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dc.contributor.author | Schwanke, Anderson Joel | es_ES |
dc.contributor.author | Balzer, Rosana | es_ES |
dc.contributor.author | Lopes, Christian Wittee | es_ES |
dc.contributor.author | Meira, Debora Motta | es_ES |
dc.contributor.author | DÍAZ MORALES, URBANO MANUEL | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.contributor.author | Pergher, Sibele | es_ES |
dc.date.accessioned | 2021-04-28T03:31:39Z | |
dc.date.available | 2021-04-28T03:31:39Z | |
dc.date.issued | 2020-08-17 | es_ES |
dc.identifier.issn | 0947-6539 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/165715 | |
dc.description | This is the peer reviewed version of the following article: A. J. Schwanke, R. Balzer, C. Wittee Lopes, D. Motta Meira, U. Díaz, A. Corma, S. Pergher, Chem. Eur. J. 2020, 26, 10459, which has been published in final form at https://doi.org/10.1002/chem.202000862. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | es_ES |
dc.description.abstract | [EN] In this work, an MWW-type zeolite with pillars containing silicon and niobium oxide was synthesized to obtain a hierarchical zeolite. The effect of niobium insertion in the pillaring process was determined by combining a controllable acidity and accessibility in the final material. All pillared materials had niobium occupying framework positions in pillars and extra-framework positions. The pillared material, Pil-Nb-4.5 with 4.5 wt % niobium, did not compromise the mesoporosity formed by pillaring, while the increase of niobium in the structure gradually decreased the mesoporosity and ordering of lamellar stacking. The morphology of the pillared zeolites and the niobium content were found to directly affect the catalytic activity. Specifically, we report on the activity of the MWW-type zeolites with niobium catalyzing the gas-phase oxidation of volatile organic compounds (VOCs), which is an important reaction for clean environmental. All produced MWW-type zeolites with niobium were catalytically active, even at low temperatures and low niobium loading, and provided excellent conversion efficiencies. | es_ES |
dc.description.sponsorship | A.J.S. thanks the CordenacAo de Aperfeicoamento de Pessoal de Nivel Superior-Brasil (CAPES)-Finance Code 001, the PDSE program (process number 99999.004779/2014-02) and the prof. Claudio Radtke from the PPGQ-UFRGS for the XPS analyses. C.W.L. is grateful to INOMAT/CAPES for a postdoctoral fellowship. U.D. thanks the funding by the Spanish Government (MAT2017-82288-C2-1-P). | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | John Wiley & Sons | es_ES |
dc.relation.ispartof | Chemistry - A European Journal | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Layered compounds | es_ES |
dc.subject | MCM-36 | es_ES |
dc.subject | Niobium | es_ES |
dc.subject | Oxidation | es_ES |
dc.subject | Zeolite | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | A Lamellar MWW Zeolite With Silicon and Niobium Oxide Pillars: A Catalyst for the Oxidation of Volatile Organic Compounds | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1002/chem.202000862 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-82288-C2-1-P/ES/MATERIALES HIBRIDOS MULTIFUNCIONALES BASADOS EN NANO-UNIDADES ESTRUCTURALES ACTIVAS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/CAPES//001/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/CAPES//99999.004779%2F2014-02/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Schwanke, AJ.; Balzer, R.; Lopes, CW.; Meira, DM.; Díaz Morales, UM.; Corma Canós, A.; Pergher, S. (2020). A Lamellar MWW Zeolite With Silicon and Niobium Oxide Pillars: A Catalyst for the Oxidation of Volatile Organic Compounds. Chemistry - A European Journal. 26(46):1-12. https://doi.org/10.1002/chem.202000862 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1002/chem.202000862 | es_ES |
dc.description.upvformatpinicio | 1 | es_ES |
dc.description.upvformatpfin | 12 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 26 | es_ES |
dc.description.issue | 46 | es_ES |
dc.identifier.pmid | 32427389 | es_ES |
dc.relation.pasarela | S\434007 | es_ES |
dc.contributor.funder | Coordenaçao de Aperfeiçoamento de Pessoal de Nível Superior, Brasil | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
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