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The Influence of the Support on the Activity of Mn-Fe Catalysts Used for the Selective Catalytic Reduction of NOx with Ammonia

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The Influence of the Support on the Activity of Mn-Fe Catalysts Used for the Selective Catalytic Reduction of NOx with Ammonia

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dc.contributor.author López-Hernández, Irene es_ES
dc.contributor.author Mengual Cuquerella, Jesús es_ES
dc.contributor.author Palomares Gimeno, Antonio Eduardo es_ES
dc.date.accessioned 2021-04-21T03:31:18Z
dc.date.available 2021-04-21T03:31:18Z
dc.date.issued 2020-01 es_ES
dc.identifier.uri http://hdl.handle.net/10251/165399
dc.description.abstract [EN] Mono and bimetallic Mn-Fe catalysts supported on different materials were prepared and their catalytic performance in the NH3-SCR of NOx was investigated. It was shown that Mn and Fe have a synergic effect that enhances the activity at low temperature. Nevertheless, the activity of the bimetallic catalysts depends very much on the support selected. The influence of the support on the catalyst activity has been studied using materials with different textural and acid-base properties. Microporous (BEA-zeolite), mesoporous (SBA15 and MCM41) and bulk (metallic oxides) materials with different acidity have been used as supports for the Mn-Fe catalysts. It has been shown that the activity depends on the acidity of the support and on the surface area. Acid sites are necessary for ammonia adsorption and high surface area produces a better dispersion of the active sites resulting in improved redox properties. The best results have been obtained with the catalysts supported on alumina and on beta zeolite. The first one is the most active at low temperatures but it presents some reversible deactivation in the presence of water. The Mn-Fe catalyst supported on beta zeolite is the most active at temperatures higher than 350 degrees C, without any deactivation in the presence of water and with a 100% selectivity towards nitrogen. es_ES
dc.description.sponsorship This research was funded by the Spanish Ministry of Economy and Competitiveness (MINECO/FEDER), projects RTI2018-101784-B-I00 and RTI2018-101033-B-100 and by Generalitat Valenciana and European Social Fund, the pre doctoral grant ACIF2017. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Catalysts es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject NOx es_ES
dc.subject NH3-SCR es_ES
dc.subject Mn es_ES
dc.subject Fe es_ES
dc.subject Catalysts es_ES
dc.subject Support es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.subject.classification TECNOLOGIA DEL MEDIO AMBIENTE es_ES
dc.title The Influence of the Support on the Activity of Mn-Fe Catalysts Used for the Selective Catalytic Reduction of NOx with Ammonia es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/catal10010063 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101784-B-I00/ES/NUEVOS MATERIALES ZEOLITICOS PARA PROCESOS DE SEPARACION SELECTIVA DE GASES, APLICACIONES MEDIOAMBIENTALES Y CONSERVACION DE ALIMENTOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101033-B-I00/ES/DISEÑO DE CATALIZADORES MULTIFUNCIONALES PARA LA CONVERSION EFICIENTE DE BIOGAS Y GAS NATURAL A HIDROCARBUROS DE INTERES INDUSTRIAL/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//ACIF%2F2017%2F079/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Hidráulica y Medio Ambiente - Departament d'Enginyeria Hidràulica i Medi Ambient es_ES
dc.description.bibliographicCitation López-Hernández, I.; Mengual Cuquerella, J.; Palomares Gimeno, AE. (2020). The Influence of the Support on the Activity of Mn-Fe Catalysts Used for the Selective Catalytic Reduction of NOx with Ammonia. Catalysts. 10(1):1-12. https://doi.org/10.3390/catal10010063 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/catal10010063 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 12 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 10 es_ES
dc.description.issue 1 es_ES
dc.identifier.eissn 2073-4344 es_ES
dc.relation.pasarela S\409632 es_ES
dc.contributor.funder European Social Fund es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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