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Tailoring La(2-x)A(x)Ni(1-y)ByO(4+delta) cathode performance by simultaneous A and B doping for IT-SOFC

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Tailoring La(2-x)A(x)Ni(1-y)ByO(4+delta) cathode performance by simultaneous A and B doping for IT-SOFC

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dc.contributor.author Navarrete Algaba, Laura es_ES
dc.contributor.author Fabuel Robledo, Maria es_ES
dc.contributor.author Yoo, C.-Y. es_ES
dc.contributor.author Serra Alfaro, José Manuel es_ES
dc.date.accessioned 2021-07-16T03:31:42Z
dc.date.available 2021-07-16T03:31:42Z
dc.date.issued 2020-06-08 es_ES
dc.identifier.issn 0360-3199 es_ES
dc.identifier.uri http://hdl.handle.net/10251/169349
dc.description.abstract [EN] The present work focuses on the study of different Ruddlesden-Popper based cathode materials for Solid Oxide Fuel Cells at Intermediate Temperature (IT-SOFC). The partial substitution of La and Ni by Pr and Co, respectively, were studied in the La(2-x)A(x)Ni(1-y)ByO(4+delta) system, with the purpose of enhancing their mixed ionic-electronic conductivity and the electrocatalytic activity for the O-2-reduction while the crystal structure was preserved. All synthesized compounds were characterized by electrochemical impedance spectroscopy (EIS), DC conductivity measurements, X-Ray diffraction (XRD), iodometric titration and scanning electron microscopy (SEM). XRD analyses by Rietveld refinement revealed the influence of the ionic radius on the crystalline phase for the different dopants, i.e., variation of the cell parameters and M-O bond lengths. The substitution in both La and Ni sites improves La2NiO4+delta electrochemical properties as IT-SOFC cathode, since higher conductivity and lower polarization resistance were obtained. Finally, La1.5Pr0.5Ni0.8Co0.2O4+delta cathode exhibited the lowest electrode polarization resistance and activation energy values in the temperature range of 450-900 degrees C. La1.5Pr0.5Ni0.8Co0.2O4+delta was applied on an anode supported cell and a maximum power density of similar to 400 mW cm(-2) was obtained at 700 degrees C using pure hydrogen and air. es_ES
dc.description.sponsorship This work was financially supported by Spanish Government (Grants SEV-2016-0683 and RTI2018-102161) and Generalitat Valenciana (PROMETEO/2018/006). Vicente B. Vert, Ji Haeng Yu and Dae Sik Yun are kindly acknowledged for their support during this work preparation and Forschungszentrum Julich for providing the anode supported cell. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof International Journal of Hydrogen Energy es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.title Tailoring La(2-x)A(x)Ni(1-y)ByO(4+delta) cathode performance by simultaneous A and B doping for IT-SOFC es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.ijhydene.2020.03.150 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2018%2F006/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-102161-B-I00/ES/CONVERSION DIRECTA DE CO2 EN PORTADORES DE ENERGIA QUIMICA UTILIZANDO REACTORES ELECTROCATALITICOS DE MEMBRANA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Navarrete Algaba, L.; Fabuel Robledo, M.; Yoo, C.; Serra Alfaro, JM. (2020). Tailoring La(2-x)A(x)Ni(1-y)ByO(4+delta) cathode performance by simultaneous A and B doping for IT-SOFC. International Journal of Hydrogen Energy. 45(31):15589-15599. https://doi.org/10.1016/j.ijhydene.2020.03.150 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.ijhydene.2020.03.150 es_ES
dc.description.upvformatpinicio 15589 es_ES
dc.description.upvformatpfin 15599 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 45 es_ES
dc.description.issue 31 es_ES
dc.relation.pasarela S\418561 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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