- -

Structural modulation and direct measurement of subnanometric bimetallic PtSn clusters confined in zeolites

RiuNet: Institutional repository of the Polithecnic University of Valencia

Share/Send to

Cited by

Statistics

Structural modulation and direct measurement of subnanometric bimetallic PtSn clusters confined in zeolites

Show full item record

Liu, L.; Lopez-Haro, M.; Lopes, CW.; Rojas-Buzo, S.; Concepción Heydorn, P.; Manzorro, R.; Simonelli, L.... (2020). Structural modulation and direct measurement of subnanometric bimetallic PtSn clusters confined in zeolites. Nature Catalysis. 3(8):628-638. https://doi.org/10.1038/s41929-020-0472-7

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/172142

Files in this item

Item Metadata

Title: Structural modulation and direct measurement of subnanometric bimetallic PtSn clusters confined in zeolites
Author: Liu, Lichen Lopez-Haro, Miguel Lopes, Christian W. Rojas-Buzo, Sergio Concepción Heydorn, Patricia Manzorro, Ramon Simonelli, Laura Sattler, Aaron Serna, Pedro Calvino, Jose J. Corma Canós, Avelino
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
[EN] Modulating the structures of subnanometric metal clusters at the atomic level is a great synthetic and characterization challenge in catalysis. Here, we show how the catalytic properties of subnanometric platinum ...[+]
Copyrigths: Reserva de todos los derechos
Source:
Nature Catalysis. (eissn: 2520-1158 )
DOI: 10.1038/s41929-020-0472-7
Publisher:
Nature Publishing Group
Publisher version: https://doi.org/10.1038/s41929-020-0472-7
Project ID:
info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/
info:eu-repo/grantAgreement/CAPES//13191%2F13-6/
info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-87579-R/ES/FASES 2D ULTRAFINAS SOBRE OXIDOS CON MORFOLOGIA CONTROLADA: PLATAFORMA DE NANOCATALIZADORES MULTICOMPONENTE CON APLICACIONES EN PROTECCION DEL MEDIO AMBIENTE/
info:eu-repo/grantAgreement/MINECO//MAT2016-81118-P/ES/DISEÑO Y CARACTERIZACION AVANZADA DE CATALIZADORES CON NANOINTERFASES MODELO AU%2F%2FCEO2/
Thanks:
This work was supported by the European Union through the European Research Council (grant ERC-AdG-2014-671093, SynCatMatch) and the Spanish government through the "Severo Ochoa Program" (SEV-2016-0683). L.L. thanks the ...[+]
Type: Artículo

References

Liu, L. & Corma, A. Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles. Chem. Rev. 118, 4981–5079 (2018).

An, K. & Somorjai, G. A. Nanocatalysis I: synthesis of metal and bimetallic nanoparticles and porous oxides and their catalytic reaction studies. Catal. Lett. 145, 233–248 (2014).

Ferrando, R., Jellinek, J. & Johnston, R. L. Nanoalloys: from theory to applications of alloy clusters and nanoparticles. Chem. Rev. 108, 845–910 (2008). [+]
Liu, L. & Corma, A. Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles. Chem. Rev. 118, 4981–5079 (2018).

An, K. & Somorjai, G. A. Nanocatalysis I: synthesis of metal and bimetallic nanoparticles and porous oxides and their catalytic reaction studies. Catal. Lett. 145, 233–248 (2014).

Ferrando, R., Jellinek, J. & Johnston, R. L. Nanoalloys: from theory to applications of alloy clusters and nanoparticles. Chem. Rev. 108, 845–910 (2008).

Yu, W., Porosoff, M. D. & Chen, J. G. Review of Pt-based bimetallic catalysis: from model surfaces to supported catalysts. Chem. Rev. 112, 5780–5817 (2012).

Resasco, D. E. in Encyclopedia of Catalysis (ed. Horváth, I.) (Wiley, 2002).

Vora, B. V. Development of dehydrogenation catalysts and processes. Top. Catal. 55, 1297–1308 (2012).

Sattler, J. J., Ruiz-Martinez, J., Santillan-Jimenez, E. & Weckhuysen, B. M. Catalytic dehydrogenation of light alkanes on metals and metal oxides. Chem. Rev. 114, 10613–10653 (2014).

Sanfilippo, D. & Miracca, I. Dehydrogenation of paraffins: synergies between catalyst design and reactor engineering. Catal. Today 111, 133–139 (2006).

Redekop, E. A. et al. Delivering a modifying element to metal nanoparticles via support: Pt–Ga alloying during the reduction of Pt/Mg(Al,Ga)Ox catalysts and Its effects on propane dehydrogenation. ACS Catal. 4, 1812–1824 (2014).

Deng, L. et al. Dehydrogenation of propane over silica-supported platinum–tin catalysts prepared by direct reduction: effects of tin/platinum ratio and reduction temperature. ChemCatChem 6, 2680–2691 (2014).

Filez, M., Redekop, E. A., Poelman, H., Galvita, V. V. & Marin, G. B. Advanced elemental characterization during Pt–In catalyst formation by wavelet transformed X-ray absorption spectroscopy. Anal. Chem. 87, 3520–3526 (2015).

Searles, K. et al. Highly productive propane dehydrogenation catalyst using silica-supported Ga–Pt nanoparticles generated from single-sites. J. Am. Chem. Soc. 140, 11674–11679 (2018).

Liu, L. et al. Generation of subnanometric platinum with high stability during transformation of a 2D zeolite into 3D. Nat. Mater. 16, 132–138 (2017).

Moliner, M. et al. Reversible transformation of Pt nanoparticles into single atoms inside high-silica chabazite zeolite. J. Am. Chem. Soc. 138, 15743–15750 (2016).

Liu, L. et al. Evolution and stabilization of subnanometric metal species in confined space by in situ TEM. Nat. Commun. 9, 574 (2018).

Liu, Y. et al. A general strategy for fabricating isolated single metal atomic site catalysts in Y zzeolite. J. Am. Chem. Soc. 141, 9305–9311 (2019).

Liu, L. et al. Regioselective generation and reactivity control of subnanometric platinum clusters in zeolites for high-temperature catalysis. Nat. Mater. 18, 866–873 (2019).

Lazic, I., Bosch, E. G. T. & Lazar, S. Phase contrast STEM for thin samples: integrated differential phase contrast. Ultramicroscopy 160, 265–280 (2016).

Yucelen, E., Lazic, I. & Bosch, E. G. T. Phase contrast scanning transmission electron microscopy imaging of light and heavy atoms at the limit of contrast and resolution. Sci. Rep. 8, 2676 (2018).

Lewis, J. D. et al. Distinguishing active site identity in Sn-Beta zeolites using 31P MAS NMR of adsorbed trimethylphosphine oxide. ACS Catal. 8, 3076–3086 (2018).

Uemura, Y. et al. In situ time-resolved XAFS study on the structural transformation and phase separation of Pt3Sn and PtSn alloy nanoparticles on carbon in the oxidation process. Phys. Chem. Chem. Phys. 13, 15833–15844 (2011).

Ramallo-López, J. M. et al. XPS and XAFS Pt L2,3-edge studies of dispersed metallic Pt and PtSn clusters on SiO2 obtained by organometallic synthesis: structural and electronic characteristics. J. Phys. Chem. B 107, 11441–11451 (2003).

Deng, L. et al. Elucidating strong metal-support interactions in Pt–Sn/SiO2 catalyst and its consequences for dehydrogenation of lower alkanes. J. Catal. 365, 277–291 (2018).

Zhang, B. et al. Exceptional electrochemical performance of freestanding electrospun carbon nanofiber anodes containing ultrafine SnOx particles. Energy Environ. Sci. 5, 9895–9902 (2012).

Collins, S. E. et al. The role of Pd–Ga bimetallic particles in the bifunctional mechanism of selective methanol synthesis via CO2 hydrogenation on a Pd/Ga2O3 catalyst. J. Catal. 292, 90–98 (2012).

Ogata, K. et al. Evolving affinity between Coulombic reversibility and hysteretic phase transformations in nano-structured silicon-based lithium-ion batteries. Nat. Commun. 9, 479 (2018).

Cui, C., Gan, L., Heggen, M., Rudi, S. & Strasser, P. Compositional segregation in shaped Pt alloy nanoparticles and their structural behaviour during electrocatalysis. Nat. Mater. 12, 765–771 (2013).

Pei, Y. et al. Catalytic properties of intermetallic platinum-tin nanoparticles with non-stoichiometric compositions. J. Catal. 374, 136–142 (2019).

Freakley, S. J. et al. Palladium-tin catalysts for the direct synthesis of H2O2 with high selectivity. Science 351, 965–968 (2016).

Mayrhofer, K. J., Juhart, V., Hartl, K., Hanzlik, M. & Arenz, M. Adsorbate-induced surface segregation for core–shell nanocatalysts. Angew. Chem. Int. Ed. 48, 3529–3531 (2009).

Peng, L., Ringe, E., Van Duyne, R. P. & Marks, L. D. Segregation in bimetallic nanoparticles. Phys. Chem. Chem. Phys. 17, 27940–27951 (2015).

Li, G.-J., Fujimoto, T., Fukuoka, A. & Ichikawa, M. Ship-in-bottle synthesis of Pt9-Pt15 carbonyl clusters inside NaY and NaX zeolites, in-situ FTIR and EXAFS characterization and the catalytic behaviors in 13CO exchange reaction and NO reduction by CO. Catal. Lett. 12, 171–185 (1992).

Gruene, P., Fielicke, A., Meijer, G. & Rayner, D. M. The adsorption of CO on group 10 (Ni, Pd, Pt) transition-metal clusters. Phys. Chem. Chem. Phys. 10, 6144–6149 (2008).

Serykh, A. I. et al. Stable subnanometre Pt clusters in zeolite NaX via stoichiometric carbonyl complexes: probing of negative charge by DRIFT spectroscopy of adsorbed CO and H2. Phys. Chem. Chem. Phys. 2, 5647–5652 (2000).

Garnier, A., Sall, S., Garin, F., Chetcuti, M. J. & Petit, C. Site effects in the adsorption of carbon monoxide on real 1.8 nm Pt nanoparticles: an infrared investigation in time and temperature. J. Mol. Catal. A 373, 127–134 (2013).

Corma, A., Serna, P., Concepcion, P. & Calvino, J. J. Transforming nonselective into chemoselective metal catalysts for the hydrogenation of substituted nitroaromatics. J. Am. Chem. Soc. 130, 8748–8753 (2008).

Concepcion, P. et al. The promotional effect of Sn-beta zeolites on platinum for the selective hydrogenation of α,β-unsaturated aldehydes. Phys. Chem. Chem. Phys. 15, 12048–12055 (2013).

de Menorval, L.-C., Chaqroune, A., Coq, B. & François Figueras, A. Characterization of mono- and bi-metallic platinum catalysts using CO FTIR spectroscopy size effects and topological segregation. J. Chem. Soc., Faraday Trans. 93, 3715–3720 (1997).

Balakrishnan, K. A chemisorption and XPS study of bimetallic Pt-Sn/Al2O3 catalysts. J. Catal. 127, 287–306 (1991).

Panja, C. & Koel, B. E. Probing the influence of alloyed Sn on Pt(100) surface chemistry by CO chemisorption. Isr. J. Chem. 38, 365–374 (1998).

Liu, Z., Jackson, G. S. & Eichhorn, B. W. PtSn intermetallic, core–shell, and alloy nanoparticles as CO-tolerant electrocatalysts for H2 oxidation. Angew. Chem. Int. Ed. 49, 3173–3176 (2010).

Wang, X. et al. Pt/Sn intermetallic, core/shell and alloy nanoparticles: colloidal synthesis and structural control. Chem. Mater. 25, 1400–1407 (2012).

Redekop, E. A. et al. Early stages in the formation and burning of graphene on a Pt/Mg(Al)Ox dehydrogenation catalyst: a temperature- and time-resolved study. J. Catal. 344, 482–495 (2016).

Shi, L. et al. Al2O3 nanosheets rich in pentacoordinate Al3+ ions stabilize Pt-Sn clusters for propane dehydrogenation. Angew. Chem. Int. Ed. 54, 13994–13998 (2015).

Sattler, J. J., Beale, A. M. & Weckhuysen, B. M. Operando Raman spectroscopy study on the deactivation of Pt/Al2O3 and Pt–Sn/Al2O3 propane dehydrogenation catalysts. Phys. Chem. Chem. Phys. 15, 12095–12103 (2013).

Vu, B. K. et al. Location and structure of coke generated over Pt–Sn/Al2O3 in propane dehydrogenation. J. Ind. Eng. Chem. 17, 71–76 (2011).

Vu, B. K. et al. Pt–Sn alloy phases and coke mobility over Pt–Sn/Al2O3 and Pt–Sn/ZnAl2O4 catalysts for propane dehydrogenation. Appl. Catal. A 400, 25–33 (2011).

Liu, L. et al. Determination of the evolution of heterogeneous single metal atoms and nanoclusters under reaction conditions: which are the working catalytic sites? ACS Catal. 9, 10626–10639 (2019).

López-Haro, M. et al. A macroscopically relevant 3D-metrology approach for nanocatalysis research. Part. Part. Syst. Charact. 35, 1700343 (2018).

Kirkland, E. J. Advanced Computing in Electron Microscopy (Springer, 2010).

Bernal, S. et al. The interpretation of HREM images of supported metal catalysts using image simulation: profile view images. Ultramicroscopy 72, 135–164 (1998).

Simonelli, L. et al. CLÆSS: the hard X-ray absorption beamline of the ALBA CELLS synchrotron. Cogent Phys. 3, 1231987 (2016).

Guilera, G., Rey, F., Hernández-Fenollosa, J. & Cortés-Vergaz, J. J. One body, many heads; the Cerberus of catalysis. A new multipurpose in-situ cell for XAS at ALBA. J. Phys. Conf. Ser. 430, 012057 (2013).

Ravel, B. & Newville, M. ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT. J. Synchrotron Radiat. 12, 537–541 (2005).

Yin, F., Ji, S., Wu, P., Zhao, F. & Li, C. Deactivation behavior of Pd-based SBA-15 mesoporous silica catalysts for the catalytic combustion of methane. J. Catal. 257, 108–116 (2008).

Allian, A. D. et al. Chemisorption of CO and mechanism of CO oxidation on supported platinum nanoclusters. J. Am. Chem. Soc. 133, 4498–4517 (2011).

[-]

recommendations

 

This item appears in the following Collection(s)

Show full item record