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Synthesis of a hybrid Pd-0/Pd-carbide/carbon catalyst material with high for reactions

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Synthesis of a hybrid Pd-0/Pd-carbide/carbon catalyst material with high for reactions

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Nombre: Garcia-Ortiz;Vida ...
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dc.contributor.author Garcia-Ortiz, Andrea es_ES
dc.contributor.author Vidal, Juan D. es_ES
dc.contributor.author Iborra Chornet, Sara es_ES
dc.contributor.author Climent Olmedo, María José es_ES
dc.contributor.author Cored-Bandrés, Jorge es_ES
dc.contributor.author Ruano-Sánchez, Daniel es_ES
dc.contributor.author Pérez-Dieste, Virginia es_ES
dc.contributor.author Concepción Heydorn, Patricia es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2021-04-01T03:31:30Z
dc.date.available 2021-04-01T03:31:30Z
dc.date.issued 2020-09 es_ES
dc.identifier.issn 0021-9517 es_ES
dc.identifier.uri http://hdl.handle.net/10251/164817
dc.description.abstract [EN] We present a highly selective and active Pd carbon catalyst prepared by an easy hydrothermal synthesis method. This synthetic procedure allows the stabilization under mild conditions of interstitial carbon atoms on the surface of a Pd-0 carbon catalyst. The so formed Pd carbide phase appears on the upper surface layers of the Pd carbon catalyst, as demonstrated by X-ray photoelectron depth profile analysis using variable synchrotron X-ray energies. The presence of carbon in the palladium carbide species modifies the electronic state of surface Pd atoms, resulting in more electron positive Pd species (Pdd+). This influences the adsorption of reactants and reaction intermediates during the hydrogenation of alkynes, dienes and imines, resulting in high selectivities at practically 100% conversion. (C) 2020 Elsevier Inc. All rights reserved. es_ES
dc.description.sponsorship The research leading to these results has received funding from the Spanish Ministry of Science, Innovation and Universities through "Severo Ochoa"Excellence Programme (SEV-2016-0683) and the PGC2018-097277-B-100 project. The authors also thank the Microscopy Service of UPV for kind help on measurements. A. Garcia-Ortiz thanks "Severo Ochoa" Programme (SEV-2016-0683) for a predoctoral fellowship. J. Cored thanks the Spanish Government (MINECO) for a "Severo Ochoa"grant (BES-2015-075748). D. R. thanks European Research Council project SYNCATMATCH (671093). The NAP-XPS experiments were performed at the NAPP branch of the CIRCE beamline at the ALBA Synchrotron with the collaboration of ALBA staff. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Journal of Catalysis es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Palladium carbide es_ES
dc.subject Selective hydrogenation es_ES
dc.subject Reductive amination es_ES
dc.subject Synchrotron XPS es_ES
dc.subject Hydrothermal synthesis es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Synthesis of a hybrid Pd-0/Pd-carbide/carbon catalyst material with high for reactions es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.jcat.2020.06.036 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//BES-2015-075748/ES/BES-2015-075748/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-097277-B-I00/ES/MEJORA DEL CONCEPTO DE BIORREFINERIA MEDIANTE IMPLEMENTACION DE NUEVOS PROCESOS CATALITICOS CON CATALIZADORES SOLIDOS DE METALES NO NOBLES PARA LA PRODUCCION DE BIOCOMPUESTOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Garcia-Ortiz, A.; Vidal, JD.; Iborra Chornet, S.; Climent Olmedo, MJ.; Cored-Bandrés, J.; Ruano-Sánchez, D.; Pérez-Dieste, V.... (2020). Synthesis of a hybrid Pd-0/Pd-carbide/carbon catalyst material with high for reactions. Journal of Catalysis. 389:706-713. https://doi.org/10.1016/j.jcat.2020.06.036 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.jcat.2020.06.036 es_ES
dc.description.upvformatpinicio 706 es_ES
dc.description.upvformatpfin 713 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 389 es_ES
dc.relation.pasarela S\418287 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.description.references Borodziński, A., & Bond, G. C. (2008). Selective Hydrogenation of Ethyne in Ethene‐Rich Streams on Palladium Catalysts, Part 2: Steady‐State Kinetics and Effects of Palladium Particle Size, Carbon Monoxide, and Promoters. Catalysis Reviews, 50(3), 379-469. doi:10.1080/01614940802142102 es_ES
dc.description.references Molnár, Á., Sárkány, A., & Varga, M. (2001). Hydrogenation of carbon–carbon multiple bonds: chemo-, regio- and stereo-selectivity. Journal of Molecular Catalysis A: Chemical, 173(1-2), 185-221. doi:10.1016/s1381-1169(01)00150-9 es_ES
dc.description.references Jones, W., Wells, P. P., Gibson, E. K., Chutia, A., Silverwood, I. P., Catlow, C. R. A., & Bowker, M. (2019). Carbidisation of Pd Nanoparticles by Ethene Decomposition with Methane Production. ChemCatChem, 11(17), 4334-4339. doi:10.1002/cctc.201900795 es_ES
dc.description.references Bugaev, A. L., Guda, A. A., Pankin, I. A., Groppo, E., Pellegrini, R., Longo, A., … Lamberti, C. (2019). The role of palladium carbides in the catalytic hydrogenation of ethylene over supported palladium nanoparticles. Catalysis Today, 336, 40-44. doi:10.1016/j.cattod.2019.02.068 es_ES
dc.description.references Bugaev, A. L., Guda, A. A., Lazzarini, A., Lomachenko, K. A., Groppo, E., Pellegrini, R., … Lamberti, C. (2017). In situ formation of hydrides and carbides in palladium catalyst: When XANES is better than EXAFS and XRD. Catalysis Today, 283, 119-126. doi:10.1016/j.cattod.2016.02.065 es_ES
dc.description.references Teschner, D., Borsodi, J., Wootsch, A., Révay, Z., Hävecker, M., Knop-Gericke, A., … Schlögl, R. (2008). The Roles of Subsurface Carbon and Hydrogen in Palladium-Catalyzed Alkyne Hydrogenation. Science, 320(5872), 86-89. doi:10.1126/science.1155200 es_ES
dc.description.references Michaelides, A., Hu, P., & Alavi, A. (1999). Physical origin of the high reactivity of subsurface hydrogen in catalytic hydrogenation. The Journal of Chemical Physics, 111(4), 1343-1345. doi:10.1063/1.479392 es_ES
dc.description.references Khan, N. A., Shaikhutdinov, S., & Freund, H.-J. (2006). Acetylene and Ethylene Hydrogenation on Alumina Supported Pd-Ag Model Catalysts. Catalysis Letters, 108(3-4), 159-164. doi:10.1007/s10562-006-0041-y es_ES
dc.description.references Teschner, D., Révay, Z., Borsodi, J., Hävecker, M., Knop‐Gericke, A., Schlögl, R., … Sautet, P. (2008). Understanding Palladium Hydrogenation Catalysts: When the Nature of the Reactive Molecule Controls the Nature of the Catalyst Active Phase. Angewandte Chemie, 120(48), 9414-9418. doi:10.1002/ange.200802134 es_ES
dc.description.references Teschner, D., Borsodi, J., Kis, Z., Szentmiklósi, L., Révay, Z., Knop-Gericke, A., … Sautet, P. (2010). Role of Hydrogen Species in Palladium-Catalyzed Alkyne Hydrogenation. The Journal of Physical Chemistry C, 114(5), 2293-2299. doi:10.1021/jp9103799 es_ES
dc.description.references Torres, D., Cinquini, F., & Sautet, P. (2013). Pressure and Temperature Effects on the Formation of a Pd/C Surface Carbide: Insights into the Role of Pd/C as a Selective Catalytic State for the Partial Hydrogenation of Acetylene. The Journal of Physical Chemistry C, 117(21), 11059-11065. doi:10.1021/jp400059m es_ES
dc.description.references Singh, N., Nguyen, M.-T., Cantu, D. C., Mehdi, B. L., Browning, N. D., Fulton, J. L., … Lercher, J. A. (2018). Carbon-supported Pt during aqueous phenol hydrogenation with and without applied electrical potential: X-ray absorption and theoretical studies of structure and adsorbates. Journal of Catalysis, 368, 8-19. doi:10.1016/j.jcat.2018.09.021 es_ES
dc.description.references Huang, F., Jia, Z., Diao, J., Yuan, H., Su, D., & Liu, H. (2019). Palladium nanoclusters immobilized on defective nanodiamond-graphene core-shell supports for semihydrogenation of phenylacetylene. Journal of Energy Chemistry, 33, 31-36. doi:10.1016/j.jechem.2018.08.006 es_ES
dc.description.references Okitsu, K., Mizukoshi, Y., Bandow, H., Yamamoto, T. A., Nagata, Y., & Maeda, Y. (1997). Synthesis of Palladium Nanoparticles with Interstitial Carbon by Sonochemical Reduction of Tetrachloropalladate(II) in Aqueous Solution. The Journal of Physical Chemistry B, 101(28), 5470-5472. doi:10.1021/jp970415f es_ES
dc.description.references Guo, R., Chen, Q., Li, X., Liu, Y., Wang, C., Bi, W., … Jin, M. (2019). PdCx nanocrystals with tunable compositions for alkyne semihydrogenation. Journal of Materials Chemistry A, 7(9), 4714-4720. doi:10.1039/c8ta12002a es_ES
dc.description.references Beltzung, A., Newton, M. A., Nachtegaal, M., Wu, H., Storti, G., & Morbidelli, M. (2018). Research Update: Distribution and stabilization of Pd catalysts in porous carbon-based supports by aggregation of pre-doped colloidal particles. APL Materials, 6(10), 100704. doi:10.1063/1.5046552 es_ES
dc.description.references Sevilla, M., Fuertes, A. B., & Mokaya, R. (2011). High density hydrogen storage in superactivated carbons from hydrothermally carbonized renewable organic materials. Energy & Environmental Science, 4(4), 1400. doi:10.1039/c0ee00347f es_ES
dc.description.references Liu, L., Gao, F., Concepción, P., & Corma, A. (2017). A new strategy to transform mono and bimetallic non-noble metal nanoparticles into highly active and chemoselective hydrogenation catalysts. Journal of Catalysis, 350, 218-225. doi:10.1016/j.jcat.2017.03.014 es_ES
dc.description.references Makowski, P., Demir Cakan, R., Antonietti, M., Goettmann, F., & Titirici, M.-M. (2008). Selective partial hydrogenation of hydroxy aromatic derivatives with palladium nanoparticles supported on hydrophilic carbon. Chemical Communications, (8), 999. doi:10.1039/b717928f es_ES
dc.description.references Liu, L., Puga, A. V., Cored, J., Concepción, P., Pérez-Dieste, V., García, H., & Corma, A. (2018). Sunlight-assisted hydrogenation of CO 2 into ethanol and C2+ hydrocarbons by sodium-promoted Co@C nanocomposites. Applied Catalysis B: Environmental, 235, 186-196. doi:10.1016/j.apcatb.2018.04.060 es_ES
dc.description.references Liu, L., Concepción, P., & Corma, A. (2016). Non-noble metal catalysts for hydrogenation: A facile method for preparing Co nanoparticles covered with thin layered carbon. Journal of Catalysis, 340, 1-9. doi:10.1016/j.jcat.2016.04.006 es_ES
dc.description.references Cored, J., García-Ortiz, A., Iborra, S., Climent, M. J., Liu, L., Chuang, C.-H., … Corma, A. (2019). Hydrothermal Synthesis of Ruthenium Nanoparticles with a Metallic Core and a Ruthenium Carbide Shell for Low-Temperature Activation of CO2 to Methane. Journal of the American Chemical Society, 141(49), 19304-19311. doi:10.1021/jacs.9b07088 es_ES
dc.description.references C.J. Powell, A.J., NIST Electron Inelastic Mean Free Path Database, version 1.1. National Institute of Standards and Technology: Gaithersburg, MD, 2002. es_ES
dc.description.references Sharma, H., Bhardwaj, M., Kour, M., & Paul, S. (2017). Highly efficient magnetic Pd(0) nanoparticles stabilized by amine functionalized starch for organic transformations under mild conditions. Molecular Catalysis, 435, 58-68. doi:10.1016/j.mcat.2017.03.019 es_ES
dc.description.references Sadezky, A., Muckenhuber, H., Grothe, H., Niessner, R., & Pöschl, U. (2005). Raman microspectroscopy of soot and related carbonaceous materials: Spectral analysis and structural information. Carbon, 43(8), 1731-1742. doi:10.1016/j.carbon.2005.02.018 es_ES
dc.description.references Baylet, A., Marécot, P., Duprez, D., Castellazzi, P., Groppi, G., & Forzatti, P. (2011). In situ Raman and in situ XRD analysis of PdO reduction and Pd° oxidation supported on γ-Al2O3 catalyst under different atmospheres. Physical Chemistry Chemical Physics, 13(10), 4607. doi:10.1039/c0cp01331e es_ES
dc.description.references C.D. Wagner, A.V. Naumkin, A. Kraut-Vass, J.W. Allison, C.J. Powell, J.R.Jr. Rumble, NIST Standart Reference Database 20, Version 3.4 can be found under http://srdata.nist.gov/xps/, 2003. es_ES
dc.description.references Tian, H., Huang, F., Zhu, Y., Liu, S., Han, Y., Jaroniec, M., … Liu, J. (2018). The Development of Yolk–Shell‐Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability. Advanced Functional Materials, 28(32), 1801737. doi:10.1002/adfm.201801737 es_ES
dc.description.references Peng, L., Zhang, J., Yang, S., Han, B., Sang, X., Liu, C., & Yang, G. (2015). The ionic liquid microphase enhances the catalytic activity of Pd nanoparticles supported by a metal–organic framework. Green Chem., 17(8), 4178-4182. doi:10.1039/c5gc01333j es_ES
dc.description.references Boucher, M. B., Zugic, B., Cladaras, G., Kammert, J., Marcinkowski, M. D., Lawton, T. J., … Flytzani-Stephanopoulos, M. (2013). Single atom alloy surface analogs in Pd0.18Cu15 nanoparticles for selective hydrogenation reactions. Physical Chemistry Chemical Physics, 15(29), 12187. doi:10.1039/c3cp51538a es_ES
dc.description.references Armbrüster, M., Kovnir, K., Behrens, M., Teschner, D., Grin, Y., & Schlögl, R. (2010). Pd−Ga Intermetallic Compounds as Highly Selective Semihydrogenation Catalysts. Journal of the American Chemical Society, 132(42), 14745-14747. doi:10.1021/ja106568t es_ES
dc.description.references Panpranot, J., Phandinthong, K., Sirikajorn, T., Arai, M., & Praserthdam, P. (2007). Impact of palladium silicide formation on the catalytic properties of Pd/SiO2 catalysts in liquid-phase semihydrogenation of phenylacetylene. Journal of Molecular Catalysis A: Chemical, 261(1), 29-35. doi:10.1016/j.molcata.2006.07.053 es_ES
dc.description.references Hu, J., Zhou, Z., Zhang, R., Li, L., & Cheng, Z. (2014). Selective hydrogenation of phenylacetylene over a nano-Pd/α-Al2O3 catalyst. Journal of Molecular Catalysis A: Chemical, 381, 61-69. doi:10.1016/j.molcata.2013.10.008 es_ES
dc.description.references Markov, P. V., Mashkovsky, I. S., Bragina, G. O., Wärnå, J., Gerasimov, E. Y., Bukhtiyarov, V. I., … Murzin, D. Y. (2019). Particle size effect in liquid-phase hydrogenation of phenylacetylene over Pd catalysts: Experimental data and theoretical analysis. Chemical Engineering Journal, 358, 520-530. doi:10.1016/j.cej.2018.10.016 es_ES
dc.description.references Huang, T. S., Wang, Y. H., Jiang, J. Y., & Jin, Z. L. (2008). PEG-stabilized palladium nanoparticles: An efficient and recyclable catalyst for the selective hydrogenation of 1,5-cyclooctadiene in thermoregulated PEG biphase system. Chinese Chemical Letters, 19(1), 102-104. doi:10.1016/j.cclet.2007.10.042 es_ES
dc.description.references Yuan, T., Gong, H., Kailasam, K., Zhao, Y., Thomas, A., & Zhu, J. (2015). Controlling hydrogenation selectivity with Pd catalysts on carbon nitrides functionalized silica. Journal of Catalysis, 326, 38-42. doi:10.1016/j.jcat.2015.03.007 es_ES
dc.description.references García-Ortiz, A., Vidal, J. D., Climent, M. J., Concepción, P., Corma, A., & Iborra, S. (2019). Chemicals from Biomass: Selective Synthesis of N-Substituted Furfuryl Amines by the One-Pot Direct Reductive Amination of Furanic Aldehydes. ACS Sustainable Chemistry & Engineering, 7(6), 6243-6250. doi:10.1021/acssuschemeng.8b06631 es_ES
dc.description.references Vidal, J. D., Climent, M. J., Concepcion, P., Corma, A., Iborra, S., & Sabater, M. J. (2015). Chemicals from Biomass: Chemoselective Reductive Amination of Ethyl Levulinate with Amines. ACS Catalysis, 5(10), 5812-5821. doi:10.1021/acscatal.5b01113 es_ES
dc.description.references T. Schiffer, G. Oenbrink, Ullmann’s Encyclopedia of Industrial Chemistry, Wiley-Interscience, New York, 2009, 11, 37–40. es_ES
dc.description.references Concepción, P., García, S., Hernández-Garrido, J. C., Calvino, J. J., & Corma, A. (2016). A promoting effect of dilution of Pd sites due to gold surface segregation under reaction conditions on supported Pd–Au catalysts for the selective hydrogenation of 1,5-cyclooctadiene. Catalysis Today, 259, 213-221. doi:10.1016/j.cattod.2015.07.022 es_ES
dc.description.references Mubarak, A. T., Alhanash, A. M., Benaissa, M., Hegazy, H. H., & Hamdy, M. S. (2019). In-situ activation of Pd-TUD-1 during the selective reduction of 1,5-cyclooctadiene. Microporous and Mesoporous Materials, 278, 225-231. doi:10.1016/j.micromeso.2018.11.035 es_ES
dc.description.references Zhang, X., Llabrés i Xamena, F. X., & Corma, A. (2009). Gold(III) – metal organic framework bridges the gap between homogeneous and heterogeneous gold catalysts. Journal of Catalysis, 265(2), 155-160. doi:10.1016/j.jcat.2009.04.021 es_ES
dc.description.references Chatterjee, M., Ishizaka, T., & Kawanami, H. (2016). Reductive amination of furfural to furfurylamine using aqueous ammonia solution and molecular hydrogen: an environmentally friendly approach. Green Chemistry, 18(2), 487-496. doi:10.1039/c5gc01352f es_ES
dc.description.references Komanoya, T., Kinemura, T., Kita, Y., Kamata, K., & Hara, M. (2017). Electronic Effect of Ruthenium Nanoparticles on Efficient Reductive Amination of Carbonyl Compounds. Journal of the American Chemical Society, 139(33), 11493-11499. doi:10.1021/jacs.7b04481 es_ES
dc.description.references Bagal, D. B., Watile, R. A., Khedkar, M. V., Dhake, K. P., & Bhanage, B. M. (2012). PS-Pd–NHC: an efficient and heterogeneous recyclable catalyst for direct reductive amination of carbonyl compounds with primary/secondary amines in aqueous medium. Catal. Sci. Technol., 2(2), 354-358. doi:10.1039/c1cy00392e es_ES
dc.description.references Bugaev, A. L., Usoltsev, O. A., Lazzarini, A., Lomachenko, K. A., Guda, A. A., Pellegrini, R., … Lamberti, C. (2018). Time-resolved operando studies of carbon supported Pd nanoparticles under hydrogenation reactions by X-ray diffraction and absorption. Faraday Discussions, 208, 187-205. doi:10.1039/c7fd00211d es_ES
dc.description.references Stytsenko, V. D., & Mel’nikov, D. P. (2016). Selective hydrogenation of dienic and acetylenic compounds on metal-containing catalysts. Russian Journal of Physical Chemistry A, 90(5), 932-942. doi:10.1134/s0036024416040294 es_ES


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