Comparison between an electrochemical reactor with and without membrane for the nor oxidation using novel ceramic electrodes
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Comparison between an electrochemical reactor with and without membrane for the nor oxidation using novel ceramic electrodes
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| dc.contributor.author | Carrillo-Abad, Jordi
|
es_ES |
| dc.contributor.author | Mora-Gómez, Julia
|
es_ES |
| dc.contributor.author | García Gabaldón, Montserrat
|
es_ES |
| dc.contributor.author | Mestre, S.
|
es_ES |
| dc.contributor.author | Pérez-Herranz, Valentín
|
es_ES |
| dc.date.accessioned | 2021-07-23T03:31:13Z | |
| dc.date.available | 2021-07-23T03:31:13Z | |
| dc.date.issued | 2020-08-15 | es_ES |
| dc.identifier.issn | 0301-4797 | es_ES |
| dc.identifier.uri | http://hdl.handle.net/10251/169900 | |
| dc.description.abstract | [EN] The electrochemical oxidation of the antibiotic Norfloxacin (NOR) in chloride media on different anodic materials was studied at two different electrochemical reactors. The results were compared with those obtained in sulphate media. The anodes under study were a commercial boron-doped diamond (BBD) and two different ceramic electrodes based on tin oxide doped with antimony oxide in the presence (CuO) and absence (BCE) of copper oxide as sintering aid. The reactors employed were a one-compartment reactor (OCR) and a two-compartment one with a membrane separating both electrodes (EMR). The use of the membrane clearly enhanced both NOR degradation and TOC mineralization for all the anodic materials studied since some parallel reactions were avoided. Additionally, two different pathways for NOR oxidation were observed as a function of the reactor employed. The EMR also favoured the ionic by-products generation and the electrolyte dechlorination. NO3¿ increased with the oxidation power of the anode employed and it was also enhanced by the EMR use. Chloride media favours ceramic electrodes performance independently of the reactor employed as they did not generate an excess of oxidants as BDD did. The BCE electrode is an interesting alternative to BDD since although its oxidative power was lower, it presented similar current efficiency with lower energy consumption. | es_ES |
| dc.description.sponsorship | The authors want to express their gratitude to the Ministerio de Economia y Competitividad (Spain) and the FEDER funds, which financially support the project RTI2018-101341-B-C21. | es_ES |
| dc.language | Inglés | es_ES |
| dc.publisher | Elsevier | es_ES |
| dc.relation.ispartof | Journal of Environmental Management | es_ES |
| dc.rights | Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) | es_ES |
| dc.subject | Norfloxacin (NOR) | es_ES |
| dc.subject | Boron-doped diamond (BDD) anode | es_ES |
| dc.subject | Ceramic anodes | es_ES |
| dc.subject | Electro-oxidation | es_ES |
| dc.subject | Electrochemical membrane reactor | es_ES |
| dc.subject.classification | INGENIERIA QUIMICA | es_ES |
| dc.title | Comparison between an electrochemical reactor with and without membrane for the nor oxidation using novel ceramic electrodes | es_ES |
| dc.type | Artículo | es_ES |
| dc.identifier.doi | 10.1016/j.jenvman.2020.110710 | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101341-B-C21/ES/ELECTROCHEMICAL CHARACTERIZATION OF CERAMIC ELECTRODES AND MEMBRANES AND APPLICATION TO PHOTOELECTROOXIDATION AND ELECTROFILTRATION PROCESSES/ | es_ES |
| dc.rights.accessRights | Abierto | es_ES |
| dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear | es_ES |
| dc.description.bibliographicCitation | Carrillo-Abad, J.; Mora-Gómez, J.; García Gabaldón, M.; Mestre, S.; Pérez-Herranz, V. (2020). Comparison between an electrochemical reactor with and without membrane for the nor oxidation using novel ceramic electrodes. Journal of Environmental Management. 268:1-9. https://doi.org/10.1016/j.jenvman.2020.110710 | es_ES |
| dc.description.accrualMethod | S | es_ES |
| dc.relation.publisherversion | https://doi.org/10.1016/j.jenvman.2020.110710 | es_ES |
| dc.description.upvformatpinicio | 1 | es_ES |
| dc.description.upvformatpfin | 9 | es_ES |
| dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
| dc.description.volume | 268 | es_ES |
| dc.identifier.pmid | 32510444 | es_ES |
| dc.relation.pasarela | S\417901 | es_ES |
| dc.contributor.funder | European Regional Development Fund | es_ES |
| dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
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| dc.subject.ods | 06.- Garantizar la disponibilidad y la gestión sostenible del agua y el saneamiento para todos | es_ES |
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