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Comparison between an electrochemical reactor with and without membrane for the nor oxidation using novel ceramic electrodes

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Comparison between an electrochemical reactor with and without membrane for the nor oxidation using novel ceramic electrodes

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dc.contributor.author Carrillo-Abad, Jordi es_ES
dc.contributor.author Mora-Gómez, Julia es_ES
dc.contributor.author García Gabaldón, Montserrat es_ES
dc.contributor.author Mestre, S. es_ES
dc.contributor.author Pérez-Herranz, Valentín es_ES
dc.date.accessioned 2021-07-23T03:31:13Z
dc.date.available 2021-07-23T03:31:13Z
dc.date.issued 2020-08-15 es_ES
dc.identifier.issn 0301-4797 es_ES
dc.identifier.uri http://hdl.handle.net/10251/169900
dc.description.abstract [EN] The electrochemical oxidation of the antibiotic Norfloxacin (NOR) in chloride media on different anodic materials was studied at two different electrochemical reactors. The results were compared with those obtained in sulphate media. The anodes under study were a commercial boron-doped diamond (BBD) and two different ceramic electrodes based on tin oxide doped with antimony oxide in the presence (CuO) and absence (BCE) of copper oxide as sintering aid. The reactors employed were a one-compartment reactor (OCR) and a two-compartment one with a membrane separating both electrodes (EMR). The use of the membrane clearly enhanced both NOR degradation and TOC mineralization for all the anodic materials studied since some parallel reactions were avoided. Additionally, two different pathways for NOR oxidation were observed as a function of the reactor employed. The EMR also favoured the ionic by-products generation and the electrolyte dechlorination. NO3¿ increased with the oxidation power of the anode employed and it was also enhanced by the EMR use. Chloride media favours ceramic electrodes performance independently of the reactor employed as they did not generate an excess of oxidants as BDD did. The BCE electrode is an interesting alternative to BDD since although its oxidative power was lower, it presented similar current efficiency with lower energy consumption. es_ES
dc.description.sponsorship The authors want to express their gratitude to the Ministerio de Economia y Competitividad (Spain) and the FEDER funds, which financially support the project RTI2018-101341-B-C21. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Journal of Environmental Management es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Norfloxacin (NOR) es_ES
dc.subject Boron-doped diamond (BDD) anode es_ES
dc.subject Ceramic anodes es_ES
dc.subject Electro-oxidation es_ES
dc.subject Electrochemical membrane reactor es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Comparison between an electrochemical reactor with and without membrane for the nor oxidation using novel ceramic electrodes es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.jenvman.2020.110710 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101341-B-C21/ES/ELECTROCHEMICAL CHARACTERIZATION OF CERAMIC ELECTRODES AND MEMBRANES AND APPLICATION TO PHOTOELECTROOXIDATION AND ELECTROFILTRATION PROCESSES/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Carrillo-Abad, J.; Mora-Gómez, J.; García Gabaldón, M.; Mestre, S.; Pérez-Herranz, V. (2020). Comparison between an electrochemical reactor with and without membrane for the nor oxidation using novel ceramic electrodes. Journal of Environmental Management. 268:1-9. https://doi.org/10.1016/j.jenvman.2020.110710 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.jenvman.2020.110710 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 9 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 268 es_ES
dc.identifier.pmid 32510444 es_ES
dc.relation.pasarela S\417901 es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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dc.subject.ods 06.- Garantizar la disponibilidad y la gestión sostenible del agua y el saneamiento para todos es_ES


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