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Effect of the CuO addition on a Sb-doped SnO2 ceramic electrode applied to the removal of Norfloxacin in chloride media by electro-oxidation

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Effect of the CuO addition on a Sb-doped SnO2 ceramic electrode applied to the removal of Norfloxacin in chloride media by electro-oxidation

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dc.contributor.author Carrillo Abad, Jorge es_ES
dc.contributor.author Mora-Gómez, Julia es_ES
dc.contributor.author García Gabaldón, Montserrat es_ES
dc.contributor.author Ortega Navarro, Emma María es_ES
dc.contributor.author Mestre, S. es_ES
dc.contributor.author Pérez-Herranz, Valentín es_ES
dc.date.accessioned 2021-05-04T03:31:32Z
dc.date.available 2021-05-04T03:31:32Z
dc.date.issued 2020-06 es_ES
dc.identifier.issn 0045-6535 es_ES
dc.identifier.uri http://hdl.handle.net/10251/165897
dc.description.abstract [EN] Norfloxacin is employed as in veterinary and human medicine against gram-positive and gram-negative bacteria. Due to the ineffective treatment at the wastewater treatment plants it becomes an emergent pollutant. Electro-oxidation appears as an alternative to its effective mineralization. This work compares Norfloxacin electro-oxidation on different anodic materials: two ceramic electrodes (both based on SnO2 + Sb2O3 with and without CuO, named as CuO and BCE, respectively) and a boron doped diamond (BDD). First, the anodes were characterized by cyclic voltammetry, revealing that NOR direct oxidation occurred at 1.30 V vs. Ag/AgCl. The higher the scan rate the higher both the current density and the anodic potential of the peak. This behavior was analyzed using the Randles¿Sevcik equation to calculate the Norfloxacin diffusion coefficient in aqueous media, giving a value of D= 7.80¿10-6 cm2 s-1 at 25 °C), which is close to the predicted value obtained using the Wilke-Chang correlation. The electrolysis experiments showed that both NOR and TOC decay increased with the applied current density, presenting a pseudo-first order kinetic. All the anodes tested achieved more than 90% NOR degradation at each current density. The CuO is not a good alternative to BCE because although it acts as a catalyst during the first use, it is lost from the anode surface in the subsequent uses. According to their oxidizing power, the anodes employed are ordered as follows: BDD>BCE>CuO. es_ES
dc.description.sponsorship The authors want to express their gratitude to the Ministerio de Economia y Competitividad (Spain) and the FEDER funds, which financially support the projects CTQ2015-65202-C2-1-R, CTQ201565202-C2-2-R and RTI2018-101341-B-C21. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Chemosphere es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Boron-doped diamond (BDD) anode es_ES
dc.subject Ceramic anodes es_ES
dc.subject Electro-oxidation es_ES
dc.subject Norfloxacin (NOR) es_ES
dc.subject Voltammetric study es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Effect of the CuO addition on a Sb-doped SnO2 ceramic electrode applied to the removal of Norfloxacin in chloride media by electro-oxidation es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.chemosphere.2020.126178 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-65202-C2-2-R/ES/NUEVOS ELECTRODOS CERAMICOS MEJORADOS MEDIANTE NANOTECNOLOGIA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-65202-C2-1-R/ES/CARACTERIZACION ELECTROQUIMICA DE ELECTRODOS CERAMICOS Y APLICACION A PROCESOS ELECTROQUIMICOS DE OXIDACION AVANZADA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101341-B-C21/ES/ELECTROCHEMICAL CHARACTERIZATION OF CERAMIC ELECTRODES AND MEMBRANES AND APPLICATION TO PHOTOELECTROOXIDATION AND ELECTROFILTRATION PROCESSES/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Carrillo Abad, J.; Mora-Gómez, J.; García Gabaldón, M.; Ortega Navarro, EM.; Mestre, S.; Pérez-Herranz, V. (2020). Effect of the CuO addition on a Sb-doped SnO2 ceramic electrode applied to the removal of Norfloxacin in chloride media by electro-oxidation. Chemosphere. 249:1-9. https://doi.org/10.1016/j.chemosphere.2020.126178 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.chemosphere.2020.126178 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 9 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 249 es_ES
dc.identifier.pmid 32087454 es_ES
dc.relation.pasarela S\417895 es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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dc.subject.ods 06.- Garantizar la disponibilidad y la gestión sostenible del agua y el saneamiento para todos es_ES


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