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Manufacturing and compatibilization of binary blends of polyethylene and poly(bulylene succinate) by injection molding

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Manufacturing and compatibilization of binary blends of polyethylene and poly(bulylene succinate) by injection molding

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dc.contributor.author Rojas-Lema, Sandra es_ES
dc.contributor.author Ivorra-Martinez, Juan es_ES
dc.contributor.author Gomez-Caturla, Jaume es_ES
dc.contributor.author Balart, Rafael es_ES
dc.contributor.author Garcia-Garcia, Daniel es_ES
dc.date.accessioned 2021-07-20T10:21:13Z
dc.date.available 2021-07-20T10:21:13Z
dc.date.issued 2021-07-16
dc.identifier.uri http://hdl.handle.net/10251/169561
dc.description.abstract [EN] In this study was analyzed the effect of three different compatibilizers polyethylene-graft-maleic anhydride (PE-g-MA), unmodified halloysite nanotubes (HNTs), and HNTs treated by silanization with (3-glycidyloxypropyl) trimethoxysilane (GLYMO) (silanized HNTs) in blends of bio-based high-density polyethylene (bioPE) and poly(butylene succinate) (PBS) with a weight ratio of (70/30). Each compatibilizer was added in a proportion of (3 phr regarding PBS). Standard samples were obtained by extrusion and subsequent injection molding. The analyzes of the samples were performed by mechanical tests, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMTA), field emission scanning electron microscopy (FESEM), and wettability (θw). Results suggest that the addition of modified HNTs (silanized HNTs) allowed to obtain better properties than samples compatibilized with unmodified HNTs and PE-g-MA, due to it contributes with the improvement in mechanical properties regarding bioPE/PBS blend, for instance, the tensile modulus and elongation at break increase about 8% and 13%, respectively. In addition, it was determined through FESEM images and that silanized HNTs particles were better dispersed over the matrix, which in fact contribute to the enhance in mechanical properties. TGA showed that silanized HNTs delay the degradation temperature regarding the uncompatibilized blend. While DMTA indicated the reduction in the mobility of the chains in samples with unmodified and modified HNTs. Therefore, it was successfully obtained compatibilized bioPE/PBS blends, which constitutes an interesting option to develop new sustainable polymers. es_ES
dc.language Inglés es_ES
dc.publisher Universitat Politècnica de València es_ES
dc.relation.ispartof Journal of Applied Research in Technology & Engineering es_ES
dc.rights Reconocimiento - No comercial - Compartir igual (by-nc-sa) es_ES
dc.subject Blends es_ES
dc.subject Halloysite nanotubes es_ES
dc.subject PE-g-MA es_ES
dc.subject Compatibility es_ES
dc.title Manufacturing and compatibilization of binary blends of polyethylene and poly(bulylene succinate) by injection molding es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.4995/jarte.2021.15727
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Escuela Politécnica Superior de Alcoy - Escola Politècnica Superior d'Alcoi es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.description.bibliographicCitation Rojas-Lema, S.; Ivorra-Martinez, J.; Gomez-Caturla, J.; Balart, R.; Garcia-Garcia, D. (2021). Manufacturing and compatibilization of binary blends of polyethylene and poly(bulylene succinate) by injection molding. Journal of Applied Research in Technology & Engineering. 2(2):71-81. https://doi.org/10.4995/jarte.2021.15727 es_ES
dc.description.accrualMethod OJS es_ES
dc.relation.publisherversion https://doi.org/10.4995/jarte.2021.15727 es_ES
dc.description.upvformatpinicio 71 es_ES
dc.description.upvformatpfin 81 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 2 es_ES
dc.description.issue 2 es_ES
dc.identifier.eissn 2695-8821
dc.relation.pasarela OJS\15727 es_ES
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