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Synthesis of isomorphically substituted Ru manganese molecular sieves and their catalytic properties for selective alcohol oxidation

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Synthesis of isomorphically substituted Ru manganese molecular sieves and their catalytic properties for selective alcohol oxidation

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dc.contributor.author Sabate-Fornons, Ferran es_ES
dc.contributor.author Jorda Moret, Jose Luis es_ES
dc.contributor.author Sabater Picot, Mª José es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2021-07-30T03:31:03Z
dc.date.available 2021-07-30T03:31:03Z
dc.date.issued 2020-02-21 es_ES
dc.identifier.issn 2050-7488 es_ES
dc.identifier.uri http://hdl.handle.net/10251/170956
dc.description.abstract [EN] Ruthenium has been incorporated into the framework of the cryptomelane type manganese oxide K-OMS-2 ([Ru]-K-OMS2) and the presence of this element into the structure has been assessed by combining analytical and vibrational techniques such as ICP, UV-Vis, FT-IR and Raman spectroscopies, X-ray diffraction, electron microscopy (HR-TEM and SEM), TPR-H-2, and X-ray photoelectron spectroscopy. Rietveld refinement of the X-ray diffractogram has allowed to estimate changes in the values of cell parameters which were compatible with an isomorphic ruthenium substitution into the original structure. These calculations are in agreement with the observed increase in the interplanar spacing of (100) planes from 7.1 angstrom to 7.7 angstrom for the Ru-doped material. es_ES
dc.description.sponsorship Financial support by the European Union through ERC-AdG-2014-671093 (SynCatMatch), the Ministerio de Economia y Competitividad, Programa Severo Ochoa (SEV2016-0683) and Ministerio de Ciencia Innovacion y Universidades, Programa Estatal de Generacion de Conocimiento (PGC2018-101247-B-100) are gratefully acknowledged. F.S. thanks to Ministerio de Ciencia, Innovacion y Universidades for the economic support (Ayuda Predoctoral FPI - Severo Ochoa). The Electron Microscope of the Universitat Politecnica de Valencia is acknowledged for their help in the characterization of samples. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Journal of Materials Chemistry A es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Synthesis of isomorphically substituted Ru manganese molecular sieves and their catalytic properties for selective alcohol oxidation es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c9ta11903e es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-101247-B-I00/ES/RECONOCIMIENTO MOLECULAR EN CATALIZADORES SOLIDOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Sabate-Fornons, F.; Jorda Moret, JL.; Sabater Picot, MJ.; Corma Canós, A. (2020). Synthesis of isomorphically substituted Ru manganese molecular sieves and their catalytic properties for selective alcohol oxidation. Journal of Materials Chemistry A. 8(7):3771-3784. https://doi.org/10.1039/c9ta11903e es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c9ta11903e es_ES
dc.description.upvformatpinicio 3771 es_ES
dc.description.upvformatpfin 3784 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 8 es_ES
dc.description.issue 7 es_ES
dc.relation.pasarela S\404302 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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