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Ultrastable Magnetic Nanoparticles Encapsulated in Carbon for Magnetically Induced Catalysis

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Ultrastable Magnetic Nanoparticles Encapsulated in Carbon for Magnetically Induced Catalysis

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dc.contributor.author Martínez-Prieto, Luis Miguel es_ES
dc.contributor.author Marbaix, Julien es_ES
dc.contributor.author Asensio, Juan M. es_ES
dc.contributor.author Cerezo-Navarrete, Christian es_ES
dc.contributor.author Fazzini, Pier-Francesco es_ES
dc.contributor.author Soulantica, Katerina es_ES
dc.contributor.author Chaudret, Bruno es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2021-05-07T03:32:15Z
dc.date.available 2021-05-07T03:32:15Z
dc.date.issued 2020-07-24 es_ES
dc.identifier.uri http://hdl.handle.net/10251/166058
dc.description.abstract [EN] Magnetically induced catalysis using magnetic nanoparticles (MagNPs) as heating agents is a new efficient method to perform reactions at high temperatures. However, the main limitation is the lack of stability of the catalysts operating in such harsh conditions. Normally, above 500 degrees C, significant sintering of MagNPs takes place. Here we present encapsulated magnetic FeCo and Co NPs in carbon (Co@C and FeCo@C) as an ultrastable heating material suitable for high-temperature magnetic catalysis. Indeed, FeCo@C or a mixture of FeCo@C:Co@C (2:1) decorated with Ni or Pt-Sn showed good stability in terms of temperature and catalytic performances. In addition, consistent conversions and selectivities regarding conventional heating were observed for CO2 methanation (Sabatier reaction), propane dehydrogenation (PDH), and propane dry reforming (PDR). Thus, the encapsulation of MagNPs in carbon constitutes a major advance in the development of stable catalysts for high-temperature magnetically induced catalysis. es_ES
dc.description.sponsorship The authors thank the Instituto de Tecnologia Quimica (ITQ), Consejo Superior de Investigaciones Cientificas (CSIC), Universitat Politecnica de València (UPV) for the facilities and Severo Ochoa programe (SEV-2016-0683), "Juan de la Cierva" by MINECO (IJCI-2016-27966), and Primero Proyectos de Investigación PAID-06-18 (SP20180088) for financial support. The authors acknowledge ERC Advanced Grants (MONACAT-2015-694159 and SynCatMatch-2014671093). We also thank the Electron Microscopy Service of the UPV for TEM facilities. es_ES
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof ACS Applied Nano Materials es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Magnetic nanoparticles es_ES
dc.subject Carbon encapsulation es_ES
dc.subject Magnetic catalysis es_ES
dc.subject Methanation es_ES
dc.subject Propane dry reforming es_ES
dc.subject Propane dehydrogenation es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Ultrastable Magnetic Nanoparticles Encapsulated in Carbon for Magnetically Induced Catalysis es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1021/acsanm.0c01392 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UPV//PAID-06-18/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/694159/EU/Magnetism and Optics for Nanoparticle Catalysis/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//IJCI-2016-27966/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UPV//SP20180088/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Martínez-Prieto, LM.; Marbaix, J.; Asensio, JM.; Cerezo-Navarrete, C.; Fazzini, P.; Soulantica, K.; Chaudret, B.... (2020). Ultrastable Magnetic Nanoparticles Encapsulated in Carbon for Magnetically Induced Catalysis. ACS Applied Nano Materials. 3(7):7076-7087. https://doi.org/10.1021/acsanm.0c01392 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1021/acsanm.0c01392 es_ES
dc.description.upvformatpinicio 7076 es_ES
dc.description.upvformatpfin 7087 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 3 es_ES
dc.description.issue 7 es_ES
dc.identifier.eissn 2574-0970 es_ES
dc.identifier.pmid 32743352 es_ES
dc.identifier.pmcid PMC7386363 es_ES
dc.relation.pasarela S\418873 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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