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Performance of graphene oxide-modified electrodeposited ZnO/Cu2O heterojunction solar cells

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Performance of graphene oxide-modified electrodeposited ZnO/Cu2O heterojunction solar cells

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dc.contributor.author Rosas-Laverde, Nelly Maria es_ES
dc.contributor.author Pruna, Alina Iuliana es_ES
dc.contributor.author Cembrero Gil, Jesús es_ES
dc.contributor.author Orozco-Messana, Javier es_ES
dc.contributor.author Manjón, Francisco-Javier es_ES
dc.date.accessioned 2021-07-14T03:31:32Z
dc.date.available 2021-07-14T03:31:32Z
dc.date.issued 2019-12 es_ES
dc.identifier.issn 0366-3175 es_ES
dc.identifier.uri http://hdl.handle.net/10251/169187
dc.description.abstract [EN] We report the fabrication of ZnO/Cu2O heterojunction solar cells by means of the electrodeposition technique. The effect of electrolyte medium for the ZnO deposition, annealing treatment and interface modification with graphene oxide (GO) layer on the photoelectrical properties was analyzed. The electrochemical results indicated a markedly dependent Cu2O film electrodeposition on the GO-modified ZnO films. The modification of ZnO/Cu2O interface with GO nanosheets and annealing treatment results in improved interface properties, varying morphology and defects in ZnO lattice that further lead to enhanced performance of the proposed heterojunction solar cells. While the obtained results indicate that the properties of GO coating need to be tailored for improved performance, a synergetic effect of the GO addition and annealing treatment on the photoelectric properties of the electrodeposited heterojunction is achieved. (C) 2019 SECV. Published by Elsevier Espana, S.L.U. es_ES
dc.description.abstract [ES] Se presenta la fabricación de celdas solares de heterounión de ZnO/Cu2O obtenidas mediante la técnica de electrodeposición. Se analizó el efecto del electrolito utilizado para la deposición de ZnO, el tratamiento térmico aplicado y la modificación de la interfaz con una capa de óxido de grafeno (GO) sobre las propiedades fotoeléctricas. Los resultados electroquímicos indicaron que existe una marcada dependencia de electrodeposición de capa de Cu2O sobre las películas de ZnO modificadas con GO. La modificación de la interfaz ZnO/Cu2O con nanohojas de GO y el tratamiento térmico dan como resultado mejoras en las propiedades de la interfaz, una morfología variable y defectos en la red de ZnO que conducen a un mejor rendimiento de las celdas solares de heterounión propuestas. Si bien los resultados obtenidos indican que las propiedades del recubrimiento de GO deben adaptarse para mejorar el rendimiento, se logra un efecto sinérgico del tratamiento de adición y térmico de GO aplicados sobre las propiedades fotoeléctricas de la heterounión electrodepositada. es_ES
dc.description.sponsorship Financial support from Escuela Politécnica Nacional (project number PIMI 15-09), Secretaría de Educación Superior, Ciencia, Tecnología e Innovación (SENESCYT) of Ecuador, Romanian National Authority for Scientific Research and Innovation CNCS ¿ UEFISCDI (project number PN-III-P1-1.1-TE-2016-1544), Spanish government MINECO (projects MAT2016-75586-C4-2-P and MAT2015-71070-REDC) and from Generalitat Valenciana (project PROMETEO 2018/123 ¿ EFIMAT) is gratefully acknowledged. In addition, authors would like to thank to the Microscopy Service of UPV and Dr. David Busquets-Mataix for useful advice. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Boletín de la Sociedad Española de Cerámica y Vidrio es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Electrochemical deposition es_ES
dc.subject ZnO es_ES
dc.subject Cu2O es_ES
dc.subject Solar cells es_ES
dc.subject Deposición electroquímica es_ES
dc.subject Celdas solares es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Performance of graphene oxide-modified electrodeposited ZnO/Cu2O heterojunction solar cells es_ES
dc.title.alternative Rendimiento de las celdas solares de heterounión ZnO/Cu2O modificadas con óxido de grafeno es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.bsecv.2019.06.002 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EPN//PIMI 15-09/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CNCS//PN-III-P1-1.1-TE-2016-1544/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2018%2F123/ES/Materiales avanzados para el uso eficiente de la energia (EFIMAT)/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2016-75586-C4-2-P/ES/COMPUESTOS ABO3 Y A2X3 EN CONDICIONES EXTREMAS DE PRESION Y TEMPERATURA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2015-71070-REDC/ES/MATERIA A ALTA PRESION. MALTA-CONSOLIDER TEAM/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.description.bibliographicCitation Rosas-Laverde, NM.; Pruna, AI.; Cembrero Gil, J.; Orozco-Messana, J.; Manjón, F. (2019). Performance of graphene oxide-modified electrodeposited ZnO/Cu2O heterojunction solar cells. Boletín de la Sociedad Española de Cerámica y Vidrio. 58(6):263-273. https://doi.org/10.1016/j.bsecv.2019.06.002 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.bsecv.2019.06.002 es_ES
dc.description.upvformatpinicio 263 es_ES
dc.description.upvformatpfin 273 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 58 es_ES
dc.description.issue 6 es_ES
dc.relation.pasarela S\398421 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder National Research Council, Rumanía es_ES
dc.contributor.funder Escuela Politécnica Nacional, Ecuador es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Secretaría de Educación Superior, Ciencia, Tecnología e Innovación, Ecuador es_ES
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