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Nanometer-thick films of antimony oxide nanoparticles grafted on defective graphenes as heterogeneous base catalysts for coupling reactions

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Nanometer-thick films of antimony oxide nanoparticles grafted on defective graphenes as heterogeneous base catalysts for coupling reactions

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dc.contributor.author Simion, Andrada es_ES
dc.contributor.author Candu, Natalia es_ES
dc.contributor.author COJOCARU, BOGDAN es_ES
dc.contributor.author Coman, Simona M. es_ES
dc.contributor.author Bucur, C. es_ES
dc.contributor.author Forneli Rubio, Mª Amparo es_ES
dc.contributor.author Primo Arnau, Ana Maria es_ES
dc.contributor.author Man, Isabela Costinela es_ES
dc.contributor.author PARVULESCU, VASILE I. es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2021-06-01T03:31:43Z
dc.date.available 2021-06-01T03:31:43Z
dc.date.issued 2020-10 es_ES
dc.identifier.issn 0021-9517 es_ES
dc.identifier.uri http://hdl.handle.net/10251/166998
dc.description.abstract [EN] Films of few-layers defective N-doped or undoped graphene (10-15 nm) containing antimony oxide nanoparticles (15-30 nm) have been prepared on quartz by pyrolysis of alginate or chitosan adsorbing Sb(OAc)(3). XPS shows that the prevalent Sb oxidation state is +III, while thermoprogrammed CO2 desorption shows that these films exhibit basic sites. These thin films have used as basic catalysts to promote the Michael addition of active methylene compounds and the Henry condensation. These results have been rationalized by DFT calculations that have shown that undercoordinated or two-fold coordinated oxygen atoms on SbOx clusters can act as basic sites, providing a wide range of basic strength. (c) 2020 Elsevier Inc. All rights reserved. es_ES
dc.description.sponsorship This work was supported by UEFISCDI (PN-III-P4-ID-PCE-2016-0146, nr. 121/2017 and project number PN-III-P1-1.1-TE-2016-2191, nr. 89/2018) and by the Spanish Ministry of Science and Innovation (Severo Ochoa and RTI2018-890237-CO2-1). es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation MINECO/RTI2018-890237-CO2-R1 es_ES
dc.relation.ispartof Journal of Catalysis es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Antinomy oxide nanoparticles as base es_ES
dc.subject Graphene as support es_ES
dc.subject Michael addition catalyst es_ES
dc.subject Henry condensation catalyst es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Nanometer-thick films of antimony oxide nanoparticles grafted on defective graphenes as heterogeneous base catalysts for coupling reactions es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.jcat.2020.07.033 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UEFISCDI//PN-III-P4-ID-PCE-2016-0146 121%2F2017/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UEFISCDI//PN-III-P1-1.1-TE-2016-2191 89%2F2018/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Simion, A.; Candu, N.; Cojocaru, B.; Coman, SM.; Bucur, C.; Forneli Rubio, MA.; Primo Arnau, AM.... (2020). Nanometer-thick films of antimony oxide nanoparticles grafted on defective graphenes as heterogeneous base catalysts for coupling reactions. Journal of Catalysis. 390:135-149. https://doi.org/10.1016/j.jcat.2020.07.033 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.jcat.2020.07.033 es_ES
dc.description.upvformatpinicio 135 es_ES
dc.description.upvformatpfin 149 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 390 es_ES
dc.relation.pasarela S\433462 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Executive Agency for Higher Education, Scientific Research, Development and Innovation Funding, Rumanía es_ES
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