Mostrar el registro sencillo del ítem
dc.contributor.author | Tampau, Alina | es_ES |
dc.contributor.author | González Martínez, María Consuelo | es_ES |
dc.contributor.author | Chiralt Boix, Mª Amparo | es_ES |
dc.date.accessioned | 2021-02-24T04:31:45Z | |
dc.date.available | 2021-02-24T04:31:45Z | |
dc.date.issued | 2020-03 | es_ES |
dc.identifier.issn | 0141-3910 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/162243 | |
dc.description.abstract | [EN] The biodegradation and disintegration of thermoplastic starch multilayers containing carvacrol(CA)-loaded poly-(epsilon-caprolactone) electrospun mats were evaluated under thermophilic composting conditions for 45 and 84 days, respectively, and compared with non-loaded carvacrol films and pure starch films. Sample mass loss, thermogravimetric and visual analyses were performed throughout the disintegration test. The disintegration behaviour of all multilayers was similar, reaching values of 75-80% after 84 days. Biodegradation, assessed by carbon dioxide measurements, revealed that all the carvacrol-free films completely biodegraded after 25 composting days. However, the presence of CA notably affected the compost inoculum activity, thus limiting the biodegradability of the CA-loaded multilayers to a maximum value of around 85% after 45 days. Nevertheless, this value was close to that established by the standard ISO method to qualify as biodegradable material. | es_ES |
dc.description.sponsorship | The authors thank the Ministerio de Economia y Competitividad (MINECO, Spain) for funding this study through the pre-doctoral grant BES-2014-068100 and through the investigation project AGL2016-76699-R. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation.ispartof | Polymer Degradation and Stability | es_ES |
dc.rights | Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) | es_ES |
dc.subject | Thermoplastic starch | es_ES |
dc.subject | Poly-(epsilon-caprolactone) | es_ES |
dc.subject | Carvacrol | es_ES |
dc.subject | TGA | es_ES |
dc.subject | Disintegration | es_ES |
dc.subject | Biodegradation | es_ES |
dc.subject.classification | TECNOLOGIA DE ALIMENTOS | es_ES |
dc.title | Biodegradability and disintegration of multilayer starch films with electrospun PCL fibres encapsulating carvacrol | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1016/j.polymdegradstab.2020.109100 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//BES-2014-068100/ES/BES-2014-068100/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//AGL2016-76699-R/ES/Materiales Biodegradables Multicapa de Alta Barrera para el Envasado Activo de Alimentos/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario de Ingeniería de Alimentos para el Desarrollo - Institut Universitari d'Enginyeria d'Aliments per al Desenvolupament | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Tecnología de Alimentos - Departament de Tecnologia d'Aliments | es_ES |
dc.description.bibliographicCitation | Tampau, A.; González Martínez, MC.; Chiralt Boix, MA. (2020). Biodegradability and disintegration of multilayer starch films with electrospun PCL fibres encapsulating carvacrol. Polymer Degradation and Stability. 173:1-8. https://doi.org/10.1016/j.polymdegradstab.2020.109100 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1016/j.polymdegradstab.2020.109100 | es_ES |
dc.description.upvformatpinicio | 1 | es_ES |
dc.description.upvformatpfin | 8 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 173 | es_ES |
dc.relation.pasarela | S\404633 | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
dc.description.references | Thompson, R. C., Moore, C. J., vom Saal, F. S., & Swan, S. H. (2009). Plastics, the environment and human health: current consensus and future trends. Philosophical Transactions of the Royal Society B: Biological Sciences, 364(1526), 2153-2166. doi:10.1098/rstb.2009.0053 | es_ES |
dc.description.references | Jahan, S., Strezov, V., Weldekidan, H., Kumar, R., Kan, T., Sarkodie, S. A., … Wilson, S. P. (2019). Interrelationship of microplastic pollution in sediments and oysters in a seaport environment of the eastern coast of Australia. Science of The Total Environment, 695, 133924. doi:10.1016/j.scitotenv.2019.133924 | es_ES |
dc.description.references | Li, J., Qu, X., Su, L., Zhang, W., Yang, D., Kolandhasamy, P., … Shi, H. (2016). Microplastics in mussels along the coastal waters of China. Environmental Pollution, 214, 177-184. doi:10.1016/j.envpol.2016.04.012 | es_ES |
dc.description.references | Renzi, M., Guerranti, C., & Blašković, A. (2018). Microplastic contents from maricultured and natural mussels. Marine Pollution Bulletin, 131, 248-251. doi:10.1016/j.marpolbul.2018.04.035 | es_ES |
dc.description.references | Santana, M. F. M., Ascer, L. G., Custódio, M. R., Moreira, F. T., & Turra, A. (2016). Microplastic contamination in natural mussel beds from a Brazilian urbanized coastal region: Rapid evaluation through bioassessment. Marine Pollution Bulletin, 106(1-2), 183-189. doi:10.1016/j.marpolbul.2016.02.074 | es_ES |
dc.description.references | Watts, A. J. R., Urbina, M. A., Corr, S., Lewis, C., & Galloway, T. S. (2015). Ingestion of Plastic Microfibers by the Crab Carcinus maenas and Its Effect on Food Consumption and Energy Balance. Environmental Science & Technology, 49(24), 14597-14604. doi:10.1021/acs.est.5b04026 | es_ES |
dc.description.references | Jinhui, S., Sudong, X., Yan, N., Xia, P., Jiahao, Q., & Yongjian, X. (2019). Effects of microplastics and attached heavy metals on growth, immunity, and heavy metal accumulation in the yellow seahorse, Hippocampus kuda Bleeker. Marine Pollution Bulletin, 149, 110510. doi:10.1016/j.marpolbul.2019.110510 | es_ES |
dc.description.references | Qiao, R., Deng, Y., Zhang, S., Wolosker, M. B., Zhu, Q., Ren, H., & Zhang, Y. (2019). Accumulation of different shapes of microplastics initiates intestinal injury and gut microbiota dysbiosis in the gut of zebrafish. Chemosphere, 236, 124334. doi:10.1016/j.chemosphere.2019.07.065 | es_ES |
dc.description.references | Heimowska, A., Morawska, M., & Bocho-Janiszewska, A. (2017). Biodegradation of poly(ε-caprolactone) in natural water environments. Polish Journal of Chemical Technology, 19(1), 120-126. doi:10.1515/pjct-2017-0017 | es_ES |
dc.description.references | Ortega-Toro, R., Contreras, J., Talens, P., & Chiralt., A. (2015). Physical and structural properties and thermal behaviour of starch-poly(ɛ-caprolactone) blend films for food packaging. Food Packaging and Shelf Life, 5, 10-20. doi:10.1016/j.fpsl.2015.04.001 | es_ES |
dc.description.references | Tampau, A., González-Martínez, C., & Chiralt, A. (2018). Release kinetics and antimicrobial properties of carvacrol encapsulated in electrospun poly-(ε-caprolactone) nanofibres. Application in starch multilayer films. Food Hydrocolloids, 79, 158-169. doi:10.1016/j.foodhyd.2017.12.021 | es_ES |
dc.description.references | Tampau, A., González-Martinez, C., & Chiralt, A. (2017). Carvacrol encapsulation in starch or PCL based matrices by electrospinning. Journal of Food Engineering, 214, 245-256. doi:10.1016/j.jfoodeng.2017.07.005 | es_ES |
dc.description.references | Ramos, M., Jiménez, A., Peltzer, M., & Garrigós, M. C. (2012). Characterization and antimicrobial activity studies of polypropylene films with carvacrol and thymol for active packaging. Journal of Food Engineering, 109(3), 513-519. doi:10.1016/j.jfoodeng.2011.10.031 | es_ES |
dc.description.references | Ben Arfa, A., Preziosi-Belloy, L., Chalier, P., & Gontard, N. (2007). Antimicrobial Paper Based on a Soy Protein Isolate or Modified Starch Coating Including Carvacrol and Cinnamaldehyde. Journal of Agricultural and Food Chemistry, 55(6), 2155-2162. doi:10.1021/jf0626009 | es_ES |
dc.description.references | Ultee, A., Bennik, M. H. J., & Moezelaar, R. (2002). The Phenolic Hydroxyl Group of Carvacrol Is Essential for Action against the Food-Borne Pathogen Bacillus cereus. Applied and Environmental Microbiology, 68(4), 1561-1568. doi:10.1128/aem.68.4.1561-1568.2002 | es_ES |
dc.description.references | Tunc, S., Chollet, E., Chalier, P., Preziosi-Belloy, L., & Gontard, N. (2007). Combined effect of volatile antimicrobial agents on the growth of Penicillium notatum. International Journal of Food Microbiology, 113(3), 263-270. doi:10.1016/j.ijfoodmicro.2006.07.004 | es_ES |
dc.description.references | Tepe, B., Sokmen, M., Akpulat, H. A., Daferera, D., Polissiou, M., & Sokmen, A. (2005). Antioxidative activity of the essential oils of Thymus sipyleus subsp. sipyleus var. sipyleus and Thymus sipyleus subsp. sipyleus var. rosulans. Journal of Food Engineering, 66(4), 447-454. doi:10.1016/j.jfoodeng.2004.04.015 | es_ES |
dc.description.references | Gursul, S., Karabulut, I., & Durmaz, G. (2019). Antioxidant efficacy of thymol and carvacrol in microencapsulated walnut oil triacylglycerols. Food Chemistry, 278, 805-810. doi:10.1016/j.foodchem.2018.11.134 | es_ES |
dc.description.references | (2012). Scientific Opinion on the safety and efficacy of phenol derivatives containing ring-alkyl, ring-alkoxy and side-chains with an oxygenated functional group (chemical group 25) when used as flavourings for all species. EFSA Journal, 10(2), 2573. doi:10.2903/j.efsa.2012.2573 | es_ES |
dc.description.references | Kavoosi, G., Dadfar, S. M. M., Mohammadi Purfard, A., & Mehrabi, R. (2013). Antioxidant and Antibacterial Properties of Gelatin Films Incorporated with Carvacrol. Journal of Food Safety, 33(4), 423-432. doi:10.1111/jfs.12071 | es_ES |
dc.description.references | López-Mata, M., Ruiz-Cruz, S., Silva-Beltrán, N., Ornelas-Paz, J., Zamudio-Flores, P., & Burruel-Ibarra, S. (2013). Physicochemical, Antimicrobial and Antioxidant Properties of Chitosan Films Incorporated with Carvacrol. Molecules, 18(11), 13735-13753. doi:10.3390/molecules181113735 | es_ES |
dc.description.references | Higueras, L., López-Carballo, G., Hernández-Muñoz, P., Catalá, R., & Gavara, R. (2014). Antimicrobial packaging of chicken fillets based on the release of carvacrol from chitosan/cyclodextrin films. International Journal of Food Microbiology, 188, 53-59. doi:10.1016/j.ijfoodmicro.2014.07.018 | es_ES |
dc.description.references | Balaguer, M. P., Villanova, J., Cesar, G., Gavara, R., & Hernandez-Munoz, P. (2015). Compostable properties of antimicrobial bioplastics based on cinnamaldehyde cross-linked gliadins. Chemical Engineering Journal, 262, 447-455. doi:10.1016/j.cej.2014.09.099 | es_ES |
dc.description.references | Cano, A. I., Cháfer, M., Chiralt, A., & González-Martínez, C. (2016). Biodegradation behavior of starch-PVA films as affected by the incorporation of different antimicrobials. Polymer Degradation and Stability, 132, 11-20. doi:10.1016/j.polymdegradstab.2016.04.014 | es_ES |
dc.description.references | Talón, E., Vargas, M., Chiralt, A., & González-Martínez, C. (2019). Eugenol incorporation into thermoprocessed starch films using different encapsulating materials. Food Packaging and Shelf Life, 21, 100326. doi:10.1016/j.fpsl.2019.100326 | es_ES |
dc.description.references | Castro-Aguirre, E., Auras, R., Selke, S., Rubino, M., & Marsh, T. (2017). Insights on the aerobic biodegradation of polymers by analysis of evolved carbon dioxide in simulated composting conditions. Polymer Degradation and Stability, 137, 251-271. doi:10.1016/j.polymdegradstab.2017.01.017 | es_ES |
dc.description.references | Collazo-Bigliardi, S., Ortega-Toro, R., & Chiralt Boix, A. (2018). Reinforcement of Thermoplastic Starch Films with Cellulose Fibres Obtained from Rice and Coffee Husks. Journal of Renewable Materials, 6(7), 599-610. doi:10.32604/jrm.2018.00127 | es_ES |
dc.description.references | Sreekumar, P. A., Al-Harthi, M. A., & De, S. K. (2012). Studies on compatibility of biodegradable starch/polyvinyl alcohol blends. Polymer Engineering & Science, 52(10), 2167-2172. doi:10.1002/pen.23178 | es_ES |
dc.description.references | Singh, R. ., Pandey, J. ., Rutot, D., Degée, P., & Dubois, P. (2003). Biodegradation of poly(ε-caprolactone)/starch blends and composites in composting and culture environments: the effect of compatibilization on the inherent biodegradability of the host polymer. Carbohydrate Research, 338(17), 1759-1769. doi:10.1016/s0008-6215(03)00236-2 | es_ES |
dc.description.references | Yang, H.-S., Yoon, J.-S., & Kim, M.-N. (2005). Dependence of biodegradability of plastics in compost on the shape of specimens. Polymer Degradation and Stability, 87(1), 131-135. doi:10.1016/j.polymdegradstab.2004.07.016 | es_ES |
dc.description.references | Murphy, C. A., Cameron, J. A., Huang, S. J., & Vinopal, R. T. (1996). Fusarium polycaprolactone depolymerase is cutinase. Applied and Environmental Microbiology, 62(2), 456-460. doi:10.1128/aem.62.2.456-460.1996 | es_ES |
dc.description.references | Murphy, C. A., Cameron, J. A., Huang, S. J., & Vinopal, R. T. (1998). A second polycaprolactone depolymerase from Fusarium , a lipase distinct from cutinase. Applied Microbiology and Biotechnology, 50(6), 692-696. doi:10.1007/s002530051352 | es_ES |
dc.description.references | Tokiwa, Y., Calabia, B., Ugwu, C., & Aiba, S. (2009). Biodegradability of Plastics. International Journal of Molecular Sciences, 10(9), 3722-3742. doi:10.3390/ijms10093722 | es_ES |
dc.description.references | Banerjee, A., Chatterjee, K., & Madras, G. (2015). Enzymatic degradation of polycaprolactone–gelatin blend. Materials Research Express, 2(4), 045303. doi:10.1088/2053-1591/2/4/045303 | es_ES |
dc.description.references | Shen, J., & Bartha, R. (1997). Priming effect of glucose polymers in soil-based biodegradation tests. Soil Biology and Biochemistry, 29(8), 1195-1198. doi:10.1016/s0038-0717(97)00031-x | es_ES |