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Synthesis of metal-free lightweight materials with sequence-encoded properties

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Synthesis of metal-free lightweight materials with sequence-encoded properties

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dc.contributor.author Azoulay, Adi es_ES
dc.contributor.author Barrio, Jesús es_ES
dc.contributor.author Tzadikov, Jonathan es_ES
dc.contributor.author Volokh, Michael es_ES
dc.contributor.author Albero-Sancho, Josep es_ES
dc.contributor.author Gervais, Christel es_ES
dc.contributor.author Amo-Ochoa, Pilar es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.contributor.author Zamora, Félix es_ES
dc.contributor.author Shalom, Menny es_ES
dc.date.accessioned 2021-07-30T03:31:09Z
dc.date.available 2021-07-30T03:31:09Z
dc.date.issued 2020-05-07 es_ES
dc.identifier.issn 2050-7488 es_ES
dc.identifier.uri http://hdl.handle.net/10251/170959
dc.description.abstract [EN] A high-temperature solid-state synthesis is a widespread tool for the construction of metal-free materials, owing to its simplicity and scalability. However, no method is currently available for the synthesis of metal-free materials, which enables control over the atomic ratio and spatial organization of several heteroatoms. Here we report a general and large-scale synthesis of phosphorus-nitrogen-carbon (PNC) materials with highly controllable elemental composition and structural, electronic, and thermal stability properties. To do so, we designed four different crystals consisting of melamine and phosphoric acid with different monomers sequences as the starting precursors. The monomer sequence of the crystals is preserved upon calcination (up to 800 degrees C) to an unprecedented degree, which leads to precise control over the composition of the final PNC materials. The latter exhibit a remarkable stability up to 970 degrees C in air, positioning them as sustainable, lightweight supports for catalysts in high-temperature reactions as well as halogen-free fire-retardant materials. es_ES
dc.description.sponsorship The authors would like to thank Dr Volodiya Ezersky, Dr Natalya Froumin, Dr Anna Milionshchik, Dr Radion Vainer, Dr Einat Nativ-Roth, and Mr Nitzan Shauloff for analytical HRTEM, XPS, TGA, SC-XRD, HRSEM, and technical support, respectively. This research was partly funded by the following: the Planning & Budgeting Committee/Israel Council for Higher Education (CHE) and Fuel Choice Initiative (Prime Minister Office of Israel), within the framework of "Israel National Research Center for Electrochemical Propulsion" (INREP); the Minerva Center No. 117873; the Spanish Ministerio de Economia y Competitividad (MAT2016-77608-C3-1-P, MAT2016-75883-C2-2-P); J. A. and H. G. also gratefully acknowledges financial support from the Spanish Ministry of Economy and Competitiveness (Severo Ochoa SEV2016-0683 and RTI2018-89023-CO2-R1) and by the Generalitat Valenciana (Prometeo 2017-083). This project has received funding from the European Research Council (ERC) under the European Union's Horizon 2020 Research and Innovation Programme (grant agreement No. [849068]). NMR spectroscopic calculations were performed using HPC resources from GENCI-IDRIS (Grant 097535). The French Region Ile de France-SESAME program is acknowledged for financial support (700 MHz spectrometer). es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation info:eu-repo/grantAgreement/MINECO//RTI2018-89023-CO2-R1 es_ES
dc.relation.ispartof Journal of Materials Chemistry A es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Synthesis of metal-free lightweight materials with sequence-encoded properties es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/d0ta03162c es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/849068/EU/Controlled Growth of Lightweight Metal-Free Materials for Photoelectrochemical Cells/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2016-77608-C3-1-P/ES/MATERIALES BIDIMENSIONALES CON PROPIEDADES MODULABLES II/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2016-75883-C2-2-P/ES/MATERIALES METAL-ORGANICOS BIOINSPIRADOS E INTELIGENTES CON COMPORTAMIENTO ESTIMULO-RESPUESTA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CNRS//097535/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/HUJI//117873/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2017%2F083/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-098237-B-C21/ES/HETEROUNIONES DE GRAFENO CON CONFIGURACION CONTROLADA. SINTESIS Y APLICACIONES COMO SOPORTE EN CATALISIS Y EN ELECTRODOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Azoulay, A.; Barrio, J.; Tzadikov, J.; Volokh, M.; Albero-Sancho, J.; Gervais, C.; Amo-Ochoa, P.... (2020). Synthesis of metal-free lightweight materials with sequence-encoded properties. Journal of Materials Chemistry A. 8(17):8752-8760. https://doi.org/10.1039/d0ta03162c es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/d0ta03162c es_ES
dc.description.upvformatpinicio 8752 es_ES
dc.description.upvformatpfin 8760 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 8 es_ES
dc.description.issue 17 es_ES
dc.relation.pasarela S\432556 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Region Ile-de-France es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Hebrew University of Jerusalem es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Ministry of Science and Technology, Israel es_ES
dc.contributor.funder Centre National de la Recherche Scientifique, Francia es_ES
dc.contributor.funder Israel National Research Center for Electrochemical Propulsion es_ES
dc.contributor.funder Planning and Budgeting Committee of the Council for Higher Education of Israel es_ES
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