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Unusually Low Heat of Adsorption of CO2 on AlPO and SAPO Molecular Sieves

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Unusually Low Heat of Adsorption of CO2 on AlPO and SAPO Molecular Sieves

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dc.contributor.author Pérez-Botella, Eduardo es_ES
dc.contributor.author Martínez-Franco, Raquel es_ES
dc.contributor.author Gonzalez-Camuñas, Nuria es_ES
dc.contributor.author Cantin Sanz, Angel es_ES
dc.contributor.author Palomino Roca, Miguel es_ES
dc.contributor.author Moliner Marin, Manuel es_ES
dc.contributor.author Valencia Valencia, Susana es_ES
dc.contributor.author Rey Garcia, Fernando es_ES
dc.date.accessioned 2021-05-11T03:31:57Z
dc.date.available 2021-05-11T03:31:57Z
dc.date.issued 2020-10-28 es_ES
dc.identifier.uri http://hdl.handle.net/10251/166142
dc.description.abstract [EN] The capture of CO2 from post-combustion streams or from other mixtures, such as natural gas, is an effective way of reducing CO2 emissions, which contribute to the greenhouse effect in the atmosphere. One of the developing technologies for this purpose is physisorption on selective solid adsorbents. The ideal adsorbents are selective toward CO2, have a large adsorption capacity at atmospheric pressure and are easily regenerated, resulting in high working capacity. Therefore, adsorbents combining molecular sieving properties and low heats of adsorption of CO2 are of clear interest as they will provide high selectivities and regenerabilities in CO2 separation process. Here we report that some aluminophosphate (AlPO) and silicoaluminophosphate (SAPO) materials with LTA, CHA and AFI structures present lower heats of adsorption of CO2 (13¿25 kJ/mol) than their structurally analogous zeolites at comparable framework charges. In some cases, their heats of adsorption are even lower than those of pure silica composition (20¿25 kJ/mol). This could mean a great improvement in the regeneration process compared to the most frequently used zeolitic adsorbents for this application while maintaining most of their adsorption capacity, if materials with the right stability and pore size and topology are found. es_ES
dc.description.sponsorship We acknowledge the Spanish Ministry of Sciences, Innovation and Universities (MCIU), State Research Agency (AEI), and the European Fund for Regional Development (FEDER) for their funding via projects Multi2HYcat (EU-Horizon 2020 funded project under grant agreement no. 720783), Program Severo Ochoa SEV-2016-0683 and RTI2018-101033-B-I00 and also Fundacion Ramon Areces for funding through a research contract (CIVP18A3908). EP-B thanks the MCIU for his grant (FPU15/01602). NG-C thanks MCIU for her grant (BES-2016-078178). es_ES
dc.language Inglés es_ES
dc.publisher Frontiers Media SA es_ES
dc.relation.ispartof Frontiers in Chemistry es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Carbon dioxide es_ES
dc.subject Separation es_ES
dc.subject Adsorption es_ES
dc.subject Capture es_ES
dc.subject Molecular sieves es_ES
dc.subject Zeolites es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Unusually Low Heat of Adsorption of CO2 on AlPO and SAPO Molecular Sieves es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3389/fchem.2020.588712 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/720783/EU/MULTI-site organic-inorganic HYbrid CATalysts for MULTI-step chemical processes/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/Fundación Ramón Areces//CIVP18A3908/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101033-B-I00/ES/DISEÑO DE CATALIZADORES MULTIFUNCIONALES PARA LA CONVERSION EFICIENTE DE BIOGAS Y GAS NATURAL A HIDROCARBUROS DE INTERES INDUSTRIAL/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MECD//FPU15%2F01602/ES/FPU15%2F01602/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI//BES-2016-078178/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Pérez-Botella, E.; Martínez-Franco, R.; Gonzalez-Camuñas, N.; Cantin Sanz, A.; Palomino Roca, M.; Moliner Marin, M.; Valencia Valencia, S.... (2020). Unusually Low Heat of Adsorption of CO2 on AlPO and SAPO Molecular Sieves. Frontiers in Chemistry. 8:1-10. https://doi.org/10.3389/fchem.2020.588712 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3389/fchem.2020.588712 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 10 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 8 es_ES
dc.identifier.eissn 2296-2646 es_ES
dc.identifier.pmid 33195090 es_ES
dc.identifier.pmcid PMC7655961 es_ES
dc.relation.pasarela S\425778 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Fundación Ramón Areces es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Ministerio de Educación, Cultura y Deporte es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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