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Synthesis of Phosphorus-Containing Polyanilines by Electrochemical Copolymerization

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Synthesis of Phosphorus-Containing Polyanilines by Electrochemical Copolymerization

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dc.contributor.author Martínez-Sánchez, Beatriz es_ES
dc.contributor.author Quintero-Jaime, Andrés Felipe es_ES
dc.contributor.author Huerta, Francisco es_ES
dc.contributor.author Cazorla-Amorós, Diego es_ES
dc.contributor.author Morallón, Emilia es_ES
dc.date.accessioned 2021-03-01T08:10:03Z
dc.date.available 2021-03-01T08:10:03Z
dc.date.issued 2020-05 es_ES
dc.identifier.uri http://hdl.handle.net/10251/162601
dc.description.abstract [EN] In this study, the phosphonation of a polyaniline (PANI) backbone was achieved in an acid medium by electrochemical methods using aminophenylphosphonic (APPA) monomers. This was done through the electrochemical copolymerization of aniline with either 2- or 4-aminophenylphosphonic acid. Stable, electroactive polymers were obtained after the oxidation of the monomers up to 1.35 V (reversible hydrogen electrode, RHE). X-ray photoelectron spectroscopy (XPS) results revealed that the position of the phosphonic group in the aromatic ring of the monomer affected the amount of phosphorus incorporated into the copolymer. In addition, the redox transitions of the copolymers were examined by in situ Fourier-transform infrared (FTIR) spectroscopy, and it was concluded that their electroactive structures were analogous to those of PANI. From the APPA monomers it was possible to synthesize, in a controlled manner, polymeric materials with significant amounts of phosphorus in their structure through copolymerization with PANI. es_ES
dc.description.sponsorship The authors would like to thank MINECO, FEDER (MAT2016-76595-R) for financial support. A.F.Q.-J. gratefully acknowledges the Generalitat Valenciana for the financial support through the Santiago Grisolia grant (GRISOLIA/2016/084). B.M.-S. acknowledges the Vice-rectorate for Research and Knowledge Transfer of University of Alicante for financial support (AII2018-16), as well as the Spanish Ministry of Science, Innovation and Universities for the FPU grant (FPU18/05127). es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Polymers es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Polyaniline es_ES
dc.subject Phosphorus es_ES
dc.subject Electrochemical polymerization es_ES
dc.subject Modified polyaniline es_ES
dc.subject.classification QUIMICA FISICA es_ES
dc.title Synthesis of Phosphorus-Containing Polyanilines by Electrochemical Copolymerization es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/polym12051029 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2016-76595-R/ES/NUEVAS ESTRATEGIAS DE FUNCIONALIZACION ELECTROQUIMICA DE MATERIALES CARBONOSOS NANOESTRUCTURADOS PARA LA REDUCCION DE OXIGENO Y BIOSENSORES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//GRISOLIA%2F2016%2F084/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UA//AII2018-16/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI//FPU18%2F05127/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Textil y Papelera - Departament d'Enginyeria Tèxtil i Paperera es_ES
dc.description.bibliographicCitation Martínez-Sánchez, B.; Quintero-Jaime, AF.; Huerta, F.; Cazorla-Amorós, D.; Morallón, E. (2020). Synthesis of Phosphorus-Containing Polyanilines by Electrochemical Copolymerization. Polymers. 12(5):1-16. https://doi.org/10.3390/polym12051029 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/polym12051029 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 16 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 12 es_ES
dc.description.issue 5 es_ES
dc.identifier.eissn 2073-4360 es_ES
dc.relation.pasarela S\415814 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Universidad de Alicante es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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