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Photoelectrocatalyzed degradation of organophosphorus pesticide fenamiphos using WO3 nanorods as photoanode

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Photoelectrocatalyzed degradation of organophosphorus pesticide fenamiphos using WO3 nanorods as photoanode

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dc.contributor.author Roselló-Márquez, Gemma es_ES
dc.contributor.author Fernández Domene, Ramón Manuel es_ES
dc.contributor.author Sánchez Tovar, Rita es_ES
dc.contributor.author Garcia-Anton, Jose es_ES
dc.date.accessioned 2021-04-27T03:32:53Z
dc.date.available 2021-04-27T03:32:53Z
dc.date.issued 2020-05 es_ES
dc.identifier.issn 0045-6535 es_ES
dc.identifier.uri http://hdl.handle.net/10251/165605
dc.description.abstract [EN] In this study, WO3 nanostructures were synthesized by the electrochemical anodization technique to use them on the degradation of persistent organic compounds such as the pesticide fenamiphos. The acids electrolyte used during the anodization were two different: 1.5 M H2SO4-0.05 M H2O2 and 1.5 M CH4O3S-0.05 M H2O2. Once the samples have been manufactured, they have been subjected to different tests to analyze the properties of the nanostructures. With Field Emission Scanning Electron Microscopy (FESEM) the samples have been examined morphologically, their composition and crystallinity has been studied through Raman Spectroscopy and their photoelectrochemical behaviour by Photoelectrochemical Impedance Spectroscopy (PEIS). Finally, degradation tests have been carried out using the technique known as photoelectrocatalysis (PEC). The conditions that were applied in this technique were a potential of 1 V-Ag/AgCI and simulated solar illumination. The degradation process was monitored by UV-Visible and High-Performance liquid Chromatography (HPLC) to control the course of the experiment. The nanostructures obtained with 1.5 M CH4O3S-0.05 M H2O2 electrolyte showed a better photoelectrochemical behaviour than nanostructures synthesized with 1.5 M H2SO4-0.05 M H2O2. The fenamiphos degradation was achieved at 2 h of experiment and the intermediate formation was noticed at 1 h of PEC experiment. es_ES
dc.description.sponsorship Authors thank for the financial support to the Ministerio de Economia y Competitividad (Project Code: CTQ2016-79203-R; for its help in the Laser Raman Microscope acquisition (UPOV08-3E-012) and for the co-finance by the European Social Fund). Authors would also like to thank the Ministerio de Ciencia, Innovacion y Universidades (Project Code: CTQ2017-90659-REDT) and the Generalitat Valenciana for its help in the Atomic Force Microscope acquisition (IDIFEDER/2018/044). Ramon M. Fernandez Domene also thanks the UPV for the concession of a post-doctoral grant (PAID-10-17) and Gemma Rosello Marquez also thanks the Generalitat Valenciana for the concession of a pre-doctoral grant (ACIF/2018/159). es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Chemosphere es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Fenamiphos es_ES
dc.subject Photoelectrocatalysis es_ES
dc.subject WO3 nanostructure es_ES
dc.subject Pesticide es_ES
dc.subject Degradation es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Photoelectrocatalyzed degradation of organophosphorus pesticide fenamiphos using WO3 nanorods as photoanode es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.chemosphere.2019.125677 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MEC//UPOV08-3E-001/ES/Utilización de Desktop Microscopy System (DMS) en el campo de los materiales/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UPV//PAID-10-17/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI//CTQ2017-90659-REDT/ES/APLICACIONES MEDIOAMBIENTALES Y ENERGETICAS DE LA TECNOLOGIA ELECTROQUIMICA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2016-79203-R/ES/MODIFICACION DE FOTOCATALIZADORES DE OXIDOS METALICOS NANOESTRUCTURADOS PARA LA ELIMINACION DE FARMACOS Y PRODUCCION ENERGETICA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//IDIFEDER%2F2018%2FA%2F044/ES/MODIFICACIÓN DE FOTOCATALIZADORES DE ÓXIDOS METÁLICOS NANOESTRUCTURADOS PARA LA ELIMINACIÓN DE FÁRMACOS Y PRODUCCIÓN ENERGÉTICA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//ACIF%2F2018%2F159/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Roselló-Márquez, G.; Fernández Domene, RM.; Sánchez Tovar, R.; Garcia-Anton, J. (2020). Photoelectrocatalyzed degradation of organophosphorus pesticide fenamiphos using WO3 nanorods as photoanode. Chemosphere. 246:1-9. https://doi.org/10.1016/j.chemosphere.2019.125677 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.chemosphere.2019.125677 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 9 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 246 es_ES
dc.identifier.pmid 31884230 es_ES
dc.relation.pasarela S\405781 es_ES
dc.contributor.funder European Social Fund es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Ministerio de Educación y Ciencia es_ES
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