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Nitro functionalized chromium terephthalate metal-organic framework as multifunctional solid acid for the synthesis of benzimidazoles

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Nitro functionalized chromium terephthalate metal-organic framework as multifunctional solid acid for the synthesis of benzimidazoles

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dc.contributor.author Vallés-García, Cristina es_ES
dc.contributor.author Cabrero-Antonino, Maria es_ES
dc.contributor.author Navalón Oltra, Sergio es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author Dhakshinamoorthy, Amarajothi es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2021-04-17T03:32:40Z
dc.date.available 2021-04-17T03:32:40Z
dc.date.issued 2020-02-15 es_ES
dc.identifier.issn 0021-9797 es_ES
dc.identifier.uri http://hdl.handle.net/10251/165283
dc.description.abstract [EN] In the present work, nitro functionalized chromium terephthalate [MIL-101(Cr)-NO2] metal-organic framework is prepared and characterized by powder X-ray diffraction (XRD), elemental analysis, infrared spectroscopy (IR), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and Brun auer-Emmett-Teller (BET) surface area. The inherent Lewis acidity of MIL-101(Cr)-NO2 is confirmed by FT-IR spectroscopy using CD3CN as a probe molecule. The performance of MIL-101(Cr)-NO2 as bifunctional catalyst (acid and redox) promoting the synthesis of wide range of benzimidazoles has been examined by catalyzed condensation on acid sites and subsequent oxidative dehydrogenation. The catalytic activity of MIL-101(Cr)-NO2 is found to be superior than analogues catalysts like MIL-101(Cr)-S0(3)H, MIL-101(Cr)-NH2, U10-66(Zr), Ui0-66(Zr)-NO2, MIL-100(Fe) and Cu-3(BTC)(2) (BTC: 1,35-benzenetricarboxylate) under identical reaction conditions, The structural stability of MIL-101(Cr)-NO2 is supported by leaching analysis and reusability tests. MIL-101(Cr)-NO2 solid is used five times without decay in its activity. Comparison of the fresh and five times used MIL-101(Cr)-NO2 solids by powder XRD, SEM and elemental analysis indicate identical crystallinity, morphology and the absence of chromium leaching, respectively. (C) 2019 Elsevier Inc. All rights reserved. es_ES
dc.description.sponsorship AD thanks the University Grants Commission, New Delhi, for the award of an Assistant Professorship under its Faculty Recharge Programme. AD also thanks the Department of Science and Technology, India, for the financial support through Extra Mural Research Funding (EMR/2016/006500). Financial support by the Spanish Ministry of Science and Innovation (Severo Ochoa and RTI2018-098237-CO21) and Generalitat Valenciana (Prometeo 2017/083) is gratefully acknowledged. S.N. thanks financial support by the Fundacion Ramon Areces (XVIII Concurso Nacional para la Adjudication de Ayudas a la Investigacion en Ciencias de la Vida y de la Materia, 2016), Ministerio de Ciencia, Innovation y Universidades RTI2018-099482-A-I00 project and Generalitat Valenciana grupos de investigacion consolidables 2019 (AICO/2019/214) project. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Journal of Colloid and Interface Science es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Benzimidazole es_ES
dc.subject Bifunctional solid catalyst es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Metal-organic frameworks es_ES
dc.subject Tandem reaction es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.title Nitro functionalized chromium terephthalate metal-organic framework as multifunctional solid acid for the synthesis of benzimidazoles es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.jcis.2019.10.093 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/DST//EMR%2F2016%2F006500/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2017%2F083/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-098237-B-C21/ES/HETEROUNIONES DE GRAFENO CON CONFIGURACION CONTROLADA. SINTESIS Y APLICACIONES COMO SOPORTE EN CATALISIS Y EN ELECTRODOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-099482-A-I00/ES/DESCOMPOSICION FOTOCATALITICA DEL AGUA ASISTIDA POR LUZ VISIBLE EMPLEANDO MATERIALES NOVEDOSOS Y MULTIFUNCIONALES UIO-66%2F67/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//AICO%2F2019%2F214/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Vallés-García, C.; Cabrero-Antonino, M.; Navalón Oltra, S.; Alvaro Rodríguez, MM.; Dhakshinamoorthy, A.; García Gómez, H. (2020). Nitro functionalized chromium terephthalate metal-organic framework as multifunctional solid acid for the synthesis of benzimidazoles. Journal of Colloid and Interface Science. 560:885-893. https://doi.org/10.1016/j.jcis.2019.10.093 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.jcis.2019.10.093 es_ES
dc.description.upvformatpinicio 885 es_ES
dc.description.upvformatpfin 893 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 560 es_ES
dc.identifier.pmid 31718791 es_ES
dc.relation.pasarela S\405839 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Fundación Ramón Areces es_ES
dc.contributor.funder University Grants Commission, India es_ES
dc.contributor.funder Department of Science and Technology, Ministry of Science and Technology, India es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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