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MCM-22, MCM-36, and ITQ-2 Zeolites with Different Si/Al Molar Ratios as Effective Catalysts of Methanol and Ethanol Dehydration

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MCM-22, MCM-36, and ITQ-2 Zeolites with Different Si/Al Molar Ratios as Effective Catalysts of Methanol and Ethanol Dehydration

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dc.contributor.author Marosz, Monika es_ES
dc.contributor.author Samojeden, Bogdan es_ES
dc.contributor.author Kowalczyk, Andrzej es_ES
dc.contributor.author Rutkowska, Malgorzata es_ES
dc.contributor.author Motak, Monika es_ES
dc.contributor.author DÍAZ MORALES, URBANO MANUEL es_ES
dc.contributor.author Palomares Gimeno, Antonio Eduardo es_ES
dc.contributor.author Chmielarz, Lucjan es_ES
dc.date.accessioned 2021-03-27T04:31:15Z
dc.date.available 2021-03-27T04:31:15Z
dc.date.issued 2020-05 es_ES
dc.identifier.uri http://hdl.handle.net/10251/164478
dc.description.abstract [EN] MCM-22, MCM-36, and ITQ-2 zeolites with the intended Si/Al molar ratios of 15, 25, and 50 were synthetized and tested as catalysts for dehydration of methanol to dimethyl ether and dehydration of ethanol to diethyl ether and ethylene. The surface concentration of acid sites was regulated by the synthesis of zeolite precursors with different aluminum content in the zeolite framework, while the influence of porous structure on the overall efficiency of alcohol conversion was analyzed by application of zeolitic materials with different types of porosity-microporous MCM-22 as well as microporous-mesoporous MCM-36 and ITQ-2. The zeolitic samples were characterized with respect to their: chemical composition (ICP-OES), structure (XRD, FT-IR), texture (N-2 sorption), and surface acidity (NH3-TPD). Comparison of the catalytic activity of the studied zeolitic catalysts with other reported catalytic systems, including zeolites with the similar Si/Al ratio as well as gamma-Al2O3 (one of the commercial catalysts for methanol dehydration), shows a great potential of MCM-22, MCM-36, and ITQ-2 in the reactions of alcohols dehydration. es_ES
dc.description.sponsorship This research was funded by National Science Centre-Poland grant number 2016/21/B/ST5/00242. U.D. acknowledges to the Spanish Government grant number MAT2017-82288-C2-1-P. The research was partially done using the equipment purchased from the funds of European Regional Development Fund, Polish Innovation Economy Operational Program, grant numberPOIG.02.01.00-12-023/08. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Materials es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject MCM-22 es_ES
dc.subject MCM-36 es_ES
dc.subject ITQ-2 es_ES
dc.subject Methanol es_ES
dc.subject Ethanol es_ES
dc.subject Dehydration es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title MCM-22, MCM-36, and ITQ-2 Zeolites with Different Si/Al Molar Ratios as Effective Catalysts of Methanol and Ethanol Dehydration es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/ma13102399 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FNP//POIG.02.01.00-12-023%2F08/PL/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-82288-C2-1-P/ES/MATERIALES HIBRIDOS MULTIFUNCIONALES BASADOS EN NANO-UNIDADES ESTRUCTURALES ACTIVAS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/NCN//2016%2F21%2FB%2FST5%2F00242/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Marosz, M.; Samojeden, B.; Kowalczyk, A.; Rutkowska, M.; Motak, M.; Díaz Morales, UM.; Palomares Gimeno, AE.... (2020). MCM-22, MCM-36, and ITQ-2 Zeolites with Different Si/Al Molar Ratios as Effective Catalysts of Methanol and Ethanol Dehydration. Materials. 13(10):1-17. https://doi.org/10.3390/ma13102399 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/ma13102399 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 17 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 13 es_ES
dc.description.issue 10 es_ES
dc.identifier.eissn 1996-1944 es_ES
dc.identifier.pmid 32456028 es_ES
dc.identifier.pmcid PMC7288170 es_ES
dc.relation.pasarela S\420364 es_ES
dc.contributor.funder National Science Centre, Polonia es_ES
dc.contributor.funder Foundation for Polish Science es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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