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Citrate adsorption on gold: Understanding the shaping mechanism of nanoparticles

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Citrate adsorption on gold: Understanding the shaping mechanism of nanoparticles

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dc.contributor.author Gisbert-González, José M. es_ES
dc.contributor.author Cheuquepán, William es_ES
dc.contributor.author Ferre Vilaplana, Adolfo es_ES
dc.contributor.author Herrero, Enrique es_ES
dc.contributor.author Feliu, Juan M. es_ES
dc.date.accessioned 2021-07-27T03:37:46Z
dc.date.available 2021-07-27T03:37:46Z
dc.date.issued 2020-10-15 es_ES
dc.identifier.issn 1572-6657 es_ES
dc.identifier.uri http://hdl.handle.net/10251/170278
dc.description.abstract [EN] Advanced applications of colloidal nanoparticles (NPs) become to depend on their specific shape, which is controlled by the adsorption behavior of the capping agent involved in their synthesis. To understand the way in which citric acid determines the shape of gold NPs, the adsorption behavior of citrate on gold under the synthesis conditions is here investigated from electrochemical experiments on well-defined surfaces. Gibb excesses and charge numbers for the citrate adlayers deposited on the Au (111), Au(100) and Au(110) electrodes when a potential is applied were estimated at pHs 1 and 3. From these results, FTIR spectra and DFT calculations, it is concluded that solvated citrate can become simultaneously adsorbed through three dehydrogenated carboxylic groups in bidentate configuration on Au(111), but only through two on Au(100) and Au(110). As a result of this behavior, citrate can become more strongly adsorbed on Au(111) than on the other two basal planes of gold under the synthesis conditions, which would explain why tetrahedral and octahedral colloidal gold NPs are preferentially shaped when citric acid is used as the capping agent in water. This conclusion coincides with the previously one obtained on platinum, suggesting that the mechanism here described would operate also on other metals having fcc structure. es_ES
dc.description.sponsorship This work has been financially supported by the MCINN-FEDER (Spain) through project CTQ2016-76221-P. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Journal of Electroanalytical Chemistry es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject.classification LENGUAJES Y SISTEMAS INFORMATICOS es_ES
dc.title Citrate adsorption on gold: Understanding the shaping mechanism of nanoparticles es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.jelechem.2020.114015 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2016-76221-P/ES/ESTRUCTURA INTERFACIAL Y REACTIVIDAD ELECTROQUIMICA/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Sistemas Informáticos y Computación - Departament de Sistemes Informàtics i Computació es_ES
dc.description.bibliographicCitation Gisbert-González, JM.; Cheuquepán, W.; Ferre Vilaplana, A.; Herrero, E.; Feliu, JM. (2020). Citrate adsorption on gold: Understanding the shaping mechanism of nanoparticles. Journal of Electroanalytical Chemistry. 875:1-11. https://doi.org/10.1016/j.jelechem.2020.114015 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.jelechem.2020.114015 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 11 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 875 es_ES
dc.relation.pasarela S\427482 es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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dc.subject.ods 03.- Garantizar una vida saludable y promover el bienestar para todos y todas en todas las edades es_ES


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