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Titanosilicate zeolite precursors for highly efficient oxidation reactions

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Titanosilicate zeolite precursors for highly efficient oxidation reactions

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dc.contributor.author Bai, Risheng es_ES
dc.contributor.author Navarro Villalba, Mª Teresa es_ES
dc.contributor.author Song, Yue es_ES
dc.contributor.author Zhang, Tianjun es_ES
dc.contributor.author Zou, Yongcun es_ES
dc.contributor.author Feng, Zhaochi es_ES
dc.contributor.author Zhang, Peng es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.contributor.author Yu, Jihong es_ES
dc.date.accessioned 2021-05-20T03:34:38Z
dc.date.available 2021-05-20T03:34:38Z
dc.date.issued 2020-12-07 es_ES
dc.identifier.issn 2041-6520 es_ES
dc.identifier.uri http://hdl.handle.net/10251/166540
dc.description.abstract [EN] Titanosilicate zeolites are catalysts of interest in the field of fine chemicals. However, the generation and accessibility of active sites in titanosilicate materials for catalyzing reactions with large molecules is still a challenge. Herein, we prepared titanosilicate zeolite precursors with open zeolitic structures, tunable pore sizes, and controllable Si/Ti ratios through a hydrothermal crystallization strategy by using quaternary ammonium templates. A series of quaternary ammonium ions are discovered as effective organic templates. The prepared amorphous titanosilicate zeolites with some zeolite framework structural order have extra-large micropores and abundant octahedrally coordinated isolated Ti species, which lead to a superior catalytic performance in the oxidative desulfurization of dibenzothiophene (DBT) and epoxidation of cyclohexene. It is anticipated that the amorphous prezeolitic titanosilicates will benefit the catalytic conversion of bulky molecules in a wide range of reaction processes. es_ES
dc.description.sponsorship The authors thank the National Key Research and Development Program of China (Grant 2016YFB0701100), the National Natural Science Foundation of China (Grant 21621001, 21920102005 and 21835002), the 111 Project (B17020), the European Union through the European Research Council (grant ERC-AdG-2014-671093, SynCatMatch), and the Spanish Government through "Severo Ochoa" (SEV-2016-0683, MINECO) for supporting this work. The APS was operated for the U.S. DOE Office of Science by the Argonne National Laboratory, and the CLS@APS facilities (Sector 20) were supported by the U.S. DOE under contract no. DEAC02-06CH11357, and the Canadian Light Source and its funding partners. R. Bai acknowledges the China Scholarship Council for the financial support. Jose Gaona Miguelez is also acknowledged for technical help. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Chemical Science es_ES
dc.rights Reconocimiento - No comercial (by-nc) es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Titanosilicate zeolite precursors for highly efficient oxidation reactions es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/d0sc04603e es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/DOE//DEAC02-06CH11357/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/NKRDPC//2016YFB0701100/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/NSFC//21621001/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MOE//B17020/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/NSFC//21920102005/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/NSFC//21835002/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Bai, R.; Navarro Villalba, MT.; Song, Y.; Zhang, T.; Zou, Y.; Feng, Z.; Zhang, P.... (2020). Titanosilicate zeolite precursors for highly efficient oxidation reactions. Chemical Science. 11(45):12341-12349. https://doi.org/10.1039/d0sc04603e es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/d0sc04603e es_ES
dc.description.upvformatpinicio 12341 es_ES
dc.description.upvformatpfin 12349 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 11 es_ES
dc.description.issue 45 es_ES
dc.relation.pasarela S\433256 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Canadian Light Source es_ES
dc.contributor.funder China Scholarship Council es_ES
dc.contributor.funder U.S. Department of Energy es_ES
dc.contributor.funder Ministry of Education, China es_ES
dc.contributor.funder National Natural Science Foundation of China es_ES
dc.contributor.funder National Key Research and Development Program of China es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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