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Valorization of Municipal Biowaste into Electrospun Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Biopapers for Food Packaging Applications

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Valorization of Municipal Biowaste into Electrospun Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Biopapers for Food Packaging Applications

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dc.contributor.author Meléndez-Rodríguez, Beatriz es_ES
dc.contributor.author Torres Giner, Sergio es_ES
dc.contributor.author Lorini, Laura es_ES
dc.contributor.author Valentino, Francesco es_ES
dc.contributor.author Sammon, Chris es_ES
dc.contributor.author Cabedo, Luis es_ES
dc.contributor.author Lagaron, Jose Maria es_ES
dc.date.accessioned 2021-05-14T03:32:06Z
dc.date.available 2021-05-14T03:32:06Z
dc.date.issued 2020-09-21 es_ES
dc.identifier.uri http://hdl.handle.net/10251/166350
dc.description American Chemical Society es_ES
dc.description.abstract [EN] The present study reports on the production and characterization of a new biopackaging material made of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) derived from municipal biowaste (MBW) and produced by the mixed bacterial culture technology. After purification and extraction, the MBW-derived PHBV was processed by electrospinning to yield defect-free ultrathin fibers, which were thermally post-treated. Annealing at 130 degrees C, well below the biopolymer's melting temperature (T-m), successfully yielded a continuous film resulting from coalescence of the electrospun fibrillar morphology, the so-called biopaper, exhibiting enhanced optical and color properties compared to traditional melt compounding routes. The crystallinity and crystalline morphology were comprehensively studied as a function of temperature by attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy and combined time-resolved synchrotron small- and wide-angle X-ray scattering (SAXS and WAXS) experiments, which clearly indicated that the molecular order within the copolyester was improved up to a maximum at 130 degrees C, and then it decreased at the biopolymer's T-m. It was hypothesized that by annealing at the temperature at which the thermally induced molecular order is maximized, the fibers generated sufficient mobility to align alongside, hence reducing surface energy and porosity. The data suggest that this material shows a good balance between enhanced mechanical and improved barrier properties to vapors and gases in comparison to traditional paper and other currently used petroleum-derived polymers, thus presenting significant potential to be part of innovative food biopackaging designs for the protection and preservation of foods in a circular bioeconomy scenario. es_ES
dc.description.sponsorship The Spanish Ministry of Science and Innovation (MICI) project RTI2018-097249-B-C21 and EU projects H2020 YPACK (reference number 773872) and H2020 USABLE (reference number 836884) are acknowledged for funding support. B.M.-R. and S.T.-G. would also like to thank MICI for the FPI fellowship (BES-2016-077972) and the Juan de la Cierva IncorporaciOn contract (IJCI-2016-29675), respectively. The ALBA Synchrotron, Spain, is also acknowledged for the funding received through the project proposal 2018022619. The authors also thank the "Unidad Asociada CSIC-UJI in Polymers Technology". es_ES
dc.language Inglés es_ES
dc.relation.ispartof ACS Applied Bio Materials es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject PHBV es_ES
dc.subject Electrospinning es_ES
dc.subject Biopapers es_ES
dc.subject Waste valorization es_ES
dc.subject Food packaging es_ES
dc.subject Circular bioeconomy es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Valorization of Municipal Biowaste into Electrospun Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Biopapers for Food Packaging Applications es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1021/acsabm.0c00698 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/773872/EU/HIGH PERFORMANCE POLYHYDROXYALKANOATES BASED PACKAGING TO MINIMISE FOOD WASTE/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/ALBA Synchrotron Light Source//2018022619/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/836884/EU/Unlocking the potential of Sustainable BiodegradabLe Packaging/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/ALBA Synchrotron Light Source//BL11-NCD-SWEET/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//IJCI-2016-29675/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-097249-B-C21/ES/ENVASE ACTIVO MULTICAPA TERMOCONFORMABLE DE ALTA BARRERA BASADO EN BIOECONOMIA CIRCULAR/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI//BES-2016-077972/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario de Ingeniería de Alimentos para el Desarrollo - Institut Universitari d'Enginyeria d'Aliments per al Desenvolupament es_ES
dc.description.bibliographicCitation Meléndez-Rodríguez, B.; Torres Giner, S.; Lorini, L.; Valentino, F.; Sammon, C.; Cabedo, L.; Lagaron, JM. (2020). Valorization of Municipal Biowaste into Electrospun Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Biopapers for Food Packaging Applications. ACS Applied Bio Materials. 3(9):6110-6123. https://doi.org/10.1021/acsabm.0c00698 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1021/acsabm.0c00698 es_ES
dc.description.upvformatpinicio 6110 es_ES
dc.description.upvformatpfin 6123 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 3 es_ES
dc.description.issue 9 es_ES
dc.identifier.eissn 2576-6422 es_ES
dc.relation.pasarela S\417690 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder ALBA Synchrotron Light Source es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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dc.subject.ods 12.- Garantizar las pautas de consumo y de producción sostenibles es_ES


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