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Regioselective Generation of Single-Site Iridium Atoms and Their Evolution into Stabilized Subnanometric Iridium Clusters in MWW Zeolite

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Regioselective Generation of Single-Site Iridium Atoms and Their Evolution into Stabilized Subnanometric Iridium Clusters in MWW Zeolite

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dc.contributor.author Liu, Lichen es_ES
dc.contributor.author Lopez-Haro, Miguel es_ES
dc.contributor.author Meira, Debora M. es_ES
dc.contributor.author Concepción Heydorn, Patricia es_ES
dc.contributor.author Calvino, Jose J. es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2021-05-20T03:33:47Z
dc.date.available 2021-05-20T03:33:47Z
dc.date.issued 2020-09-01 es_ES
dc.identifier.issn 1433-7851 es_ES
dc.identifier.uri http://hdl.handle.net/10251/166530
dc.description This is the peer reviewed version of the following article: L. Liu, M. Lopez-Haro, D. M. Meira, P. Concepcion, J. J. Calvino, A. Corma, Angew. Chem. Int. Ed. 2020, 59, 15695, which has been published in final form at https://doi.org/10.1002/anie.202005621. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. es_ES
dc.description.abstract [EN] Preparation of supported metal catalysts with uniform particle size and coordination environment is a challenging and important topic in materials chemistry and catalysis. In this work, we report the regioselective generation of single-site Ir atoms and their evolution into stabilized subnanometric Ir clusters in MWW zeolite, which are located at the 10MR window connecting the two neighboring 12MR supercages. The size of the subnanometric Ir clusters can be controlled by the post-synthesis treatments and maintain below 1 nm even after being reduced at 650 degrees C, which cannot be readily achieved with samples prepared by conventional impregnation methods. The high structure sensitivity, size-dependence, of catalytic performance in the alkane hydrogenolysis reaction of Ir clusters in the subnanometric regime is evidenced. es_ES
dc.description.sponsorship This work has been supported by the European Union through the European Research Council (grant ERC-AdG-2014-671093, SynCatMatch) and the Spanish government through the "Severo Ochoa Program" (SEV-2016-0683). The authors also thank Microscopy Service of UPV for the TEM and STEM measurements. High-resolution STEM measurements were performed at the DME-UCA node of the ELECMI National Singular Infrastruture, in Cadiz University, with financial support from FEDER/MINECO (MAT2017-87579-R and MAT2016-81118-P). This research used resources of the Advanced Photon Source, an Office of Science User Facility operated for the U.S. Department of Energy (DOE) Office of Science by Argonne National Laboratory, and was supported by the U.S. DOE under Contract No.DE-AC02-06CH11357, and the Canadian Light Source and its funding partners. The financial support from ExxonMobil on this project is also greatly acknowledged. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Angewandte Chemie International Edition es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Alkane hydrogenolysis es_ES
dc.subject Clusters es_ES
dc.subject Iridium es_ES
dc.subject Single atoms es_ES
dc.subject Zeolite es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Regioselective Generation of Single-Site Iridium Atoms and Their Evolution into Stabilized Subnanometric Iridium Clusters in MWW Zeolite es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/anie.202005621 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/DOE//DE-AC02-06CH11357/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-87579-R/ES/FASES 2D ULTRAFINAS SOBRE OXIDOS CON MORFOLOGIA CONTROLADA: PLATAFORMA DE NANOCATALIZADORES MULTICOMPONENTE CON APLICACIONES EN PROTECCION DEL MEDIO AMBIENTE/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2016-81118-P/ES/DISEÑO Y CARACTERIZACION AVANZADA DE CATALIZADORES CON NANOINTERFASES MODELO AU%2F%2FCEO2/ es_ES
dc.rights.accessRights Abierto es_ES
dc.date.embargoEndDate 2021-06-25 es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Liu, L.; Lopez-Haro, M.; Meira, DM.; Concepción Heydorn, P.; Calvino, JJ.; Corma Canós, A. (2020). Regioselective Generation of Single-Site Iridium Atoms and Their Evolution into Stabilized Subnanometric Iridium Clusters in MWW Zeolite. Angewandte Chemie International Edition. 59(36):15695-15702. https://doi.org/10.1002/anie.202005621 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/anie.202005621 es_ES
dc.description.upvformatpinicio 15695 es_ES
dc.description.upvformatpfin 15702 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 59 es_ES
dc.description.issue 36 es_ES
dc.identifier.pmid 32583951 es_ES
dc.relation.pasarela S\433668 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Canadian Light Source es_ES
dc.contributor.funder U.S. Department of Energy es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder ExxonMobil Research and Engineering Company es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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