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Enhancing visible-light photocatalytic activity for overall water splitting in UiO-66 by controlling metal node composition

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Enhancing visible-light photocatalytic activity for overall water splitting in UiO-66 by controlling metal node composition

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dc.contributor.author Melillo, Arianna es_ES
dc.contributor.author Cabrero-Antonino, Maria es_ES
dc.contributor.author Navalón Oltra, Sergio es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author Ferrer Ribera, Rosa Belén es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2021-05-14T12:41:03Z
dc.date.available 2021-05-14T12:41:03Z
dc.date.issued 2020-12-05 es_ES
dc.identifier.issn 0926-3373 es_ES
dc.identifier.uri http://hdl.handle.net/10251/166367
dc.description.abstract [EN] The photocatalytic activity of a series of five UiO-66 (M: Zr, Zr/Ti, Zr/Ce, Zr/Ce/Ti, Ce) materials for overall water splitting with generation of hydrogen and oxygen has been herein measured. The most efficient photocatalyst for the overall water splitting is the trimetallic MOF UiO-66(Zr/Ce/Ti) which achieves 230 mu mol.g(-1) of H-2 and 110 mu mol.g(-1) of O-2, upon UV light irradiation, and 210 mu mol.g(-1) of H-2 and 70 mu mol.g(-1) of O-2, under visible light irradiation. These productivity data indicate that a considerable percentage of its photocatalytic activity derives from the visible region of the spectrum (lambda > 450 nm). The photocatalytic activity of trimetallic UiO-66(Zr/Ce/Ti) was maintained upon reuse. Kinetics of the charge separated state monitored by transient absorption spectroscopy shows similar deactivation profiles for the five UiO-66 samples, suggesting that it is the charge separation efficiency the main factor responsible for the differences in the photocatalytic activity. The use of methanol as sacrificial agent during the photocatalytic experiments indicated that the high photocatalytic efficiency for overall water splitting in UiO-66(Zr/Ce/Ti) derives from the favorable kinetics of oxygen evolution. These results show the potential of multimetallic metal-organic frameworks as solar photocatalysts by tuning light absorption towards the visible region. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Science and Innovation (Severo Ochoa and RTI2018-098237-CO21) and Generalitat Valenciana (Prometeo 2017/083) is gratefully acknowledged. S.N. thanks financial support by the Fundacion Ramon Areces (XVIII Concurso Nacional para la Adjudicacion de Ayudas a la Investigacion en Ciencias de la Vida y de la Materia, 2016), Ministerio de Ciencia, Innovacion y Universidades RTI2018-099482-A-I00 project and Generalitat Valenciana grupos de investigacion consolidables 2019 (ref: AICO/2019/214) project. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Applied Catalysis B Environmental es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Overall water splitting es_ES
dc.subject Photocatalysis es_ES
dc.subject Visible light photoresponse es_ES
dc.subject UiO-66 es_ES
dc.subject Trimetallic MOF es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Enhancing visible-light photocatalytic activity for overall water splitting in UiO-66 by controlling metal node composition es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.apcatb.2020.119345 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2017%2F083/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-098237-B-C21/ES/HETEROUNIONES DE GRAFENO CON CONFIGURACION CONTROLADA. SINTESIS Y APLICACIONES COMO SOPORTE EN CATALISIS Y EN ELECTRODOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-099482-A-I00/ES/DESCOMPOSICION FOTOCATALITICA DEL AGUA ASISTIDA POR LUZ VISIBLE EMPLEANDO MATERIALES NOVEDOSOS Y MULTIFUNCIONALES UIO-66%2F67/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//AICO%2F2019%2F214/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Melillo, A.; Cabrero-Antonino, M.; Navalón Oltra, S.; Alvaro Rodríguez, MM.; Ferrer Ribera, RB.; García Gómez, H. (2020). Enhancing visible-light photocatalytic activity for overall water splitting in UiO-66 by controlling metal node composition. Applied Catalysis B Environmental. 278:1-11. https://doi.org/10.1016/j.apcatb.2020.119345 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.apcatb.2020.119345 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 11 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 278 es_ES
dc.relation.pasarela S\419873 es_ES
dc.contributor.funder Fundación Ramón Areces es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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