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Al2O3-Supported W-V-O bronzes catalysts for oxidative dehydrogenation of ethane

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Al2O3-Supported W-V-O bronzes catalysts for oxidative dehydrogenation of ethane

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dc.contributor.author Benomar, S. es_ES
dc.contributor.author Chieregato, A. es_ES
dc.contributor.author Masso, A. es_ES
dc.contributor.author Soriano Rodríguez, Mª Dolores es_ES
dc.contributor.author Vidal Moya, José Alejandro es_ES
dc.contributor.author Blasco Lanzuela, Teresa es_ES
dc.contributor.author Issaadi, R. es_ES
dc.contributor.author López Nieto, José Manuel es_ES
dc.date.accessioned 2021-04-17T03:32:57Z
dc.date.available 2021-04-17T03:32:57Z
dc.date.issued 2020-12-07 es_ES
dc.identifier.issn 2044-4753 es_ES
dc.identifier.uri http://hdl.handle.net/10251/165288
dc.description.abstract [EN] Supported vanadium-containing hexagonal tungsten bronzes (HTBs) were prepared for the first time using a combination of a new soft synthetic procedure and fine-tuned heat treatments. The characterization of heat-treated samples indicates that both unsupported and Al2O3-supported materials present mainly vanadium-containing crystals with HTB structure smaller in the supported materials. Raman, diffuse reflectance UV-visible and EPR spectroscopic results suggest the presence of different V species depending on the V loading and catalyst composition. When used as catalysts for ethane oxidative dehydrogenation (ODH), selected supported vanadium-HTBs show selectivity to ethylene as high as 80% at ethane conversion of around 18%. These values position these new materials among the most active and selective catalysts so far reported in the literature for ethane ODH over supported vanadium oxide catalysts. es_ES
dc.description.sponsorship The authors acknowledge the DGICYT in Spain (projects RTI2018-099668-B-C21 and SEV-2016-0683) for financial support. The research group of Prof. Fabrizio Cavani (University of Bologna, Italy) and Consorzio INSTM (Firenze) are gratefully acknowledged for a PhD grant to A. C. The authors also thank the Electron Microscopy Service of Universitat Politecnica de Valencia for its support. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Catalysis Science & Technology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.title Al2O3-Supported W-V-O bronzes catalysts for oxidative dehydrogenation of ethane es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/d0cy01220c es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-099668-B-C21/ES/VALORIZACION DE CO2: CAPTURA, Y TRANSFORMACION CATALITICA PARA ALMACENAMIENTO DE ENERGIA, COMBUSTIBLES Y PRODUCTOS QUIMICOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Benomar, S.; Chieregato, A.; Masso, A.; Soriano Rodríguez, MD.; Vidal Moya, JA.; Blasco Lanzuela, T.; Issaadi, R.... (2020). Al2O3-Supported W-V-O bronzes catalysts for oxidative dehydrogenation of ethane. Catalysis Science & Technology. 10(23):8064-8076. https://doi.org/10.1039/d0cy01220c es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/d0cy01220c es_ES
dc.description.upvformatpinicio 8064 es_ES
dc.description.upvformatpfin 8076 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 10 es_ES
dc.description.issue 23 es_ES
dc.relation.pasarela S\431393 es_ES
dc.contributor.funder Università di Bologna es_ES
dc.contributor.funder Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali, Italia es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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