- -

Nature and evolution of Pd catalysts supported on activated carbon fibers during the catalytic reduction of bromate in water

RiuNet: Repositorio Institucional de la Universidad Politécnica de Valencia

Compartir/Enviar a

Citas

Estadísticas

  • Estadisticas de Uso

Nature and evolution of Pd catalysts supported on activated carbon fibers during the catalytic reduction of bromate in water

Mostrar el registro sencillo del ítem

Ficheros en el ítem

Thumbnail
Nombre: Cerrllo;Lopes;Rey ...
Tamaño: 1002.Kb
Formato: PDF
Descripción: Versión del Autor.
Abrir
[Cerrado]
Nombre: versioneditor.pdf
Tamaño: 1.446Mb
Formato: PDF
Descripción: Versión editorial
Solicitar una copia al autor
dc.contributor.author Cerrillo, Jose L. es_ES
dc.contributor.author Lopes, Christian W. es_ES
dc.contributor.author Rey Garcia, Fernando es_ES
dc.contributor.author Agostini, Giovanni es_ES
dc.contributor.author Kiwi-Minsker, Lioubov es_ES
dc.contributor.author Palomares Gimeno, Antonio Eduardo es_ES
dc.date.accessioned 2021-04-17T03:33:41Z
dc.date.available 2021-04-17T03:33:41Z
dc.date.issued 2020-06-07 es_ES
dc.identifier.issn 2044-4753 es_ES
dc.identifier.uri http://hdl.handle.net/10251/165305
dc.description.abstract [EN] Catalytic hydrogenation of bromate using Pd catalysts supported on activated carbon fibers is a smart solution to treat bromate polluted water. These catalysts have been analyzed by different techniques for an in-deep characterization of the active sites. The in situ X-ray absorption spectroscopy and the CO chemisorption studies showed that Pd-0 nanoparticles with different crystal sizes were generated on the support during hydrogen activation at 200 degrees C and that the PdHx-phase was formed during the cooling to room temperature. As PdHx species formed on Pd-0 nanoparticles are responsible for bromate reduction, the most active catalysts are those having Pd-0 nanoparticles with large crystal sizes, where PdHx species are easily formed. The catalysts are fully stable in succesive reaction runs. It has been also shown that bromate reduction rate depends on the bromate concentration and on the hydrogen partial pressure, with a pseudo-first reaction order towards both reactants. es_ES
dc.description.sponsorship Authors thank the Spanish Ministry of Economy and Competitiveness through RTI2018-101784-B-I00 (MINECO/FEDER) and SEV-2016-0683 projects for the financial support. We gratefully acknowledge ALBA synchrotron for allocating beamtime (proposal 2015091414) and CLAESS beamline staff for their technical support during our experiment. C. W. Lopes (Science without Frontiers -Process no. 13191/13-6) thanks CAPES for a predoctoral fellowship. J. L. Cerrillo is grateful to MINECO for the Severo Ochoa contract for PhD formation (SVP-2014-068600). L. Kiwi-Minsker acknowledges financial support provided by Russian Science Foundation (project 15-19-20023). Authors also thank Kynol Europa GmbH for the supply of the activated carbon fibers. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Catalysis Science & Technology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Nature and evolution of Pd catalysts supported on activated carbon fibers during the catalytic reduction of bromate in water es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/d0cy00606h es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CAPES//13191%2F13-6/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SVP-2014-068600/ES/SVP-2014-068600/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101784-B-I00/ES/NUEVOS MATERIALES ZEOLITICOS PARA PROCESOS DE SEPARACION SELECTIVA DE GASES, APLICACIONES MEDIOAMBIENTALES Y CONSERVACION DE ALIMENTOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/RFBR//5-19-20023/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Cerrillo, JL.; Lopes, CW.; Rey Garcia, F.; Agostini, G.; Kiwi-Minsker, L.; Palomares Gimeno, AE. (2020). Nature and evolution of Pd catalysts supported on activated carbon fibers during the catalytic reduction of bromate in water. Catalysis Science & Technology. 10(11):3646-3653. https://doi.org/10.1039/d0cy00606h es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/d0cy00606h es_ES
dc.description.upvformatpinicio 3646 es_ES
dc.description.upvformatpfin 3653 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 10 es_ES
dc.description.issue 11 es_ES
dc.relation.pasarela S\420369 es_ES
dc.contributor.funder Russian Science Foundation es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Coordenaçao de Aperfeiçoamento de Pessoal de Nível Superior, Brasil es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.description.references Naushad, M., Khan, M. R., ALOthman, Z. A., AlSohaimi, I., Rodriguez-Reinoso, F., Turki, T. M., & Ali, R. (2015). Removal of BrO3 − from drinking water samples using newly developed agricultural waste-based activated carbon and its determination by ultra-performance liquid chromatography-mass spectrometry. Environmental Science and Pollution Research, 22(20), 15853-15865. doi:10.1007/s11356-015-4786-y es_ES
dc.description.references BUTLER, R., GODLEY, A., LYTTON, L., & CARTMELL, E. (2005). Bromate Environmental Contamination: Review of Impact and Possible Treatment. Critical Reviews in Environmental Science and Technology, 35(3), 193-217. doi:10.1080/10643380590917888 es_ES
dc.description.references Weinberg, H. S., Delcomyn, C. A., & Unnam, V. (2003). Bromate in Chlorinated Drinking Waters:  Occurrence and Implications for Future Regulation. Environmental Science & Technology, 37(14), 3104-3110. doi:10.1021/es026400z es_ES
dc.description.references OMS , Bromate in Drinking-water - Guidelines for Drinking-water Quality , WHO , 2005 es_ES
dc.description.references Jabłońska, M., Król, A., Kukulska-Zając, E., Tarach, K., Girman, V., Chmielarz, L., & Góra-Marek, K. (2015). Zeolites Y modified with palladium as effective catalysts for low-temperature methanol incineration. Applied Catalysis B: Environmental, 166-167, 353-365. doi:10.1016/j.apcatb.2014.11.047 es_ES
dc.description.references Pergher, S. B. ., Dallago, R. M., Veses, R. C., Gigola, C. E., & Baibich, I. M. (2004). Pd/NaY-zeolite and Pd-W/NaY-zeolite catalysts: preparation, characterization and NO decomposition activity. Journal of Molecular Catalysis A: Chemical, 209(1-2), 107-115. doi:10.1016/j.molcata.2003.08.005 es_ES
dc.description.references Chaplin, B. P., Reinhard, M., Schneider, W. F., Schüth, C., Shapley, J. R., Strathmann, T. J., & Werth, C. J. (2012). Critical Review of Pd-Based Catalytic Treatment of Priority Contaminants in Water. Environmental Science & Technology, 46(7), 3655-3670. doi:10.1021/es204087q es_ES
dc.description.references Höller, V., Rådevik, K., Yuranov, I., Kiwi-Minsker, L., & Renken, A. (2001). Reduction of nitrite-ions in water over Pd-supported on structured fibrous materials. Applied Catalysis B: Environmental, 32(3), 143-150. doi:10.1016/s0926-3373(01)00139-4 es_ES
dc.description.references Shen, W.-J., Ichihashi, Y., Ando, H., Okumura, M., Haruta, M., & Matsumura, Y. (2001). Influence of palladium precursors on methanol synthesis from CO hydrogenation over Pd/CeO2 catalysts prepared by deposition–precipitation method. Applied Catalysis A: General, 217(1-2), 165-172. doi:10.1016/s0926-860x(01)00606-8 es_ES
dc.description.references Hirayama, J., & Kamiya, Y. (2018). Tin-palladium supported on alumina as a highly active and selective catalyst for hydrogenation of nitrate in actual groundwater polluted with nitrate. Catalysis Science & Technology, 8(19), 4985-4993. doi:10.1039/c8cy00730f es_ES
dc.description.references Palomares, A. E., Franch, C., Yuranova, T., Kiwi-Minsker, L., García-Bordeje, E., & Derrouiche, S. (2014). The use of Pd catalysts on carbon-based structured materials for the catalytic hydrogenation of bromates in different types of water. Applied Catalysis B: Environmental, 146, 186-191. doi:10.1016/j.apcatb.2013.02.056 es_ES
dc.description.references Chen, H., Xu, Z., Wan, H., Zheng, J., Yin, D., & Zheng, S. (2010). Aqueous bromate reduction by catalytic hydrogenation over Pd/Al2O3 catalysts. Applied Catalysis B: Environmental, 96(3-4), 307-313. doi:10.1016/j.apcatb.2010.02.021 es_ES
dc.description.references Soares, O. S. G. P., Freitas, C. M. A. S., Fonseca, A. M., Órfão, J. J. M., Pereira, M. F. R., & Neves, I. C. (2016). Bromate reduction in water promoted by metal catalysts prepared over faujasite zeolite. Chemical Engineering Journal, 291, 199-205. doi:10.1016/j.cej.2016.01.093 es_ES
dc.description.references Freitas, C. M. A. S., Soares, O. S. G. P., Órfão, J. J. M., Fonseca, A. M., Pereira, M. F. R., & Neves, I. C. (2015). Highly efficient reduction of bromate to bromide over mono and bimetallic ZSM5 catalysts. Green Chemistry, 17(8), 4247-4254. doi:10.1039/c5gc00777a es_ES
dc.description.references Restivo, J., Soares, O. S. G. P., Órfão, J. J. M., & Pereira, M. F. R. (2015). Bimetallic activated carbon supported catalysts for the hydrogen reduction of bromate in water. Catalysis Today, 249, 213-219. doi:10.1016/j.cattod.2014.10.048 es_ES
dc.description.references Restivo, J., Soares, O. S. G. P., Órfão, J. J. M., & Pereira, M. F. R. (2017). Catalytic reduction of bromate over monometallic catalysts on different powder and structured supports. Chemical Engineering Journal, 309, 197-205. doi:10.1016/j.cej.2016.10.025 es_ES
dc.description.references Soares, O. S. G. P., Ramalho, P. S. F., Fernandes, A., Órfão, J. J. M., & Pereira, M. F. R. (2019). Catalytic bromate reduction in water: Influence of carbon support. Journal of Environmental Chemical Engineering, 7(3), 103015. doi:10.1016/j.jece.2019.103015 es_ES
dc.description.references Perez-Coronado, A. M., Soares, O. S. G. P., Calvo, L., Rodriguez, J. J., Gilarranz, M. A., & Pereira, M. F. R. (2018). Catalytic reduction of bromate over catalysts based on Pd nanoparticles synthesized via water-in-oil microemulsion. Applied Catalysis B: Environmental, 237, 206-213. doi:10.1016/j.apcatb.2018.05.077 es_ES
dc.description.references Li, M., Zhou, X., Sun, J., Fu, H., Qu, X., Xu, Z., & Zheng, S. (2019). Highly effective bromate reduction by liquid phase catalytic hydrogenation over Pd catalysts supported on core-shell structured magnetites: Impact of shell properties. Science of The Total Environment, 663, 673-685. doi:10.1016/j.scitotenv.2019.01.392 es_ES
dc.description.references Chen, X., Huo, X., Liu, J., Wang, Y., Werth, C. J., & Strathmann, T. J. (2017). Exploring beyond palladium: Catalytic reduction of aqueous oxyanion pollutants with alternative platinum group metals and new mechanistic implications. Chemical Engineering Journal, 313, 745-752. doi:10.1016/j.cej.2016.12.058 es_ES
dc.description.references Gao, Y., Sun, W., Yang, W., & Li, Q. (2017). Creation of Pd/Al2O3 Catalyst by a Spray Process for Fixed Bed Reactors and Its Effective Removal of Aqueous Bromate. Scientific Reports, 7(1). doi:10.1038/srep41797 es_ES
dc.description.references Li, M., Hu, Y., Fu, H., Qu, X., Xu, Z., & Zheng, S. (2019). Pt embedded in carbon rods of N-doped CMK-3 as a highly active and stable catalyst for catalytic hydrogenation reduction of bromate. Chemical Communications, 55(78), 11786-11789. doi:10.1039/c9cc05274g es_ES
dc.description.references Marco, Y., García-Bordejé, E., Franch, C., Palomares, A. E., Yuranova, T., & Kiwi-Minsker, L. (2013). Bromate catalytic reduction in continuous mode using metal catalysts supported on monoliths coated with carbon nanofibers. Chemical Engineering Journal, 230, 605-611. doi:10.1016/j.cej.2013.06.040 es_ES
dc.description.references Yuranova, T., Kiwi-Minsker, L., Franch, C., Palomares, A. E., Armenise, S., & García-Bordejé, E. (2013). Nanostructured Catalysts for the Continuous Reduction of Nitrates and Bromates in Water. Industrial & Engineering Chemistry Research, 52(39), 13930-13937. doi:10.1021/ie302977h es_ES
dc.description.references Palomares, A. E., Franch, C., & Corma, A. (2011). A study of different supports for the catalytic reduction of nitrates from natural water with a continuous reactor. Catalysis Today, 172(1), 90-94. doi:10.1016/j.cattod.2011.05.015 es_ES
dc.description.references Yuranova, T., Franch, C., Palomares, A. E., Garcia-Bordejé, E., & Kiwi-Minsker, L. (2012). Structured fibrous carbon-based catalysts for continuous nitrate removal from natural water. Applied Catalysis B: Environmental, 123-124, 221-228. doi:10.1016/j.apcatb.2012.04.007 es_ES
dc.description.references Lan, H., Mao, R., Tong, Y., Liu, Y., Liu, H., An, X., & Liu, R. (2016). Enhanced Electroreductive Removal of Bromate by a Supported Pd–In Bimetallic Catalyst: Kinetics and Mechanism Investigation. Environmental Science & Technology, 50(21), 11872-11878. doi:10.1021/acs.est.6b02822 es_ES
dc.description.references Yao, F., Yang, Q., Yan, M., Li, X., Chen, F., Zhong, Y., … Li, X. (2020). Synergistic adsorption and electrocatalytic reduction of bromate by Pd/N-doped loofah sponge-derived biochar electrode. Journal of Hazardous Materials, 386, 121651. doi:10.1016/j.jhazmat.2019.121651 es_ES
dc.description.references Morais, D. F. S., Boaventura, R. A. R., Moreira, F. C., & Vilar, V. J. P. (2019). Advances in bromate reduction by heterogeneous photocatalysis: The use of a static mixer as photocatalyst support. Applied Catalysis B: Environmental, 249, 322-332. doi:10.1016/j.apcatb.2019.02.070 es_ES
dc.description.references Cunha, G. S., Santos, S. G. S., Souza-Chaves, B. M., Silva, T. F. C. V., Bassin, J. P., Dezotti, M. W. C., … Vilar, V. J. P. (2019). Removal of bromate from drinking water using a heterogeneous photocatalytic mili-reactor: impact of the reactor material and water matrix. Environmental Science and Pollution Research, 26(32), 33281-33293. doi:10.1007/s11356-019-06266-9 es_ES
dc.description.references Matatov-Meytal, Y., & Sheintuch, M. (2002). Catalytic fibers and cloths. Applied Catalysis A: General, 231(1-2), 1-16. doi:10.1016/s0926-860x(01)00963-2 es_ES
dc.description.references Joannet, E., Horny, C., Kiwi-Minsker, L., & Renken, A. (2002). Palladium supported on filamentous active carbon as effective catalyst for liquid-phase hydrogenation of 2-butyne-1,4-diol to 2-butene-1,4-diol. Chemical Engineering Science, 57(16), 3453-3460. doi:10.1016/s0009-2509(02)00215-4 es_ES
dc.description.references Crespo-Quesada, M., Dykeman, R. R., Laurenczy, G., Dyson, P. J., & Kiwi-Minsker, L. (2011). Supported nitrogen-modified Pd nanoparticles for the selective hydrogenation of 1-hexyne. Journal of Catalysis, 279(1), 66-74. doi:10.1016/j.jcat.2011.01.003 es_ES
dc.description.references Fang, W., Yang, S., Wang, X.-L., Yuan, T.-Q., & Sun, R.-C. (2017). Manufacture and application of lignin-based carbon fibers (LCFs) and lignin-based carbon nanofibers (LCNFs). Green Chemistry, 19(8), 1794-1827. doi:10.1039/c6gc03206k es_ES
dc.description.references Yaseneva, P., Marti, C. F., Palomares, E., Fan, X., Morgan, T., Perez, P. S., … Lapkin, A. A. (2014). Efficient reduction of bromates using carbon nanofibre supported catalysts: Experimental and a comparative life cycle assessment study. Chemical Engineering Journal, 248, 230-241. doi:10.1016/j.cej.2014.03.034 es_ES
dc.description.references Shim, J.-W., Park, S.-J., & Ryu, S.-K. (2001). Effect of modification with HNO3 and NaOH on metal adsorption by pitch-based activated carbon fibers. Carbon, 39(11), 1635-1642. doi:10.1016/s0008-6223(00)00290-6 es_ES
dc.description.references Rouquerol, J., Llewellyn, P., & Rouquerol, F. (2007). Is the bet equation applicable to microporous adsorbents? Characterization of Porous Solids VII - Proceedings of the 7th International Symposium on the Characterization of Porous Solids (COPS-VII), Aix-en-Provence, France, 26-28 May 2005, 49-56. doi:10.1016/s0167-2991(07)80008-5 es_ES
dc.description.references J. R. Anderson , Structure of metallic catalysts , Academic Press , London-New York , 1918 es_ES
dc.description.references Martínez, A., Arribas, M. A., Derewinski, M., & Burkat-Dulak, A. (2010). Enhanced sulfur resistance of bifunctional Pd/HZSM-5 catalyst comprising hierarchical carbon-templated zeolite. Applied Catalysis A: General, 379(1-2), 188-197. doi:10.1016/j.apcata.2010.03.023 es_ES
dc.description.references Ravel, B., & Newville, M. (2005). ATHENA,ARTEMIS,HEPHAESTUS: data analysis for X-ray absorption spectroscopy usingIFEFFIT. Journal of Synchrotron Radiation, 12(4), 537-541. doi:10.1107/s0909049505012719 es_ES
dc.description.references Groppo, E., Agostini, G., Borfecchia, E., Wei, L., Giannici, F., Portale, G., … Lamberti, C. (2014). Formation and Growth of Pd Nanoparticles Inside a Highly Cross-Linked Polystyrene Support: Role of the Reducing Agent. The Journal of Physical Chemistry C, 118(16), 8406-8415. doi:10.1021/jp5003897 es_ES
dc.description.references Groppo, E., Liu, W., Zavorotynska, O., Agostini, G., Spoto, G., Bordiga, S., … Zecchina, A. (2010). Subnanometric Pd Particles Stabilized Inside Highly Cross-Linked Polymeric Supports. Chemistry of Materials, 22(7), 2297-2308. doi:10.1021/cm903176d es_ES
dc.description.references Bugaev, A. L., Guda, A. A., Lazzarini, A., Lomachenko, K. A., Groppo, E., Pellegrini, R., … Lamberti, C. (2017). In situ formation of hydrides and carbides in palladium catalyst: When XANES is better than EXAFS and XRD. Catalysis Today, 283, 119-126. doi:10.1016/j.cattod.2016.02.065 es_ES
dc.description.references Fernández-García, M. (2002). XANES analysis of catalytic systems under reaction conditions. Catalysis Reviews, 44(1), 59-121. doi:10.1081/cr-120001459 es_ES
dc.description.references Lopes, C. W., Cerrillo, J. L., Palomares, A. E., Rey, F., & Agostini, G. (2018). An in situ XAS study of the activation of precursor-dependent Pd nanoparticles. Physical Chemistry Chemical Physics, 20(18), 12700-12709. doi:10.1039/c8cp00517f es_ES
dc.description.references Wang, J., Wang, Q., Jiang, X., Liu, Z., Yang, W., & Frenkel, A. I. (2014). Determination of Nanoparticle Size by Measuring the Metal–Metal Bond Length: The Case of Palladium Hydride. The Journal of Physical Chemistry C, 119(1), 854-861. doi:10.1021/jp510730a es_ES
dc.description.references Srabionyan, V. V., Bugaev, A. L., Pryadchenko, V. V., Avakyan, L. A., van Bokhoven, J. A., & Bugaev, L. A. (2014). EXAFS study of size dependence of atomic structure in palladium nanoparticles. Journal of Physics and Chemistry of Solids, 75(4), 470-476. doi:10.1016/j.jpcs.2013.12.012 es_ES
dc.description.references Franch, C., Rodríguez-Castellón, E., Reyes-Carmona, Á., & Palomares, A. E. (2012). Characterization of (Sn and Cu)/Pd catalysts for the nitrate reduction in natural water. Applied Catalysis A: General, 425-426, 145-152. doi:10.1016/j.apcata.2012.03.015 es_ES
dc.description.references Dong, Z., Dong, W., Sun, F., Zhu, R., & Ouyang, F. (2012). Effects of preparation conditions on catalytic activity of Ru/AC catalyst to reduce bromate ion in water. Reaction Kinetics, Mechanisms and Catalysis, 107(1), 231-244. doi:10.1007/s11144-012-0473-x es_ES
dc.description.references Restivo, J., Soares, O. S. G. P., Órfão, J. J. M., & Pereira, M. F. R. (2015). Metal assessment for the catalytic reduction of bromate in water under hydrogen. Chemical Engineering Journal, 263, 119-126. doi:10.1016/j.cej.2014.11.052 es_ES
dc.description.references Siddiqui, M., Zhai, W., Amy, G., & Mysore, C. (1996). Bromate ion removal by activated carbon. Water Research, 30(7), 1651-1660. doi:10.1016/0043-1354(96)00070-x es_ES
dc.description.references Sun, J., Zhang, J., Fu, H., Wan, H., Wan, Y., Qu, X., … Zheng, S. (2018). Enhanced catalytic hydrogenation reduction of bromate on Pd catalyst supported on CeO2 modified SBA-15 prepared by strong electrostatic adsorption. Applied Catalysis B: Environmental, 229, 32-40. doi:10.1016/j.apcatb.2018.02.009 es_ES
dc.description.references Sun, W., Li, Q., Gao, S., & Shang, J. K. (2013). Highly efficient catalytic reduction of bromate in water over a quasi-monodisperse, superparamagnetic Pd/Fe3O4 catalyst. Journal of Materials Chemistry A, 1(32), 9215. doi:10.1039/c3ta11455d es_ES


Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem