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Enhanced NiO Dispersion on a High Surface Area Pillared Heterostructure Covered by Niobium Leads to Optimal Behaviour in the Oxidative Dehydrogenation of Ethane

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Enhanced NiO Dispersion on a High Surface Area Pillared Heterostructure Covered by Niobium Leads to Optimal Behaviour in the Oxidative Dehydrogenation of Ethane

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dc.contributor.author Rodríguez-Castellón, Enrique es_ES
dc.contributor.author Delgado-Muñoz, Daniel es_ES
dc.contributor.author Dejoz, Ana es_ES
dc.contributor.author Vázquez, Isabel es_ES
dc.contributor.author Agouram, Said es_ES
dc.contributor.author Cecilia, Juan A. es_ES
dc.contributor.author Solsona, Benjamín es_ES
dc.contributor.author López Nieto, José Manuel es_ES
dc.date.accessioned 2021-04-21T03:31:34Z
dc.date.available 2021-04-21T03:31:34Z
dc.date.issued 2020-07-27 es_ES
dc.identifier.issn 0947-6539 es_ES
dc.identifier.uri http://hdl.handle.net/10251/165407
dc.description This is the peer reviewed version of the following article: E. Rodríguez-Castellón, D. Delgado, A. Dejoz, I. Vázquez, S. Agouram, J. A. Cecilia, B. Solsona, J. M. López Nieto, Chem. Eur. J. 2020, 26, 9371, which has been published in final form at https://doi.org/10.1002/chem.202000832. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. es_ES
dc.description.abstract [EN] A Nb-containing siliceous porous clay heterostructure (PCH) with Nb contents from 0 to 30 wt %) was prepared from a bentonite and used as support in the preparation of supported NiO catalysts with NiO loading from 15 to 80 wt %. Supports and NiO-containing catalysts were characterised by several physicochemical techniques and tested in the oxidative dehydrogenation (ODH) of ethane. The characterisation studies on Nb-containing supports showed the presence of well-anchored Nb(5+)species without the formation of Nb(2)O(5)crystals. High dispersion of nickel oxide with low crystallinity was observed for the Nb-containing PCH supports. In addition, when NiO is supported on these Nb-containing porous clays, it is more effective in the ODH of ethane (ethylene selectivity of ca. 90 %) than NiO supported on the corresponding Nb-free siliceous PCH or on Nb2O5(ethylene selectivities of ca. 30 and 60 %, respectively). Factors such as the NiO-Nb(5+)interaction, the NiO particle size and the properties of surface Ni(n+)species were shown to determine the catalytic performance. es_ES
dc.description.sponsorship The authors would like to acknowledge the Ministerio de Ciencia, Innovacion y Universidades of Spain (CRTl2018-099668-B-C21, RTl2018-099668-B-C22 and MAT2017-84118-C2-1-R projects). Authors from ITQ also thank Project SEV-2016-0683 for supporting this research. D.D. thanks MINECO and Severo Ochoa Excellence Program for his fellowship (SVP-2014-068669). es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Chemistry - A European Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Dehydrogenation es_ES
dc.subject Nickel es_ES
dc.subject Niobium es_ES
dc.subject Porous heterostructures es_ES
dc.subject Supported catalysts es_ES
dc.title Enhanced NiO Dispersion on a High Surface Area Pillared Heterostructure Covered by Niobium Leads to Optimal Behaviour in the Oxidative Dehydrogenation of Ethane es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/chem.202000832 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SVP-2014-068669/ES/SVP-2014-068669/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84118-C2-1-R/ES/VALORIZACION DE RECURSOS NATURALES COMO NUEVOS MATERIALES AVANZADOS :APLICACIONES CATALITICAS Y ELECTROQUIMICAS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-099668-B-C21/ES/VALORIZACION DE CO2: CAPTURA, Y TRANSFORMACION CATALITICA PARA ALMACENAMIENTO DE ENERGIA, COMBUSTIBLES Y PRODUCTOS QUIMICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI//RTl2018-099668-B-C22/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Rodríguez-Castellón, E.; Delgado-Muñoz, D.; Dejoz, A.; Vázquez, I.; Agouram, S.; Cecilia, JA.; Solsona, B.... (2020). Enhanced NiO Dispersion on a High Surface Area Pillared Heterostructure Covered by Niobium Leads to Optimal Behaviour in the Oxidative Dehydrogenation of Ethane. Chemistry - A European Journal. 26(42):9371-9381. https://doi.org/10.1002/chem.202000832 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/chem.202000832 es_ES
dc.description.upvformatpinicio 9371 es_ES
dc.description.upvformatpfin 9381 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 26 es_ES
dc.description.issue 42 es_ES
dc.identifier.pmid 32301531 es_ES
dc.relation.pasarela S\431397 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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