufactured by conventional extrusion-compounding followed by injection molding. The obtained results indicate a slight decrease in tensile and flexural strength as well as in elongation at break, both properties related to material cohesion. On the contrary, the stiffness increases with the HNTs content. The tensile strength and modulus change from 64.6 MPa/2.1 GPa (neat PLA) to 57.7/2.3 GPa MPa for the composite with 9 wt% HNTs. The elongation at break decreases from 6.1% (neat PLA) down to a half for composites with 9 wt% HNTs. Regarding flexural properties, the flexural strength and modulus change from 116.1 MPa and 3.6 GPa respectively for neat PLA to values of 107.6 MPa and 3.9 GPa for the composite with 9 wt% HNTs. HNTs do not affect the glass transition temperature with invariable values of about 64 degrees C, or the melt peak temperature, while they move the cold crystallization process towards lower values, from 112.4 degrees C for neat PLA down to 105.4 degrees C for the composite containing 9 wt% HNTs. The water uptake has been assessed to study the influence of HNTs on the water saturation. HNTs contribute to increased hydrophilicity with a change in the asymptotic water uptake from 0.95% (neat PLA) up to 1.67% (PLA with 9 wt % HNTs) and the effect of HNTs on disintegration in controlled compost soil has been carried out to see the influence of HNTs on this process, which is a slight delay on it. These PLA-HNT composites show good balanced properties and could represent an interesting solution to develop active materials. es_ES
dc.description.sponsorship This research was supported by the Ministry of Science, Innovation, and Universities (MICIU) through the MAT2017-84909-C2-2-R program number. D. Lascano wants to thank UPV for the grant received though the PAID-01-18 program. Microscopy services at UPV are acknowledged for their help in collecting and analyzing FESEM images. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Polymers es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Poly(lactic acid) es_ES
dc.subject Halloysite nanotubes es_ES
dc.subject Mechanical characterization es_ES
dc.subject Morphology es_ES
dc.subject Thermal characterization es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.subject.classification INGENIERIA MECANICA es_ES
dc.title Manufacturing and Characterization of Functionalized Aliphatic Polyester from Poly(lactic acid) with Halloysite Nanotubes es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/polym11081314 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UPV//PAID-01-18/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84909-C2-2-R/ES/PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.description.bibliographicCitation Montava-Jorda, S.; Chacon, V.; Lascano-Aimacaña, DS.; Sanchez-Nacher, L.; Montanes, N. (2019). Manufacturing and Characterization of Functionalized Aliphatic Polyester from Poly(lactic acid) with Halloysite Nanotubes. Polymers. 11(8):1-21. https://doi.org/10.3390/polym11081314 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/polym11081314 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 21 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 11 es_ES
dc.description.issue 8 es_ES
dc.identifier.eissn 2073-4360 es_ES
dc.identifier.pmid 31390814 es_ES
dc.identifier.pmcid PMC6722548 es_ES
dc.relation.pasarela S\392195 es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
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