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Growing modulator agents for the synthesis of Al-MOF-type materials based on assembled 1D structural sub-domains

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Growing modulator agents for the synthesis of Al-MOF-type materials based on assembled 1D structural sub-domains

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dc.contributor.author Moreno, José María es_ES
dc.contributor.author Velty, Alexandra es_ES
dc.contributor.author Vidal Moya, José Alejandro es_ES
dc.contributor.author DÍAZ MORALES, URBANO MANUEL es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2021-04-21T03:31:22Z
dc.date.available 2021-04-21T03:31:22Z
dc.date.issued 2018-04-21 es_ES
dc.identifier.issn 1477-9226 es_ES
dc.identifier.uri http://hdl.handle.net/10251/165401
dc.description.abstract [EN] Novel aluminium MOF-type materials structured by 1D subdomains, such as organic-inorganic nanoribbons, were synthesized by modifying the conditions of solvothermal synthesis and the nature of the solvents in the presence of aryl monocarboxylate linkers with long alkyl chains, which acted as growth-modulating agents. Specifically, three different families of materials were prepared with various morphological characteristics: (i) isoreticular MIL-53(Al)-type materials, (ii) mesoscopic metalorganic structures and (iii) lamellar aluminium MOFs. The length of the alkyl chain in the aryl linker and the hydrophobic/hydrophilic nature of the solvothermal synthesis media determined the structuration level that was achieved. The derived Al-MOFs are active and stable catalysts for the synthesis of fine chemicals. This was illustrated by the efficient synthesis of 2,3-dihydro-2,2,4-trimethyl-1H-1,5-benzodiazepine. es_ES
dc.description.sponsorship The authors are grateful for financial support from the Spanish Government under MAT2014-52085-C2-1-P, MAT2017-82288-C2-1-P and Severo Ochoa Excellence Program SEV-2016-0683. J. M. M. thanks predoctoral fellowships from MINECO for economic support. The European Union is also acknowledged for ERC-AdG-2014-671093-SynCatMatch es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation info:eu-repo/grantAgreement/MINECO//MAT2014-52085-C2-1-P/ES/NUEVOS MATERIALES CON DIFERENTES CENTROS ACTIVOS INCORPORADOS EN POSICIONES ESPECIFICAS DE LA RED Y SU APLICACION PARA PROCESOS CATALITICOS MULTI-ETAPA Y NANOTECNOLOGICOS/ es_ES
dc.relation MINISTERIO DE ECONOMÍA, INDUSTRIA Y COMPETITIVIDAD/SEV-2016-0683 es_ES
dc.relation Ministerio Ciencia, Innovación y Universidades/MAT2017-82288-C2-1-P es_ES
dc.relation.ispartof Dalton Transactions es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Growing modulator agents for the synthesis of Al-MOF-type materials based on assembled 1D structural sub-domains es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/C8DT00394G es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Moreno, JM.; Velty, A.; Vidal Moya, JA.; Díaz Morales, UM.; Corma Canós, A. (2018). Growing modulator agents for the synthesis of Al-MOF-type materials based on assembled 1D structural sub-domains. Dalton Transactions. 47(15):5492-5502. https://doi.org/10.1039/C8DT00394G es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/C8DT00394G es_ES
dc.description.upvformatpinicio 5492 es_ES
dc.description.upvformatpfin 5502 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 47 es_ES
dc.description.issue 15 es_ES
dc.identifier.pmid 29611585 es_ES
dc.relation.pasarela S\361722 es_ES
dc.contributor.funder Ministerio de Economía, Industria y Competitividad es_ES
dc.contributor.funder European Research Council es_ES
dc.contributor.funder Ministerio de Ciencia, Innovación y Universidades es_ES


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