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Tracking homogeneous reactions during electrodialysis of organic acids via EIS

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Tracking homogeneous reactions during electrodialysis of organic acids via EIS

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dc.contributor.author Martí Calatayud, Manuel César es_ES
dc.contributor.author Evdochenko, E. es_ES
dc.contributor.author Bär, J. es_ES
dc.contributor.author García Gabaldón, Montserrat es_ES
dc.contributor.author Wessling, M. es_ES
dc.contributor.author Pérez-Herranz, Valentín es_ES
dc.date.accessioned 2021-07-28T03:30:57Z
dc.date.available 2021-07-28T03:30:57Z
dc.date.issued 2020-02-01 es_ES
dc.identifier.issn 0376-7388 es_ES
dc.identifier.uri http://hdl.handle.net/10251/170578
dc.description.abstract [EN] Organic acids are highly valuable platform chemicals that can be obtained from bioresources and subsequently transformed into a wide spectrum of profitable consumer goods. After their synthesis, organic acids need to be separated from other by-products and conveniently upconcentrated. Based on the ionic nature of organic acids, electromembrane processes are viable technologies for their recovery. Transport of weak acids through ion- exchange membranes is a complex process influenced by multiple phenomena, i.e. concentration polarization, water dissociation and counterion-membrane interactions. In the present study, the transport of two different organic acids (citric and oxalic acid) through anion-exchange membranes is investigated by means of using linear sweep voltammetry, chronopotentiometry and electrochemical impedance spectroscopy (EIS). Results have shown that, at pH values where multivalent acid anions predominate in solution, a first limiting current density is registered in the current-voltage curves, followed by an increase in membrane resistance. A further increase in current leads to a second limiting current density and a steeper increase in membrane resistance associated with an intensified ion depletion. A strong correlation between polarization curves and electrochemical impedance measurements reveals that such increase in resistance is prompted by generation of Hþ and OH? ions and the concomitant onset of homogeneous reactions in very thin solution layers. The generation of Hþ and OH? ions is tracked by a Gerischer arc in the impedance spectra. As the polarization level increases, the subsequent reaction of multivalent anions into lower-charge acid anions involves the evolution of additional Gerischer arcs. Furthermore, the lower conductivity of the reaction products correlates with the increased system resistance. The characteristic times of these reactions are in the order of milliseconds, thus being only directly accessible with the use of frequency response analysis techniques, such as EIS. es_ES
dc.description.sponsorship M.C. Marti-Calatayud acknowledges the support of Generalitat Valenciana through the funding APOSTD/2017/059. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Journal of Membrane Science es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Electrodialysis es_ES
dc.subject Weak electrolytes es_ES
dc.subject Electrochemical impedance spectroscopy (EIS) es_ES
dc.subject Platform chemicals es_ES
dc.subject Organic acid recovery es_ES
dc.subject Biorefinery es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Tracking homogeneous reactions during electrodialysis of organic acids via EIS es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.memsci.2019.117592 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//APOSTD%2F2017%2F059/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Martí Calatayud, MC.; Evdochenko, E.; Bär, J.; García Gabaldón, M.; Wessling, M.; Pérez-Herranz, V. (2020). Tracking homogeneous reactions during electrodialysis of organic acids via EIS. Journal of Membrane Science. 595:1-10. https://doi.org/10.1016/j.memsci.2019.117592 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.memsci.2019.117592 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 10 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 595 es_ES
dc.relation.pasarela S\410165 es_ES
dc.contributor.funder GENERALITAT VALENCIANA es_ES
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dc.subject.ods 08.- Fomentar el crecimiento económico sostenido, inclusivo y sostenible, el empleo pleno y productivo, y el trabajo decente para todos es_ES
dc.subject.ods 13.- Tomar medidas urgentes para combatir el cambio climático y sus efectos es_ES


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