- -

Salicylate method for ammonia quantification in nitrogen electroreduction experiments: The correction of iron III interference

RiuNet: Repositorio Institucional de la Universidad Politécnica de Valencia

Compartir/Enviar a

Citas

Estadísticas

  • Estadisticas de Uso

Salicylate method for ammonia quantification in nitrogen electroreduction experiments: The correction of iron III interference

Mostrar el registro sencillo del ítem

Ficheros en el ítem

Thumbnail
Nombre: Gner-Sanz;Leverck ...
Tamaño: 2.370Mb
Formato: PDF
Descripción: Versión editorial
Abrir
dc.contributor.author Giner-Sanz, Juan José es_ES
dc.contributor.author Leverick, G.M. es_ES
dc.contributor.author Pérez-Herranz, Valentín es_ES
dc.contributor.author Shao-Horn, Y. es_ES
dc.date.accessioned 2021-05-27T03:33:26Z
dc.date.available 2021-05-27T03:33:26Z
dc.date.issued 2020-10-01 es_ES
dc.identifier.issn 0013-4651 es_ES
dc.identifier.uri http://hdl.handle.net/10251/166820
dc.description.abstract [EN] The salicylate method is one of the ammonia quantification methods that has been extensively used in literature for quantifying ammonia in the emerging field of nitrogen (electro)fixation. The presence of iron in the sample causes a strong negative interference on the salicylate method. Today, the recommended method to deal with such interferences is the experimental correction method: the iron concentration in the sample is measured using an iron quantification method, and then the corresponding amount of iron is added to the calibration samples. The limitation of this method is that when a batch of samples presents a great iron concentration variability, a different calibration curve has to be obtained for each sample. In this work, the interference of iron III on the salicylate method was experimentally quantified, and a model was proposed to capture the effect of iron III interference on the ammonia quantification result. This model can be used to correct the iron III interferences on ammonia quantification. The great advantage of this correction method is that it only requires three experimental curves in order to correct the iron III interference in any sample provided the iron III concentration is below the total peak suppression concentration. es_ES
dc.description.sponsorship This work was supported by the Toyota Research Institute through the Accelerated Materials Design and Discovery program. This work made use of the MRSEC Shared Experimental Facilities at MIT (SEM) supported by the National Science Foundation under award number DMR-1419807 as well as the HZDR Ion Beam Center TEM facilities. J.J.G.S. is very grateful to the Generalitat Valenciana and to the European Social Fund, for their economic support in the form of Vali+d postdoctoral grant (APOSTD-2018-001). G.M.L. was partially supported by a Natural Sciences and Engineering Research Council of Canada (NSERC) PGS-D. es_ES
dc.language Inglés es_ES
dc.publisher The Electrochemical Society es_ES
dc.relation.ispartof Journal of The Electrochemical Society es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Ammonia quantification es_ES
dc.subject Interference quantification and correction es_ES
dc.subject Iron interferences es_ES
dc.subject Salicylate method es_ES
dc.subject UV-visible spectroscopy es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Salicylate method for ammonia quantification in nitrogen electroreduction experiments: The correction of iron III interference es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1149/1945-7111/abbdd6 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/NSF//1419807/US/MIT Materials Research Science and Engineering Center - Full Proposal/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//APOSTD%2F2018%2F001/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Giner-Sanz, JJ.; Leverick, G.; Pérez-Herranz, V.; Shao-Horn, Y. (2020). Salicylate method for ammonia quantification in nitrogen electroreduction experiments: The correction of iron III interference. Journal of The Electrochemical Society. 167(13):1-10. https://doi.org/10.1149/1945-7111/abbdd6 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1149/1945-7111/abbdd6 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 10 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 167 es_ES
dc.description.issue 13 es_ES
dc.relation.pasarela S\423545 es_ES
dc.contributor.funder European Social Fund es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Toyota Research Institute es_ES
dc.contributor.funder National Science Foundation, EEUU es_ES
dc.contributor.funder Natural Sciences and Engineering Research Council of Canada es_ES
dc.description.references Kibsgaard, J., Nørskov, J. K., & Chorkendorff, I. (2019). The Difficulty of Proving Electrochemical Ammonia Synthesis. ACS Energy Letters, 4(12), 2986-2988. doi:10.1021/acsenergylett.9b02286 es_ES
dc.description.references Wang, Q., Guo, J., & Chen, P. (2020). The Power of Hydrides. Joule, 4(4), 705-709. doi:10.1016/j.joule.2020.02.008 es_ES
dc.description.references Wang, Y., Shi, M., Bao, D., Meng, F., Zhang, Q., Zhou, Y., … Jiang, Q. (2019). Generating Defect‐Rich Bismuth for Enhancing the Rate of Nitrogen Electroreduction to Ammonia. Angewandte Chemie International Edition, 58(28), 9464-9469. doi:10.1002/anie.201903969 es_ES
dc.description.references Andersen, S. Z., Čolić, V., Yang, S., Schwalbe, J. A., Nielander, A. C., McEnaney, J. M., … Chorkendorff, I. (2019). A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements. Nature, 570(7762), 504-508. doi:10.1038/s41586-019-1260-x es_ES
dc.description.references Kim, K., Lee, N., Yoo, C.-Y., Kim, J.-N., Yoon, H. C., & Han, J.-I. (2016). Communication—Electrochemical Reduction of Nitrogen to Ammonia in 2-Propanol under Ambient Temperature and Pressure. Journal of The Electrochemical Society, 163(7), F610-F612. doi:10.1149/2.0231607jes es_ES
dc.description.references Murakami, T., Nishikiori, T., Nohira, T., & Ito, Y. (2005). Investigation of Anodic Reaction of Electrolytic Ammonia Synthesis in Molten Salts Under Atmospheric Pressure. Journal of The Electrochemical Society, 152(5), D75. doi:10.1149/1.1874752 es_ES
dc.description.references Yang, J., Li, T., Zhong, C., Guan, X., & Hu, C. (2016). Nitrogen Fixation in Water Using Air Phase Gliding Arc Plasma. Journal of The Electrochemical Society, 163(10), E288-E292. doi:10.1149/2.0221610jes es_ES
dc.description.references Wang, P., Chang, F., Gao, W., Guo, J., Wu, G., He, T., & Chen, P. (2016). Breaking scaling relations to achieve low-temperature ammonia synthesis through LiH-mediated nitrogen transfer and hydrogenation. Nature Chemistry, 9(1), 64-70. doi:10.1038/nchem.2595 es_ES
dc.description.references Nash, J., Yang, X., Anibal, J., Wang, J., Yan, Y., & Xu, B. (2017). Electrochemical Nitrogen Reduction Reaction on Noble Metal Catalysts in Proton and Hydroxide Exchange Membrane Electrolyzers. Journal of The Electrochemical Society, 164(14), F1712-F1716. doi:10.1149/2.0071802jes es_ES
dc.description.references Wang, Q., Guo, J., & Chen, P. (2019). Recent progress towards mild-condition ammonia synthesis. Journal of Energy Chemistry, 36, 25-36. doi:10.1016/j.jechem.2019.01.027 es_ES
dc.description.references Li, D., Xu, X., Li, Z., Wang, T., & Wang, C. (2020). Detection methods of ammonia nitrogen in water: A review. TrAC Trends in Analytical Chemistry, 127, 115890. doi:10.1016/j.trac.2020.115890 es_ES
dc.description.references Searle, P. L. (1984). The berthelot or indophenol reaction and its use in the analytical chemistry of nitrogen. A review. The Analyst, 109(5), 549. doi:10.1039/an9840900549 es_ES
dc.description.references Song, Y., Johnson, D., Peng, R., Hensley, D. K., Bonnesen, P. V., Liang, L., … Rondinone, A. J. (2018). A physical catalyst for the electrolysis of nitrogen to ammonia. Science Advances, 4(4). doi:10.1126/sciadv.1700336 es_ES
dc.description.references Ivancic, I. (1984). An optimal manual procedure for ammonia analysis in natural waters by the indophenol blue method. Water Research, 18(9), 1143-1147. doi:10.1016/0043-1354(84)90230-6 es_ES
dc.description.references Ayyub, O. B., Behrens, A. M., Heligman, B. T., Natoli, M. E., Ayoub, J. J., Cunningham, G., … Kofinas, P. (2015). Simple and inexpensive quantification of ammonia in whole blood. Molecular Genetics and Metabolism, 115(2-3), 95-100. doi:10.1016/j.ymgme.2015.04.004 es_ES
dc.description.references Prieto-Blanco, M. C., Jornet-Martinez, N., Verdú-Andrés, J., Molíns-Legua, C., & Campíns-Falcó, P. (2019). Quantifying both ammonium and proline in wines and beer by using a PDMS composite for sensoring. Talanta, 198, 371-376. doi:10.1016/j.talanta.2019.02.001 es_ES
dc.description.references Prieto-Blanco, M. C., Jornet-Martínez, N., Moliner-Martínez, Y., Molins-Legua, C., Herráez-Hernández, R., Verdú Andrés, J., & Campins-Falcó, P. (2015). Development of a polydimethylsiloxane–thymol/nitroprusside composite based sensor involving thymol derivatization for ammonium monitoring in water samples. Science of The Total Environment, 503-504, 105-112. doi:10.1016/j.scitotenv.2014.07.077 es_ES
dc.description.references Prieto-Blanco, M. C., Ballester-Caudet, A., Souto-Varela, F. J., López-Mahía, P., & Campíns-Falcó, P. (2020). Rapid evaluation of ammonium in different rain events minimizing needed volume by a cost-effective and sustainable PDMS supported solid sensor. Environmental Pollution, 265, 114911. doi:10.1016/j.envpol.2020.114911 es_ES
dc.description.references McEnaney, J. M., Blair, S. J., Nielander, A. C., Schwalbe, J. A., Koshy, D. M., Cargnello, M., & Jaramillo, T. F. (2020). Electrolyte Engineering for Efficient Electrochemical Nitrate Reduction to Ammonia on a Titanium Electrode. ACS Sustainable Chemistry & Engineering, 8(7), 2672-2681. doi:10.1021/acssuschemeng.9b05983 es_ES
dc.description.references Schiffer, Z. J., Lazouski, N., Corbin, N., & Manthiram, K. (2019). Nature of the First Electron Transfer in Electrochemical Ammonia Activation in a Nonaqueous Medium. The Journal of Physical Chemistry C, 123(15), 9713-9720. doi:10.1021/acs.jpcc.9b00669 es_ES
dc.description.references Moliner-Martínez, Y., Herráez-Hernández, R., & Campíns-Falcó, P. (2005). Improved detection limit for ammonium/ammonia achieved by Berthelot’s reaction by use of solid-phase extraction coupled to diffuse reflectance spectroscopy. Analytica Chimica Acta, 534(2), 327-334. doi:10.1016/j.aca.2004.11.044 es_ES
dc.description.references López Pasquali, C. E., Fernández Hernando, P., & Durand Alegría, J. S. (2007). Spectrophotometric simultaneous determination of nitrite, nitrate and ammonium in soils by flow injection analysis. Analytica Chimica Acta, 600(1-2), 177-182. doi:10.1016/j.aca.2007.03.015 es_ES
dc.description.references Kashima, H., & Regan, J. M. (2015). Facultative Nitrate Reduction by Electrode-Respiring Geobacter metallireducens Biofilms as a Competitive Reaction to Electrode Reduction in a Bioelectrochemical System. Environmental Science & Technology, 49(5), 3195-3202. doi:10.1021/es504882f es_ES
dc.description.references Caballo-López, A., & Luque de Castro, M. D. (2006). Continuous Ultrasound-Assisted Extraction Coupled to Flow Injection−Pervaporation, Derivatization, and Spectrophotometric Detection for the Determination of Ammonia in Cigarettes. Analytical Chemistry, 78(7), 2297-2301. doi:10.1021/ac051115u es_ES
dc.description.references Bietz, J. A. (1974). Micro-Kjeldahl analysis by an improved automated ammonia determination following manual digestion. Analytical Chemistry, 46(11), 1617-1618. doi:10.1021/ac60347a040 es_ES
dc.description.references Lazouski, N., Schiffer, Z. J., Williams, K., & Manthiram, K. (2019). Understanding Continuous Lithium-Mediated Electrochemical Nitrogen Reduction. Joule, 3(4), 1127-1139. doi:10.1016/j.joule.2019.02.003 es_ES
dc.description.references McEnaney, J. M., Singh, A. R., Schwalbe, J. A., Kibsgaard, J., Lin, J. C., Cargnello, M., … Nørskov, J. K. (2017). Ammonia synthesis from N2and H2O using a lithium cycling electrification strategy at atmospheric pressure. Energy & Environmental Science, 10(7), 1621-1630. doi:10.1039/c7ee01126a es_ES
dc.description.references Cerdà, A., Oms, M. T., Forteza, R., & Cerdà, V. (1995). Evaluation of flow injection methods for ammonium determination in wastewater samples. Analytica Chimica Acta, 311(2), 165-173. doi:10.1016/0003-2670(95)00182-y es_ES
dc.description.references Molins-Legua, C., Meseguer-Lloret, S., Moliner-Martinez, Y., & Campíns-Falcó, P. (2006). A guide for selecting the most appropriate method for ammonium determination in water analysis. TrAC Trends in Analytical Chemistry, 25(3), 282-290. doi:10.1016/j.trac.2005.12.002 es_ES
dc.description.references Verdouw, H., Van Echteld, C. J. A., & Dekkers, E. M. J. (1978). Ammonia determination based on indophenol formation with sodium salicylate. Water Research, 12(6), 399-402. doi:10.1016/0043-1354(78)90107-0 es_ES
dc.description.references Kempers, A. J., & Kok, C. J. (1989). Re-examination of the determination of ammonium as the indophenol blue complex using salicylate. Analytica Chimica Acta, 221, 147-155. doi:10.1016/s0003-2670(00)81948-0 es_ES
dc.description.references Yu, H., Yang, L., Li, D., & Chen, Y. (2021). A hybrid intelligent soft computing method for ammonia nitrogen prediction in aquaculture. Information Processing in Agriculture, 8(1), 64-74. doi:10.1016/j.inpa.2020.04.002 es_ES
dc.description.references Wang, C., Li, Z., Pan, Z., & Li, D. (2018). Development and characterization of a highly sensitive fluorometric transducer for ultra low aqueous ammonia nitrogen measurements in aquaculture. Computers and Electronics in Agriculture, 150, 364-373. doi:10.1016/j.compag.2018.05.011 es_ES
dc.description.references Fernandez, C. A., Hortance, N. M., Liu, Y.-H., Lim, J., Hatzell, K. B., & Hatzell, M. C. (2020). Opportunities for intermediate temperature renewable ammonia electrosynthesis. Journal of Materials Chemistry A, 8(31), 15591-15606. doi:10.1039/d0ta03753b es_ES
dc.description.references Guo, J., & Chen, P. (2017). Catalyst: NH3 as an Energy Carrier. Chem, 3(5), 709-712. doi:10.1016/j.chempr.2017.10.004 es_ES
dc.description.references Sclafani, A., Augugliaro, V., & Schiavello, M. (1983). Dinitrogen Electrochemical Reduction to Ammonia over Iron Cathode in Aqueous Medium. Journal of The Electrochemical Society, 130(3), 734-736. doi:10.1149/1.2119794 es_ES
dc.description.references Zhou, F., Azofra, L. M., Ali, M., Kar, M., Simonov, A. N., McDonnell-Worth, C., … MacFarlane, D. R. (2017). Electro-synthesis of ammonia from nitrogen at ambient temperature and pressure in ionic liquids. Energy & Environmental Science, 10(12), 2516-2520. doi:10.1039/c7ee02716h es_ES
dc.description.references Mcdonald, M., Fuller, J., Fortunelli, A., Goddard, W. A., & An, Q. (2019). Highly Efficient Ni-Doped Iron Catalyst for Ammonia Synthesis from Quantum-Mechanics-Based Hierarchical High-Throughput Catalyst Screening. The Journal of Physical Chemistry C, 123(28), 17375-17383. doi:10.1021/acs.jpcc.9b04386 es_ES
dc.description.references Chen, S., Perathoner, S., Ampelli, C., Mebrahtu, C., Su, D., & Centi, G. (2017). Electrocatalytic Synthesis of Ammonia at Room Temperature and Atmospheric Pressure from Water and Nitrogen on a Carbon-Nanotube-Based Electrocatalyst. Angewandte Chemie International Edition, 56(10), 2699-2703. doi:10.1002/anie.201609533 es_ES
dc.description.references Wang, H.-B., Wang, J.-Q., Zhang, R., Cheng, C.-Q., Qiu, K.-W., Yang, Y., … Du, X.-W. (2020). Bionic Design of a Mo(IV)-Doped FeS2 Catalyst for Electroreduction of Dinitrogen to Ammonia. ACS Catalysis, 10(9), 4914-4921. doi:10.1021/acscatal.0c00271 es_ES
dc.description.references Bower, C. E., & Holm-Hansen, T. (1980). A Salicylate–Hypochlorite Method for Determining Ammonia in Seawater. Canadian Journal of Fisheries and Aquatic Sciences, 37(5), 794-798. doi:10.1139/f80-106 es_ES
dc.description.references Le, P. T. T., & Boyd, C. E. (2012). Comparison of Phenate and Salicylate Methods for Determination of Total Ammonia Nitrogen in Freshwater and Saline Water. Journal of the World Aquaculture Society, 43(6), 885-889. doi:10.1111/j.1749-7345.2012.00616.x es_ES
dc.description.references Pym, R. V. E., & Milham, P. J. (1976). Selectivity of reaction among chlorine, ammonia, and salicylate for determination of ammonia. Analytical Chemistry, 48(9), 1413-1415. doi:10.1021/ac50003a035 es_ES
dc.description.references Krom, M. D. (1980). Spectrophotometric determination of ammonia: a study of a modified Berthelot reaction using salicylate and dichloroisocyanurate. The Analyst, 105(1249), 305. doi:10.1039/an9800500305 es_ES
dc.description.references Viollier, E., Inglett, P. ., Hunter, K., Roychoudhury, A. ., & Van Cappellen, P. (2000). The ferrozine method revisited: Fe(II)/Fe(III) determination in natural waters. Applied Geochemistry, 15(6), 785-790. doi:10.1016/s0883-2927(99)00097-9 es_ES
dc.description.references Yegorov, D. Y., Kozlov, A. V., Azizova, O. A., & Vladimirov, Y. A. (1993). Simultaneous determination of Fe(III) and Fe(II) in water solutions and tissue homogenates using desferal and 1,10-phenanthroline. Free Radical Biology and Medicine, 15(6), 565-574. doi:10.1016/0891-5849(93)90158-q es_ES
dc.description.references BAG, H., TÜRKER, A. R., TUNÇELI, A., & LALE, M. (2001). Determination of Fe(II)and Fe(III)in Water by Flame Atomic Absorption Spectrophotometry after Their Separation with Aspergillus niger Immobilized on Sepiolite. Analytical Sciences, 17(7), 901-904. doi:10.2116/analsci.17.901 es_ES
dc.description.references Kaasalainen, H., Stefánsson, A., & Druschel, G. K. (2016). Determination of Fe(II), Fe(III) and Fetotal in thermal water by ion chromatography spectrophotometry (IC-Vis). International Journal of Environmental Analytical Chemistry, 96(11), 1074-1090. doi:10.1080/03067319.2016.1232717 es_ES
dc.description.references Pu, X., Hu, B., Jiang, Z., & Huang, C. (2005). Speciation of dissolved iron(ii) and iron(iii) in environmental water samples by gallic acid-modified nanometer-sized alumina micro-column separation and ICP-MS determination. The Analyst, 130(8), 1175. doi:10.1039/b502548f es_ES
dc.subject.ods 07.- Asegurar el acceso a energías asequibles, fiables, sostenibles y modernas para todos es_ES


Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem