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dc.contributor.author | Moreno, José María | es_ES |
dc.contributor.author | Velty, Alexandra | es_ES |
dc.contributor.author | Vidal Moya, José Alejandro | es_ES |
dc.contributor.author | DÍAZ MORALES, URBANO MANUEL | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.date.accessioned | 2021-04-21T03:31:22Z | |
dc.date.available | 2021-04-21T03:31:22Z | |
dc.date.issued | 2018-04-21 | es_ES |
dc.identifier.issn | 1477-9226 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/165401 | |
dc.description.abstract | [EN] Novel aluminium MOF-type materials structured by 1D subdomains, such as organic-inorganic nanoribbons, were synthesized by modifying the conditions of solvothermal synthesis and the nature of the solvents in the presence of aryl monocarboxylate linkers with long alkyl chains, which acted as growth-modulating agents. Specifically, three different families of materials were prepared with various morphological characteristics: (i) isoreticular MIL-53(Al)-type materials, (ii) mesoscopic metalorganic structures and (iii) lamellar aluminium MOFs. The length of the alkyl chain in the aryl linker and the hydrophobic/hydrophilic nature of the solvothermal synthesis media determined the structuration level that was achieved. The derived Al-MOFs are active and stable catalysts for the synthesis of fine chemicals. This was illustrated by the efficient synthesis of 2,3-dihydro-2,2,4-trimethyl-1H-1,5-benzodiazepine. | es_ES |
dc.description.sponsorship | The authors are grateful for financial support from the Spanish Government under MAT2014-52085-C2-1-P, MAT2017-82288-C2-1-P and Severo Ochoa Excellence Program SEV-2016-0683. J. M. M. thanks predoctoral fellowships from MINECO for economic support. The European Union is also acknowledged for ERC-AdG-2014-671093-SynCatMatch | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | The Royal Society of Chemistry | es_ES |
dc.relation.ispartof | Dalton Transactions | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Growing modulator agents for the synthesis of Al-MOF-type materials based on assembled 1D structural sub-domains | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1039/C8DT00394G | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//MAT2014-52085-C2-1-P/ES/NUEVOS MATERIALES CON DIFERENTES CENTROS ACTIVOS INCORPORADOS EN POSICIONES ESPECIFICAS DE LA RED Y SU APLICACION PARA PROCESOS CATALITICOS MULTI-ETAPA Y NANOTECNOLOGICOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-82288-C2-1-P/ES/MATERIALES HIBRIDOS MULTIFUNCIONALES BASADOS EN NANO-UNIDADES ESTRUCTURALES ACTIVAS/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Moreno, JM.; Velty, A.; Vidal Moya, JA.; Díaz Morales, UM.; Corma Canós, A. (2018). Growing modulator agents for the synthesis of Al-MOF-type materials based on assembled 1D structural sub-domains. Dalton Transactions. 47(15):5492-5502. https://doi.org/10.1039/C8DT00394G | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1039/C8DT00394G | es_ES |
dc.description.upvformatpinicio | 5492 | es_ES |
dc.description.upvformatpfin | 5502 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 47 | es_ES |
dc.description.issue | 15 | es_ES |
dc.identifier.pmid | 29611585 | es_ES |
dc.relation.pasarela | S\361722 | es_ES |
dc.contributor.funder | European Research Council | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
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