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Electrical conductivity of an all-natural and biocompatible semi-interpenetrating polymer network containing a deep eutectic solvent

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Electrical conductivity of an all-natural and biocompatible semi-interpenetrating polymer network containing a deep eutectic solvent

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dc.contributor.author Gachuz, Edwin J. es_ES
dc.contributor.author Castillo-Santillán, Martín es_ES
dc.contributor.author Juarez-Moreno, Carla es_ES
dc.contributor.author Maya Cornejo, Jose es_ES
dc.contributor.author Martinez-Richa, Antonio es_ES
dc.contributor.author Andrio, Andreu es_ES
dc.contributor.author Compañ Moreno, Vicente es_ES
dc.contributor.author Mota-Morales, Josué D. es_ES
dc.date.accessioned 2021-02-19T04:34:17Z
dc.date.available 2021-02-19T04:34:17Z
dc.date.issued 2020-09-07 es_ES
dc.identifier.issn 1463-9262 es_ES
dc.identifier.uri http://hdl.handle.net/10251/161864
dc.description.abstract [EN] A series of semi-interpenetrating polymer networks (semi-IPNs) consisting of crosslinked poly(itaconic acid) in the presence of the polysaccharide inulin were prepared by free-radical polymerization, taking advantage of the chemistry of deep eutectic systems (DESs). Up to 14 wt% of the polysaccharide inulin readily dissolves in a nonaqueous DES composed of glycerol (Gly) and choline chloride (ChCl). On the other hand, itaconic acid (IA) mixed with ChCl formed a deep eutectic solvent (DES) monomer, which upon free-radical polymerization in solution aided by multifunctional acrylates allowed the synthesis of highly crosslinked polymer networks. Bringing together both DESs, the DES monomer containing IA and the inert one containing inulin dissolved in it, allowed the synthesis of all-natural (ca.96 wt% of biobased components, excluding crosslinkers) and biocompatible semi-IPNs. Remarkably, the DESs entrapped in the semi-IPNs served as a stable nonaqueous electrolyte in the range of 25-75 degrees C, thus exhibiting a typical Arrhenius dependence of conductivity with temperature (an apparent activation energy of 18 kJ mol(-1)), irrespective of the type of crosslinker used. Following electrode polarization (EP) analysis based on the Macdonald-Trukhan model, the free-ion diffusivity, the mobility, and the number of charge carrier density of the polymeric networks were calculated. The results show that diffusivity and mobility increase along with temperature in all semi-IPNs with a maximum conductivity of 3.2 mS cm(-1)at 65 degrees C in the semi-IPN crosslinked with a trifunctional acrylate. The higher conductivity and diffusivity observed in the semi-IPN crosslinked with the trifunctional acrylate in comparison with the difunctional one are related to the long-translational diffusion, because the diffusive dynamics are dominated by the localized motions that are not strongly affected by the confinement of the DES electrolyte within the polymeric network. In summary, this work furthers the applications of DES chemistry towards the fabrication of greener materials,e.g.natural polymers and biobased feedstocks, with future applications in technologies seeking biocompatible conductive gels. es_ES
dc.description.sponsorship J. D. M.-M. acknowledges the financial support from the National Council of Science and Technology (CONACYT) through grant no. 252774, and PAPIIT-UNAM project no. IA202018 and TA200220, Mexico. All authors kindly acknowledge The National Laboratory for Characterization of Physicochemical Properties and Molecular Structure, CONACYT (Grant No. 123732) for the instrumentation time provided, and technical assistance provided by Beatriz Millan-Malo (CFATA-UNAM) in XRD measurements (Laboratorio Nacional de Caracterizacion de Materiales con Certificacion ISO 9001:2015), and Karla A. Barrera-Rivera (UG) for obtaining DSC thermograms. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Green Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.title Electrical conductivity of an all-natural and biocompatible semi-interpenetrating polymer network containing a deep eutectic solvent es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/d0gc02274h es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CONACyT//123732/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CONACyT//252774/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UNAM//IA202018/MX/Nanocompositos macroporosos jerárquicos a partir de emulsiones gel “Pickering” estabilizados por biopolímeros usando disolventes eutécticos no acuosos/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UNAM//TA200220/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada es_ES
dc.description.bibliographicCitation Gachuz, EJ.; Castillo-Santillán, M.; Juarez-Moreno, C.; Maya Cornejo, J.; Martinez-Richa, A.; Andrio, A.; Compañ Moreno, V.... (2020). Electrical conductivity of an all-natural and biocompatible semi-interpenetrating polymer network containing a deep eutectic solvent. Green Chemistry. 22(17):5785-5797. https://doi.org/10.1039/d0gc02274h es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/d0gc02274h es_ES
dc.description.upvformatpinicio 5785 es_ES
dc.description.upvformatpfin 5797 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 22 es_ES
dc.description.issue 17 es_ES
dc.relation.pasarela S\424072 es_ES
dc.contributor.funder Universidad Nacional Autónoma de México es_ES
dc.contributor.funder Consejo Nacional de Ciencia y Tecnología, México es_ES
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